R. Kaveeshwar and V. K. Gupta, “A New Spectrophotometric Method for the Determination of Hydrazine in Environmental Samples,” Fresenius Journal of Analytical Chemistry, Vol. 344, No. 3, 1992, pp. 114-117. doi:10.1007/BF00325125

has been cited by the following article:

• TITLE: Flow Injection Analysis of Hydrazine in the Aqueous Streams of Purex Process by Liquid Chromatography System Coupled with UV-Visible Detector

  AUTHORS: P. Velavendan, S. Ganesh, N. K. Pandey, N. K. Pandey, U. Kamachi Mudali, R. Natarajan

  KEYWORDS: Hydrazine; Liquid Chromatography; Purex Process; Flow Injection Analysis; Para-Dimethylaminobenaldehyde; UV-Vis Detector

  JOURNAL NAME: Journal of Analytical Sciences, Methods and Instrumentation, Vol.2 No.3, September 28, 2012

  ABSTRACT: Present study describes the development of a rapid, sensitive and selective flow injection analysis of hydrazine in the aqueous streams of purex process by liquid chromatography system coupled with UV-Visible detector. The method is based on the formation of yellow coloured azine complex by reaction of hydrazine with para-dimethy laminobenzaldehyde (pDMAB). The formed yellow coloured complex is stable in acidic medium and has a maximum absorption at 460 nm. The presence of uranium in hydrazine solution is not interfering in the analysis. Under optimum condition, the absorption intensity linearly increased with the concentration of hydrazine in the range from 0.05-10 mg?L–1 with a correlation coefficient of R2=0.9999 (n=7). The experimental detection limit is 0.05mgL–1. The sampling frequency is 15 samples h–1 and the relative standard deviation was 2.1% for 0.05 mg?L–1. This method is suitable for automatic and continuous analysis and successfully applied to determine the concentration of hydrazine in the aqueous stream of nuclear fuel reprocessing.