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http://dx.doi.org/10.1002/pen.760291311

has been cited by the following article:

• TITLE: Synthesis of Polysilanes Using Mg and Lewis Acid and the Consideration of This Reaction Mechanism

  AUTHORS: Hiroaki Murase, Masayuki Sugimoto, Hiroyuki Nishimura, Kazushi Yamada

  KEYWORDS: Polysilane, Magnesium, Lewis Acid Catalysts

  JOURNAL NAME: Materials Sciences and Applications, Vol.6 No.6, June 26, 2015

  ABSTRACT: Reduction of dichlorosilanes with Mg metal in the presence of LiCl and Lewis acid such as FeCl2 or ZnCl2 was found to be the highly practical method for the synthesis of polysilanes (PS). This method is so useful and practical that PS can be prepared by stirring dichlorosilanes at room temperature. This method was successfully applied for the synthesis of various types of PS having a linear structure, a cyclic structure and silane-styrene copolymers as another type of PS. The structure of the reaction intermediates was also analyzed. At the initiation stage the results of FD-MS (Field desorption mass spectrometry) and GPC (Gel permeation chromatography) showed that linear oligomers were mainly formed by stepwise reactions, and then the high polymers and cyclic oligomers were formed in parallel.