Article citationsMore>>
Ji, L., Zhang, D.F., Zhao, Q., Hu, S.M., Qian, C. and Chen, X.Z. (2013) Diastereospecific Epoxidation and Highly Regioselective Ring-Opening of (+)-Valienamine: Practical Synthesis of (+)-Valiolamine. Tetrahedron, 69, 7031-7037.
http://dx.doi.org/10.1016/j.tet.2013.06.046
has been cited by the following article:
-
TITLE:
Carbohydrate-Derived Organocatalysts for the Reduction of Imines with Trichlorosilane
AUTHORS:
Xin Ge, Chao Qian, Xinzhi Chen
KEYWORDS:
Carbohydrate, Organocatalyst, Reduction, Imine
JOURNAL NAME:
Journal of Materials Science and Chemical Engineering,
Vol.3 No.6,
June
12,
2015
ABSTRACT:
The backbone of D-glucosamine hydrochloride
was fine-tuned and modified by protecting the hydroxyl groups. In order to
reduce imines with trichlorosilane, the carbohydrate-derived organocatalysts
were prepared and screened. Methyl-4,6-O-benzylidene-2-amino-2-deoxy-α-D-glucopyr
anoside was found as the best catalyst. The reduction was proceeded under CHCl3
as solvent at 40?C, affording 68% - 94% yield.