TITLE:
Synthesis of 5-Substituted 2, 9-Dimethyl-1,10-Phenanthroline Dialdehydes and Their Schiff Bases with Sulfur-Containing Amines
AUTHORS:
Zinia Jaman, Mohammad R. Karim, Tasneem A. Siddiquee, Aminul H. Mirza, Mohamad A. Ali
KEYWORDS:
5-Nitro-1, 10-Phenanthroline Dialdehyde; 5-Bromo-1, 10-Phenanthroline Dialdehyde; Schiff Bases; S-Alkyl/Aryldithiocarbazates; Thiosemicarbazide
JOURNAL NAME:
International Journal of Organic Chemistry,
Vol.3 No.3,
September
25,
2013
ABSTRACT: Eight new Schiff bases of 5-nitro and 5-bromo-substituted 1,10-phenanthroline-2,9-dicarboxaldehydes with sulfur-containing amines, thiosemicarbazide, S-alkyl/aryl dithiocarbazates and 2-mercaptoaniline have been synthesized and characterized by a variety of spectroscopic methods. The condensation reactions of the dialdehydes with the amines were carried out both in the presence and absence of conc. sulfuric acid. A significant increase in yield of the Schiff bases was observed when the reactions were carried out in the presence of sulfuric acid.