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Article citations


L. Zhou, H. Chen, X. Jiang, F. Lu, Y. Zhou, W. Yin and X. Ji, “Modification of Montmorillonite Surfaces Using a Novel Class of Cationic Gemini Surfactants,” Journal of Colloid and Interface Science, Vol. 332, No. 1, 2009, pp. 16-21. doi:10.1016/j.jcis.2008.12.051

has been cited by the following article:

  • TITLE: Electrocatalytic and Sensors Properties of Natural Smectite Type Clay towards the Detection of Paraquat Using a Film-Modified Electrode

    AUTHORS: H. L. Tcheumi, I. K. Tonle, A. Walcarius, E. Ngameni

    KEYWORDS: Electrocatalysis; Paraquat; Clay-Film Modified Electrode; Voltammetry; Sensor

    JOURNAL NAME: American Journal of Analytical Chemistry, Vol.3 No.11, November 29, 2012

    ABSTRACT: In this study, a low-cost and sensitive voltammetric method was developed for the determination of paraquat (PQ2+). This was achieved by coating a glassy carbon electrode with a purified fraction of a smectite-type clay, which was then used to accumulate paraquat by an ion exchange process. The electronanalytical procedure involves two steps: the chemical preconcentration of paraquat under open-circuit conditions in an aqueous medium, followed by the voltammetric detection of the preconcentrated pollutant in a medium containing permanganate ions which significantly improved through its catalytic action the electrode response. A systematic study of the experimental conditions (pH of the accumulation and detection media, permanganate concentration in the detection medium, clay content of the coating, potential and duration of the electrolysis step) on the stripping response were examined in detail. After optimization, a linear calibration curve for paraquat was obtained in the concentration range from 1.6 to 2.8 μM, leading to a detection limit of 3.8 × 10–9 mol·L–1 (S/N = 3). The proposed method was successfully applied to the determination of paraquat in spring water.