Adeyemi, O.G., Eke, U.B., Cheng, L., Cook, L.M., Billing, D.G., Mamba B.B., Levendis D.C. and Coville N.J. (2004) Solid-state isomerisation reactions of (η5-C5H4R)-M(CO)2(PR3’)I (M = W, Mo; R = tBu, Me; R = Ph, OjPr3). Journal of Organometallic Chemistry, 689, 2207-2215. doi:10.1016/j.jorganchem.2004.04.009

has been cited by the following article:

• TITLE: Solid state transformation of cis and trans methylcyclopentadienyl molybdenumdicarbonyltriphenylphosphineiodide on pelleting utilizing different diluents

  AUTHORS: Olalere G. Adeyemi, Umaru Salami

  KEYWORDS: Solid State; cis/trans-[(η5-C5H4Me)Mo(CO)2PPh3I]; Pelleting; Diluents; FT IR

  JOURNAL NAME: Open Journal of Inorganic Chemistry, Vol.2 No.2, April 24, 2012

  ABSTRACT: [(η5-C5H4Me)Mo(CO)2PPh3I] undergoes solid state transformation on the formation of a good pellet for FT IR measurement. There was a formation of the products mixture on pelleting using different diluents of group I metal salts on either the cis or the trans isomer of the [(η5-C5H4Me)Mo(CO)2PPh3I] complex. The cis or the trans isomer gave the same IR spectra i.e. a mixture of cis and trans isomer of the complex. It does not matter the isomer started with in the course of solid state transformation reaction, an equilibrium ratio of 30/70 (trans/cis) will still be achieved. The solid state IR spectra show very strong peaks at νco 1957, 1947 and strong peaks at 1867, 1853 cm–1. The individual IR cis/trans isomer will therefore show at 1947 and 1853/1957 and 1867 cm–1. The solution IR spectra gave, cis = 1961, 1875 and trans = 1963, 1882 cm–1 in dry CHCl3. Hence, most of the solid state IR measurement of the organometallic complex of the type (η5-C5H4Me)Mo(CO)2(PPh3)I on pelleting will give isomer mixture.