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https://doi.org/10.1021/jf00050a016

has been cited by the following article:

• TITLE: Hydrogen Bonds Sites of Amylose or Amylopectin from Starch at the ONION Level (B3LYP/6-311++G [d, p]: AM1)

  AUTHORS: Ablé Anoh Valentin, N’Guessan Boka Robert, Bamba El Hadji Sawaliho

  KEYWORDS: Hydrogen Bonds, Glucose, Amylose, Amylopectin

  JOURNAL NAME: Computational Chemistry, Vol.9 No.1, January 25, 2021

  ABSTRACT: The research aims to help reduce the enormous post-harvest losses of rice or bananas in Cote d’Ivoire. It focuses on the breakdown mechanism of their starch. This process contributes to their decay. This study wants to elucidate it; to do this, it analyzes the tetra or penta saccharide reactions with the water or dioxide carbon. It calculates the geometric, energetic and spectroscopic parameters at the ONIOM level (B3LYP/6-311++G [d, p]: AM1). These quantities allow establishing that oxygenrepresents the privileged hydrogen bond (HB) site for amylose with four or five D-glucose building blocks. They suggest andare respectively those of amylopectin when the latter consists of four and five D-glucose synthons. They prove that amylose deteriorates before it; the degradation of starch begins with its alteration into disaccharides. It continues with that of amylopectin into tri or tetra-saccharides with four or five building blocks.