TITLE:
Acidic Polyester Imides as Thermally Stable Binder Polymers for Negative-Tone Black Photoresist
AUTHORS:
Genggongwo Shi, Kyeongha Baek, Jun Bae, Lee Soon Park
KEYWORDS:
Polyester Imide, One-Pot Solution Polymerization, Black Photoresist, Photolithography
JOURNAL NAME:
Materials Sciences and Applications,
Vol.11 No.4,
April
13,
2020
ABSTRACT: Polyimides are well-known for their high chemical inertness and thermal stability. However, it is usually challenging to synthesize UV-curable polyimides since the imidization reaction requires such harsh conditions that acrylate type double bonds cannot withstand. In this work, synthetic methods are developed to obtain polyester-imide type binder polymers with high thermal stability, high compatibility with the other components of the black photoresist, and fine photolithographic patterning property for the negative-tone black photoresist. The syntheses of diimide-diacid or diimide-diol intermediates for the polyesterification with dianhydride gave polyester imides which meets this requirement. The photolithographic tests have shown that the patterning of the micron-sized PDL of the organic light emitting diode (OLED) panel could be obtained. This work will interest the researchers working on the design and optimization of thermally stable binder polymers.