Ilhan, S., Temel, H., Yilmaz, I. and Sekerci, M. (2007) Synthesis, Structural Characterization and Electrochemical Studies of New Macrocyclic Schiff Base Containing Pyridine Head and Its Metal Complexes. Journal of Organometallic Chemistry, 692, 3855-3865.
https://doi.org/10.1016/j.jorganchem.2007.05.031

has been cited by the following article:

• TITLE: Synthesis, Spectral Characterization and Thermal Behavior of Newly Derived La(III), Co(III) and Mn(II) Complexes with Schiff Base Derived from Methionine and Salicylaldehyde

  AUTHORS: Shariful Islam, A. K. M. Nur Alam Siddiki, Shahida Begum, Md. Abdus Salam

  KEYWORDS: Schiff Base, Metal Complexes, Spectral Studies, Thermal Behavior, X-Ray Powder Diffraction

  JOURNAL NAME: Open Journal of Inorganic Chemistry, Vol.8 No.2, March 30, 2018

  ABSTRACT: Many metal complexes of Schiff base derived from different amino acids are widely employed as biologically active materials, especially as antibacterial agents. Three new metal [Co(III), Mn(II) and La(III)] complexes with the Schiff base (L) derived from salicylaldehyde and amino acid (methionine) were synthesized and investigated by using various physico-chemical techniques such as elemental analysis, FTIR, UV-visible spectroscopy, magnetic measurement, thermo gravimetric analysis (TGA) and X-ray powder diffraction (XRD) method. From spectral studies, it has been concluded that the synthesized ligand acts as a tetra-dentate molecule, coordinates metal through azomethine nitrogen, sulfur, phenolic oxygen and carboxylate oxygen. UV-visible spectrophotometry showed the characteristic absorption bands corresponding to a square planar geometry for La(III) and Mn(II) metal complexes and tetrahedral geometry for Co(III) complex. The XRD data demonstrated that the manganese and cobalt complexes were crystalline but the lanthanum complex was amorphous in nature. The empirical formula of the synthesized complexes based on analytical data were [Co(C12H13SNO3)]·(NO3), [La(C12H13SNO3)](Cl)(H2O) and [Mn (C12H13SNO3)].