Article citationsMore>>
Prokhorova, T.G., Khasanov, S.S., Zorina, L.V., Buravov, L.I., Tkacheva, V.A., Baskakov, A.A., Morgunov, R.B., Gener, M., Canadell, E., Shibaeva, R.P. and Yagubskii, E.B. (2003) Molecular Metals Based on BEDT-TTF Radical Cation Salts with Magnetic Metal Oxalates as Counterions: β”-(BEDT-TTF)4A[M(C2O4)3]·DMF (A = NH4+, K+; M = CrIII, FeIII). Advanced Functional Materials, 13, 403-411.
https://doi.org/10.1002/adfm.200304283
has been cited by the following article:
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TITLE:
Anionic Nanochanneled Silver-Deficient Oxalatochromate(III) Complex with Hydroxonium as Counter Ion: Synthesis, Characterization and Crystal Structure
AUTHORS:
Clémence T. Eboga, Gouet Bebga, Yves A. Mbiangué, Emmanuel N. Nfor, Patrick L. Djonwouo, Michel M. Bélombé, Justin Nenwa
KEYWORDS:
Silver-Deficient Oxalatochromate(III), Water-Filled Nanochannels, Protons, Thermal Analysis, Crystal Structure
JOURNAL NAME:
Open Journal of Inorganic Chemistry,
Vol.7 No.3,
July
18,
2017
ABSTRACT: Reaction of Ba0.50[Ag2Cr(C2O4)3]·5H2O with Ag2SO4 in an aqueous solution of sulfuric acid (pH ≈ 3) yielded the silver(I)/chromium(III) oxalate salt H0.50[Ag2.50Cr(C2O4)3]·5H2O (1). Compound 1 can be best described as an anionic silver-deficient oxalatochromate(III) complex [Ag2.50Cr(C2O4)3]0.5- with nanochannels containing hydrogen-bonded water molecules and protons. Thermal analyses show significant weight losses corresponding to the elimination of water molecules of crystallization followed by the decomposition of the network.