Van Uitert, L.G. and Hass, C.G. (1953) Studies on Coördination Compounds. I. A Method for Determining Thermodynamic Equilibrium Constants in Mixed Solvents. Journal of the American Chemical Society, 75, 451-455.
http://dx.doi.org/10.1021/ja01098a057

has been cited by the following article:

• TITLE: Effect of Temperature and Solvent Composition on the Acid Dissociation Constants of 2-Pyrrol and 2-Thiophene Aldehyde Phenyl Sulphonyl Hydrazones

  AUTHORS: Refaat I. Nessim, Imad E. Albalaa, Mona Abu Assi

  KEYWORDS: Acid Dissociation Constant, Pyrrol, Thiophene

  JOURNAL NAME: Natural Science, Vol.8 No.10, October 31, 2016

  ABSTRACT: Acid dissociation constants, pKa, of 2-pyrrolaldehyde phenylsulphonyl hydrazone, 1, and 2-thiophenealdehyde phenylsulphonyl hydrazone, 2, have been determined spectrophotometrically in ethanol-water media of various compositions over the temperature range 25℃ - 45℃. The obtained results were used in the calculation of the enthalpy, △H°, and the entropy, △S°, of the ionization processes. The slight variations observed in the pKa values of the thiophene compound compared to the pyrrol analogue revealed that neither of the two hetero atoms in the pyrrol or thiophene rings, of the two compounds, is involved in a hydrogen bond chelation. This conclusion was also confirmed through measurements of the dipole moment, IR and NMR spectra.