Lux, S.F., Schmuck, M., Appetecchi, G.B., Passerini, S., Winter, M. and Balducci, A. (2009) Lithium Insertion in Graphite from Ternary Ionic Liquid-Lithium Salt Electrolyte. II. Evaluation of Specific Capacity and Cycling Efficiency and Stability at Room Temperature. Journal of Power Sources, 192, 606-611. - References

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Lux, S.F., Schmuck, M., Appetecchi, G.B., Passerini, S., Winter, M. and Balducci, A. (2009) Lithium Insertion in Graphite from Ternary Ionic Liquid-Lithium Salt Electrolyte. II. Evaluation of Specific Capacity and Cycling Efficiency and Stability at Room Temperature. Journal of Power Sources, 192, 606-611.
http://dx.doi.org/10.1016/j.jpowsour.2009.02.066

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TITLE: Safety Assessment of Ionic Liquid-Based Lithium-Ion Battery Prototypes

AUTHORS: J. Kalhoff, G.-T. Kim, S. Passerini, G. B. Appetecchi

KEYWORDS: Ionic Liquids, Lithium-Ion Battery Prototype, Abuse Tests

JOURNAL NAME: Journal of Power and Energy Engineering, Vol.4 No.3, March 18, 2016

ABSTRACT: In this paper we report the results of combined cycle- and life-aging and abuse tests carried out under severe conditions on Li4Ti5O12/LiFePO4 lithium-ion stacked prototypes using a PYR14 FSI-LiTFSI ionic liquid electrolyte. No relevant degradation phenomena took place within ionic liquid electrolyte during prolonged inactivity period or overcharging. No fire/explosion or venting event as well as no gas development occurred during abuse tests, which led only to modest raise in temperature. Therefore, electrodes based on Li4Ti5O12 and LiFePO4 active materials can be favorably combined with non-volatile and non-flammable pyrrolidinium FSI ionic liquid electrolytes to realize highly safe lithium-ion battery systems.

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