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http://dx.doi.org/10.1016/j.electacta.2004.01.078

has been cited by the following article:

• TITLE: Rhodium Nanoparticle-Loaded Carbon Black Electrocatalyst for the Glycerol Oxidation Reaction in Alkaline Medium

  AUTHORS: Binh Thi Xuan Lam, Masanobu Chiku, Eiji Higuchi, Hiroshi Inoue

  KEYWORDS: Glycerol Oxidation Reaction, Direct Glycerol Fuel Cell, Rhodium, Nanoparticle

  JOURNAL NAME: Advances in Nanoparticles, Vol.5 No.1, February 15, 2016

  ABSTRACT: Rhodium nanoparticle-loaded carbon black (Rh/CB) was prepared by a wet method, and its activity and durability for glycerol oxidation reaction (GOR) in alkaline medium were compared with Pt, Pd and Au nanoparticle-loaded CB (Pt/CB, Pd/CB and Au/CB). In the cyclic voltammogram of the Rh/CB electrode, the redox waves due to hydrogen adsorption/desorption and the surface OH monolayer formation/reduction were observed at more negative potentials than the Pt/CB and Pd/CB electrodes. The onset and peak potentials of the GOR current densities for the Rh/CB electrode were ca. –0.55 and –0.30 V vs. Hg/HgO, respectively, which were 0.10 and 0.20 V more negative than the Pt/CB electrode whose GOR activity was the best, indicating that Rh was a fascinating metal for reducing the overpotential for GOR. In the electrostatic electrolysis with the Rh/CB and Pt/CB electrodes, the decrease in the GOR current density in the former with time was suppressed compared to that in the latter, suggesting that the tolerance to poisoning for the Rh/CB electrode was superior to that for the Pt/CB electrode.