Arockiasamy, S., Sreetharan, O.M., Mallika, C., Raghunathan, V.S. and Nagaraja, K.S. (2007) Development, Characterisation and Rapid Evaluation of Standard Enthalpies of Vaporisation and Fusion of Volatile Bis(NR-Salicylaldimine) Nickel(II) (nR= Methyl to Pentyl) Complexes for Its MOCVD Applications. Chemical Engineering Science, 62, 1703-1711.
http://dx.doi.org/10.1016/j.ces.2006.12.001

has been cited by the following article:

• TITLE: Characterization and Evaluation of Standard Enthalpy of Vaporization and Kinetic Studies of Volatile bis(N-ethyl-5-methyl-salicylaldimine)nickel(II) Complex

  AUTHORS: Thevabakthi Siluvai Muthu Arul Jeevan, Maria Francis George Johnson, Atnafu Guadie Assefa, Sebastian Arockiasamy, Karachalacheruvu Seetharamaiah Nagaraja

  KEYWORDS: Nickel Complexes, Enthalpy of Vaporization, Thermogravimetry, Vapour Pressure, Kinetic Studies

  JOURNAL NAME: American Journal of Analytical Chemistry, Vol.6 No.2, January 20, 2015

  ABSTRACT: The bis(N-ethyl-5-methylsalicylaldimine)nickel(II) [Ni(5-me-saletN)2] complex was synthesized and characterized by elemental analyses, FT-IR, TG-DTA, mass spectrometry and vapour pressure measurement studies. The TG curve of the complex showed a single-step weight loss commencing from 490 K to nil residue at 600 K, without competing fragmentation step. The non-isothermal vaporization activation energy value determined by Coats-Redfern method yielded the value of 93.5 ± 7 kJmol–1. The dynamic TG run proved the complex to be completely volatile. And the equilibrium vapour pressure of the complex over the temperature range of 421 - 524 K, determined by the TG-based transpiration technique yielded the value of 94.2 ± 1.2 kJmol–1 for its standard enthalpy of vaporization . The entropy of vaporization was calculated from the intercept and found to be 249.4 ± 2.6 Jmol–1•K–1.