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Andrés, R., Brissard, M., Gruselle, M., Train, C., Vaissermann, J., Malézieux, B., Jamet, J.P. and Verdaguer, M. (2001) Rational Design of Three-Dimensional (3D) Optically Active Molecule-Based Magnets: Synthesis, Structure, Optical and Magnetic Properties of {[Ru(bpy)3]2+, , [MnIICrIII(ox)3]-}n and {[Ru(bpy)2ppy]+, [MIICrIII(ox)3]-}n, with MII = MnII, NiII. X-Ray Structure of {[ΔRu(bpy)3]2+, , [ΔMnIIΔCrIII(ox)3]-}n and {[ΛRu(bpy)2ppy]+,
[ΛMnIIΛCrIII(ox)3]-}n. Inorganic Chemistry, 40, 4633-4640. http://dx.doi.org/10.1021/ic010363f
has been cited by the following article:
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TITLE:
Synthesis, Crystal Structure and Thermal Behavior of a 3-D Barium(II)/Iron(III)-Oxalate Polymer
AUTHORS:
Noé Makon Ma Houga, Brian S. Dolinar, Justin Nenwa, Gouet Bebga
KEYWORDS:
Tris(Oxalato)Ferrate(III) Anion, Bimetallic Complex Polymer, Crystal Structure, Thermal Stability
JOURNAL NAME:
Open Journal of Inorganic Chemistry,
Vol.4 No.2,
April
14,
2014
ABSTRACT: Reaction of Ba(NO3)2 with Fe(NO3)3·9H2O
and H2C2O4·2H2O in aqueous medium
readily affords, in high yield, the bimetallic complex polymer of chemical
composition {Ba6(H2O)17[Fe(C2O4)3]4}·7H2O
(1), consistent with the expected ratio of 3BaII vs. 2FeIII. Compound 1 was
fully characterized by elemental and thermal analyses, vibrational FTIR
spectroscopy, and by single crystal X-ray structure determination. The bulk
structure of 1 is a 3-D metal-organic framework held together by intermetallic
linkages across oxalate and aqua oxygen bridgings. Thermal analyses of 1 show significant weight losses corresponding to
water molecules (lattice and coordinated), followed by the decomposition of the
network.