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has been cited by the following article:

• TITLE: Molecular and electronic structure of several 2,3-dithienylquinoxalines and their 2:1 complexes with silver(I) nitrate

  AUTHORS: Guy Crundwell, Stefanie Cantalupo, Paul D. C. Foss, Brian McBurney, Kristen Kopp, Barry L. Westcott, James Updegraff III, Matthias Zeller, Allen D. Hunter

  KEYWORDS: X-Ray Diffraction; Silver(I) Complexes; Thiophene; Quinoxalines; Photoelectron Spectroscopy

  JOURNAL NAME: Open Journal of Inorganic Chemistry, Vol.4 No.1, January 2, 2014

  ABSTRACT: We have synthesized three bis (thienyl) quinoxalinesilver(I) complexes; however, unlike analogous silver(I) complexes of pyridylquinoxaline that utilize (N, N) bidentate behavior from the quinoxaline and pyridyl ring nitrogens, the bis(thienyl) quinoxaline ligands did not utilize the bonding potential of the thienyl rings to give (N, S) bonding modes. PES spectra modeling of these ligands indicates that the preferential metal bonding via only the quinoxaline nitrogen atoms is due to the N-rich, but S-poor, characters of the frontier orbitals.