Parametric Study of Calibration Blackbody Uncertainty Using Design of Experiments ()

Nipa Phojanamongkolkij, Joe A. Walker, Richard P. Cageao, Martin G. Mlynczak, Joseph J. O’Connell, Rosemary R. Baize

Aeronautics System Engineering, Engineering Directorate, NASA Langley Research Center, Hampton, USA.

Clarreo Project Office, Flight Projects Directorate, NASA Langley Research Center, Hampton, USA..

Climate Science Branch, Science Directorate, NASA Langley Research Center, Hampton, USA.

Remote Sensing Flight Systems, Engineering Directorate, NASA Langley Research Center, Hampton, USA.

Science Systems and Applications Inc., Hampton, USA.

**DOI: **10.4236/jasmi.2012.23020
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Aeronautics System Engineering, Engineering Directorate, NASA Langley Research Center, Hampton, USA.

Clarreo Project Office, Flight Projects Directorate, NASA Langley Research Center, Hampton, USA..

Climate Science Branch, Science Directorate, NASA Langley Research Center, Hampton, USA.

Remote Sensing Flight Systems, Engineering Directorate, NASA Langley Research Center, Hampton, USA.

Science Systems and Applications Inc., Hampton, USA.

NASA is developing the Climate Absolute Radiance and Refractivity Observatory (CLARREO) mission to provide accurate measurements to substantially improve understanding of climate change. CLARREO will include a Reflected Solar (RS) Suite, an Infrared (IR) Suite, and a Global Navigation Satellite System-Radio Occultation (GNSS-RO). The IR Suite consists of a Fourier Transform Spectrometer (FTS) covering 5 to 50 micrometers (2000-200 cm^{-1} wavenumbers) and on-orbit calibration and verification systems. The IR instrument will use a cavity blackbody view and a deep space view for on-orbit calibration. The calibration blackbody and the verification system blackbody will both have Phase Change Cells (PCCs) to accurately provide a SI reference to absolute temperature. One of the most critical parts of obtaining accurate CLARREO IR scene measurements relies on knowing the spectral radiance output from the blackbody calibration source. The blackbody spectral radiance must be known with a low uncertainty, and the magnitude of the uncertainty itself must be reliably quantified. This study focuses on determining which parameters in the spectral radiance equation of the calibration blackbody are critical to the blackbody accuracy. Fourteen parameters are identified and explored. Design of Experiments (DOE) is applied to systematically set up an experiment (i.e., parameter settings and number of runs) to explore the effects of these 14 parameters. The experiment is done by computer simulation to estimate uncertainty of the calibration blackbody spectral radiance. Within the explored ranges, only 4 out of 14 parameters were discovered to be critical to the total uncertainty in blackbody radiance, and should be designed, manufactured, and/or controlled carefully. The uncertainties obtained by computer simulation are also compared to those obtained using the “Law of Propagation of Uncertainty”. The two methods produce statistically different uncertainties. Nevertheless, the differences are small and are not considered to be important. A follow-up study has been planned to examine the total combined uncertainty of the CLARREO IR Suite, with a total of 47 contributing parameters. The DOE method will help in identifying critical parameters that need to be effectively and efficiently designed to meet the stringent IR measurement accuracy requirements within the limited resources.

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Phojanamongkolkij, N. , Walker, J. , Cageao, R. , Mlynczak, M. , O’Connell, J. and R. Baize, R. (2012) Parametric Study of Calibration Blackbody Uncertainty Using Design of Experiments. *Journal of Analytical Sciences, Methods and Instrumentation*, **2**, 109-119. doi: 10.4236/jasmi.2012.23020.

1. Introduction

NASA is developing the Climate Absolute Radiance and Refractivity Observatory (CLARREO) mission [1,2] to provide accurate measurements to substantially improve understanding of climate change [3], as recommended in the Decadal Survey [4] of the National Research Council (NRC). CLARREO will include a Reflected Solar (RS) Suite, an Infrared (IR) Suite, and a Global Navigation Satellite System-Radio Occultation (GNSS-RO) [2]. The IR Suite consists of a Fourier Transform Spectrometer (FTS) covering 5 to 50 micrometers (2000 - 200 cm^{–1} wavenumbers) and on-orbit calibration and verification systems [5]. The IR instrument will use a cavity blackbody view and a deep space view for on-orbit calibration. The calibration blackbody and the verification system blackbody will both have Phase Change Cells (PCCs) [6] to accurately provide a SI-traceable reference [7] to absolute temperature. One of the most critical parts of obtaining accurate CLARREO IR scene measurements relies on knowing the spectral radiance output from the blackbody calibration source. The blackbody spectral radiance must be known with a low uncertainty, and the magnitude of the uncertainty itself must be reliably quantified.

This study focuses on determining which parameters in the spectral radiance equation of the calibration blackbody are critical to the blackbody accuracy. The spectral radiance of the calibration blackbody can be broken down into the radiance emitted by the blackbody and the radiance reflected by the blackbody. The reflected radiance portion is composed of the all flux entering the blackbody from all other surfaces surrounding the blackbody, and reflected back out by the blackbody. For a preliminary study, the surrounding surfaces are categorized as either the blackbody external heater, or the FTS, which in this case includes all the blackbody surroundings except the heater. The external heater is a device used periodically to measure the blackbody reflectance.

The major components of the system are shown in Figure 1. For this analysis, the scene select mirror (SSM) and its housing are assumed to be at the same temperature as the FTS, so its effects are lumped together with the FTS. The SSM is a “barrel-roll” type of mirror that rotates to allow the FTS to view different radiation sources, one of which is the calibration blackbody. Equation (1) is the expression for the spectral radiance of the calibration blackbody for this simplified model [7].

(1)

The Planck radiation equation for spectral radiance at wavenumber u and temperature T, in units of W·m^{–2}·sr^{–1}·(cm^{–1})^{–1} is

(2)

Equation (1) may not be adequate to describe the conditions for the on-orbit calibration accuracy required by

Figure 1. FTS, Scene Select Mirror Assembly, and Calibration Blackbody.

the CLARREO IR instrument, in that it does not account for the individual contributions to the reflected radiance by all elements of the blackbody surroundings; rather it lumps them all together into the two terms—heater and FTS. It is used here as a first order model to allow for a demonstration of the application of the Design of Experiments (DOE) technique to systematically set up an experiment. DOE provides the experimental method (i.e., parameter settings and number of runs) to randomly explore all the parameters in Equation (1) without the need to exhaustively examine all of the infinitely possible permutations of parameter values.

Although the system under the study is simple and has been well studied in literature, we would like to emphasize that our intention is to demonstrate the DOE application with the well-understood system before applying it to the system comprised of the CLARREO IR suite. The total combined uncertainty of the IR Suite will be affected by the individual uncertainties of a number of contributing components, including for example, the calibration blackbody, the cold scene source, the system nonlinearity, and the contributions of several elements of the FTS, especially the detector and optical systems. There are a total of 47 parameters that contribute to the total combined uncertainty. Because the CLARREO IR measurement accuracy requirement is very stringent, a follow-up study has been planned to exhaustively examine as many of the large number of possible permutations of these 47 parameters as possible. The DOE method will provide significant benefit in systematically setting up an experiment to explore the effects of all 47 parameters with an optimal number of runs.

2. Method

A parametric study is usually performed to gain some insight on how changes in parameters affect the changes in the response or output. Traditionally, it changes one parameter at a time (OPAT) while keeping all other parameters at their nominal values, and observes the parameter’s effect on the response. This OPAT method works well if the response behaves the same way when a particular parameter changes, regardless of the values at which all other parameters are set, i.e., main effect. However, if the responses can behave differently, depending on the values of the other parameters, e.g. the cross-term effect, then this OPAT method will fail to capture that dependence.

As opposed to the traditional OPAT study, DOE allows all parameters to vary simultaneously with optimal runs, making it possible to extract both the main and cross-term effects and test them statistically for significance. We will be able to determine which parameters and their cross-term effects in the blackbody radiance equations are more critical to the total uncertainty. The process can be used to identify critical characteristics that should be designed, manufactured, and/or controlled with special care.

We code Equations (1) and (2) in MATLAB. If we know the values of all parameters on the right hand side of Equation (1), we can then calculate the spectral radiance of the calibration blackbody as a function of all wavenumbers. The obtained radiance is treated as truth because all parameters are known without any uncertainty associated with them. On the contrary, if all parameter values are assumed to follow a Normal distribution that has the estimated mean and standard deviation, then the obtained radiance distribution will also be Normal, with the estimated mean (i.e., the truth) and standard deviation (i.e., the total radiance uncertainty). We would like to get a good estimate of this total radiance uncertainty. In this study, we will use computer simulations to estimate the total uncertainty.

Figure 2 provides details of the experiment chosen for this study. There are 5 responses, which are uncertainty (1 standard deviation) of the calibration blackbody radiance at wavenumbers 200, 600, 1000, 1400, and 2000 cm^{–1}. Fourteen input parameters are investigated. The first 7 inputs are parameters in Equation (1), while the last 7 inputs are their corresponding uncertainties (at 3 standard deviations). Experimental ranges for all inputs are given as low and high possible values. These ranges are chosen to represent the current known specifications at the time of this study. The center values are the midpoints of the experimental ranges. There would be an infinite number of possible combinations if we were to randomly select input values from these ranges to generate the responses. However, because our main objective here is to screen for critical parameters and to understand cross-term effects, we develop a procedure to determine statistically which parameters should be retained in a parsimonious model. Those retained parameters are our critical parameters.

The parsimonious model is based on a second-order Taylor series expansion, excluding the pure quadratic terms, as

(3)

All b’s and their corresponding uncertainties are estimated from simulation results. There are 5 versions of this equation, one for each wavenumber. For screening purposes, we do not need to know the coefficients of the purely quadratic terms in Equation (3), but rather we need to determine if they should be included in the next sequential experiment. Therefore, there are 106 unknown coefficients (i.e., 1 for the intercept, 14 for the main independent parameters, and 91 for the cross-term effects). We will need at least 106 unique combinations of all 14 parameters to be able to determine all coefficients.

When selecting these unique parameter combinations, we only need to test the lower and upper values of all parameters. For example, if outputs at low and high values of are not different significantly, then is unlikely to be significant. On the contrary, if both end

Figure 2. Experiment setting for computer simulation.

values have statistically different outputs, then is likely to be one of the significant parameters in the first order (linear) sense. To investigate the cross-term effects, for example, , we keep at its low value and observe the output gradient of changing from low to high, compare this gradient to that of when at its high value. If both gradients are not significantly different, then is unlikely to be significant, and vice versa. There could be a case where the output may have a concave or convex bell shape, in which the center value has the lowest/highest output. So testing only at the ends is not sufficient if both ends have the same outputs. To guard against this situation, we add a few center runs in which all parameters are set at their center values. If the average center run output is higher than the average output at all ends, then we know that the linear model assumption is invalid. In that case, we can add sequential runs to determine the purely quadratic or higher-order terms.

In this screening experiment we use a 128^{th} fraction of the 2^{14} factorial design with 10 center points (i.e., + 10 center points). This is a resolution IV design, in which no main effect is aliased with any other main effect or cross-term effect, but cross-term effects are aliased with each other. We may perform a sequential experiment if we have to de-alias cross-term effects to accurately conclude the results from this screening experiment. Empirically, it is less likely that higher-order cross-terms significantly contribute to the response [8]. Therefore, it is unlikely that we will lose any significant information by using this design.

There is a rationale for assigning factor letters to parameters (column “Factor” in Figure 2). We use subject-matter judgment based on the alias structure of the design. The more likely parameters can be assigned to factors that alias with the less likely ones. The low confidence parameters (or ones with limited knowledge) are assigned to factors that only alias with three-factor or higher-order cross-terms. With this strategy, we feel more confident when drawing conclusions.

The chosen design requires 138 runs. Out of 138 runs, 128 runs are unique parameter combinations of the low and high values, and the other 10 are repeated with all parameters the same, and set at their center values. Since all experiment runs are computer simulations, it may seem that runs using duplicated values would give the same output. However that is not the case, because each time the duplicated values are run, different random numbers are used to estimate the radiance uncertainties.

We investigate the quality of computer simulation results. The mean radiance of the simulation solutions has to be an unbiased estimator of its corresponding truth radiance. This mean radiance changes as the number of simulations increases. We evaluate the sensitivity of using different numbers of simulations to simulation error (the uncertainty of the mean). We would expect simulation error to improve as the number of simulations increases. This technique is referred to as Variance Reduction technique [9]. Simulation error can be calculated from

(4)

Figure 3 shows the sensitivity of the number of simulations to the simulation error for a randomly selected run

Figure 3. Sensitivity of the number of simulations to the simulation error.

from our 138 runs. The error converges to the minimum value after 10,000 simulations. For our study, we can therefore use 10,000 simulations for each of 138 runs. However, a general practice often suggests 100,000 simulations to guarantee convergence to the minimum uncertainty of the mean. We therefore choose N to be 100,000 for our study.

Figure 4 shows the detail on how the computer simulation is done. The outer loop is repeated 138 times, one for each run. We produce a 100,000 by 5 array of calibration blackbody radiances for each run. Row represents 100,000 different sets of random numbers used in the simulation. Column represents 5 different wavenumbers of interest. Also produced for each run is the truth radiances (a 1 by 5 array) when all parameters do not have any uncertainty. Uncertainty for each run is then estimated based on root mean squared error.

Details of Monte Carlo function are given in Figure 5. The temperature of the calibration blackbody is assumed to follow a Normal distribution with its mean and standard deviation given by Tcbb and U_Tcbb/3, respectively. Similar distribution assumptions apply for temperatures of the heater and the FTS. Due to the physical limit of emissivities and view factors (i.e., must be less than or equal to 1), their distributions are handled differently than those of temperatures. For any runs with low Ecbb value (0.98), the emissivity of the calibration blackbody is assumed to follow a Normal distribution with mean and standard deviation given by Ecbb (0.98) and U_Ecbb/3 (0.0001/3), respectively. This is because it is unlikely for these runs to have any Ecbb’s sampled from this distribution greater than 1. We have validated this during our experiment. Similar Normal distribution assumptions apply for emissivities of the heater and the FTS, and the view factor of any runs with low values. On the other hand, for any runs with high Ecbb value (0.999),

Figure 4. Computer simulation framework.

Figure 5. Monte Carlo function.

its distribution is assumed to follow Right Truncated Normal (RTN) distribution. This RTN distribution can be thought of as the right-bounded Normal distribution, where the sampled Ecbb values cannot exceed 0.9995 (or Ecbb + k_{r} × U_Ecbb/3 = 0.999 + 1 × 0.0015/3). RTN distributions are also assumed for emissivities of heater and FTS, and view factor of any runs with high values. The sampled Eheat, Efts, and F values are not allowed to exceed 0.9983, 0.9967, and 0.92, respectively. The rightbounded values (k_{r}) are subjectively chosen and should not have an impact on the findings of the screening experiment as long as the sample values do not exceed 1.

When running this experiment, we partition our 138 runs into 2 blocks of 69 each. This is done to ensure that the actual batch execution on a personal computer for each block can be complete without interruption, such as power shutdown, or any other computer related issues. We also randomize all runs to guard against possible unknown bias (e.g., random number quality) that could sabotage our findings. Our design is in fact a randomized complete block experiment [8].

3. Results

We used Minitab [10] in setting and analyzing this experiment. The factorial experiment is usually analyzed by using Analysis-of-Variance (ANOVA). We investigated to make certain that none of ANOVA assumptions (normality, independency, and constant variance of residuals) is violated. There is no strong evidence of any violations. Block effect has no statistical effect on the responses. In other words, our responses do not depend on when the computer simulation is run. This also implies that the quality of random numbers is good. Figure 6 summarizes the analysis. For each wavenumber, we test several models (in the form of Equation (3)) with different number of significant regression coefficients based on ANOVA and 95% confidence level. These are reported in column “#Signi. Effects”, which includes the intercept term. The last 9 columns provide the significant terms in descending order of the coefficient magnitudes for all models under investigation.

Standard error (SE), prediction error sum of squares (PRESS), and total variation explained by the model, adjusted for appropriate number of terms in the model (R-sq(adj)) are statistics measures to determine the best model. They are reported in columns “SE”, “PRESS”, and “R-sq(adj)”, respectively. The “Quadratic/Nonlinear model needed?” column indicates if the model requires pure quadratic terms and higher-order terms. These are to test the hypothesis of whether or not the center-point average differs from the average at all ends. All models suggest that they are. Therefore, we will need to add additional runs if we were to use the model to predict the calibration blackbody uncertainty more accurately.

We also perform an additional 138 confirmation runs to check model predictability. These confirmation runs are another 128^{th} fraction of the 2^{14} factorial design with 10 center points. Column “RMPE” (root mean square prediction error) shows how well each model predicts based on these 138 confirmation runs. The RMPE is calculated from

Figure 6. Detailed analysis summary for all wavenumbers.

(5)

Note that PRESS and RMPE are quite similar. However, the PRESS is based on the data that is used to fit the model, while the RMPE is based on the new data that are not used during model fitting. More coefficient terms in the model usually improve PRESS, but may result in poor RMPE. This is the case when we over-fit the model (see an example in Figure 6, for 1000 wavenumber, Models 2 and 3).

The best model can be determined based on the minimum SE, PRESS, R-sq(adj), and RMPE statistics. By subjectively evaluating using these four statistics, the best model for each wavenumber was selected (bold font in Figure 6). Figure 7 provides critical parameters and their relative contribution to the total variability in the data explained by the selected model for all wavenumbers. Out of 14 parameters explored, there are 4 critical parameters for which their main and cross-term effects drive the uncertainty of the calibration blackbody radiance. They are 1) calibration blackbody emissivity and 2) its uncertainty, and 3) calibration blackbody temperature and 4) its uncertainty. These 4 main effects alone contribute at least 83% to the total variability explained by the model. The other 17% of the total variability can be explained by their cross-term effects. Deending on wavenumbers, each effect contributes differently to the total variability. For example, at 200 wavenumber, the highest two contributors are U_Tcbb and Ecbb, while at other wavenumbers, the highest two are U_Tcbb and Tcbb. We also observe that at 2000 wavenumber, a three-factor cross-term, Tcbb*U_Tcbb* U_Ecbb, is significant, while this cross-term is not significant at other wavenumbers.

Up to this point, we have used computer simulation to estimate uncertainty of the calibration blackbody radiance. We can also use the propagation of uncertainty law as described in Taylor and Kuyatt [11], Gertsbakh [12], and Coleman and Steele [13] to calculate uncertainty. Applying the propagation of uncertainty to Equation (1), assuming that all cross terms are negligible, gives

(6)

where

Figure 7. Critical parameters and their relative contribution to the total variability in the data explained by the selected model.

The quality of uncertainty estimates from Equation (6) depends on the validity of the assumption that the uncertainty contributors are independent (i.e., the cross terms are insignificant). On the other hand, the quality of uncertainty estimates from simulation depends on the quality of random numbers and sufficient number of simulation runs, which has been demonstrated earlier to have good quality.

We estimate the uncertainties of the calibration blackbody using Equation (6) with the same parameter settings as in those from 138 simulated experimental runs, and from 138 simulated confirmation runs. We also include additional 523 experimental runs for the same parameter ranges to explore uncertainties obtained from the 2 methods. Figure 8(a) provides histograms of 799 (138 + 138 + 523) differences in uncertainty between the two approaches. Specifically,

(7)

Based on our observation, the differences have high tendency to be zero, but they may not follow a Normal distribution because of the very long tail on the left. Regardless of the distributions of the differences, the mean

Figure 8. Analysis of differences in uncertainty of blackbody radiances obtained by simulation and Uncertainty Propagation methods.

differences will follow the Normal distribution according to the Central Limit Theorem. Figure 8(b) shows the 95% confidence intervals of the mean differences. All intervals do not cover zero. Therefore, on average the computer simulation and the propagation of uncertainty methods produce different uncertainties in the calibration blackbody radiances for all wavenumbers. Because the mean differences are negative, on average the propagation of uncertainty method estimates higher uncertainties than those from the computer simulation approach. We suspect that the cross terms excluded in Equation (6) must be negative on average.

We observe from our data (not shown) that radiance uncertainties vary depending on wavenumbers, regardless which method is used. Uncertainties are smaller for wavenumbers 200 and 2000 cm^{–1}, because their radiances are smaller. In Figure 8(b), the interval widths of the mean differences vary depending on wavenumbers, with tighter widths for wavenumbers 200 and 2000 cm^{–1}. This does not imply that their mean differences are more predictable than those of other wavenumbers. Rather their tighter widths may in fact be proportional to the magnitudes of the absolute radiances. Therefore, we normalize all differences by their associated relative uncertainty from simulation (Uncertainty Difference/U (Monte Carlo). Figure 9 shows similar analyses as in Figure 8, but for normalized differences.

The normalized differences (in %) have a high tendency to be zero. On average, the normalized differences are not zero, but are negative. In the worst case across all 5 wavenumbers, the mean normalized differences can be as high as –1.2%. On average, the cross terms in the propagation of uncertainty method must be negative. The interval widths of the mean normalized differences are now consistent across wavenumbers.

4. Conclusions and Future Works

The on-orbit blackbody calibration source of the CLARREO IR Suite is one of the most critical components in obtaining accurate CLARREO IR measurements. To

Figure 9. Analysis of normalized differences in uncertainty of blackbody radiances obtained by simulation and Uncertainty Propagation methods.

achieve such accuracy, CLARREO relies on highly accurate knowledge of the spectral radiance of the calibration blackbody. This study focuses on determining which parameters in the spectral radiance equation of the calibration blackbody are critical to the blackbody accuracy. Based on the spectral radiance equation used in this study, fourteen parameters were identified and explored. The Design of Experiments (DOE) method was applied to systematically set up an experiment to provide parameter settings and number of runs in order to explore these 14 parameters. The experiment was done by computer simulation to estimate the total radiance uncertainty. The sensitivity of number of simulations to simulation error was explored and used to determine the number of simulations.

All explored parameters’ ranges were based on the current known specifications available at time of this study. A 128^{th} fraction of the 2^{14} factorial design with 10 center points (i.e., + 10 center points) was chosen for this study. It is a resolution IV design, in which no main effect is aliased with any other main effect or cross-term effect, but cross-term effects are aliased with each other. This design was sufficient for the screening purpose to determine which of these parameters were critical to the total radiance uncertainty of the calibration blackbody. The parsimonious models based on a second-order Taylor series expansion were fit based on the experimental uncertainty data. Another 128^{th} fraction of the 2^{14} factorial design with 10 center points were run and used as confirmation points to check the models for predictability. The best models were then chosen based on best statistics of fitting and predicting errors.

Within the explored ranges, only 4 out of 14 parameters were discovered to be critical and should be designed, manufactured, and controlled carefully. They were emissivity of blackbody, temperature of blackbody, uncertainty of blackbody emissivity, and uncertainty of blackbody temperature. Emissivities and temperatures, and their associated uncertainties, for other surfaces surrounding the blackbody were less critical to the total blackbody uncertainty. The uncertainties obtained by simulation were also compared to those from the propagation of error method. The two methods produced statistically different uncertainties and the differences were suspected to be due to the first-order assumption in the propagation of uncertainty. Nevertheless, the differences were small and were considered to be not practically different.

Although the system under the study is simple and has been well studied in literature, we would like to emphasize that our intention is to demonstrate the DOE application with the well understood system before applying it to the system of CLARREO IR suite. The total combined uncertainty of the IR Suite will be affected by the individual uncertainties of a number of contributing components. There are a total of 47 parameters that contribute to the total combined uncertainty. Because the CLARREO IR measurement accuracy requirement is very stringent, a follow-up study has been planned to apply the DOE in systematically setting up an experiment to explore the effects of all 47 parameters. It is our believe that the DOE method will help identifying critical parameters to the total IR measurement uncertainty that need to be effectively and efficiently designed to meet the instrument accuracy requirement within the limited resources.

5. Acknowledgements

We would like to thank Dave G. Johnson and Alan D. Little at NASA Langley Research Center for their valuable perspectives for this work.

Nomenclature

Wavenumbers: 200, 600, 1000, 1400, and 2000 cm^{−}^{1}

Planck Constant = 6.62606896 × 10^{−34} Js [14]

Speed of light in a vacuum = 2.99792458 × 10^{8 }m/s [14]

Boltzmann constant = 1.3806504 × 10^{−23} JK^{−1} [14]

Temperature of calibration blackbody (K)

Temperature of heater (K)

Temperature of FTS (K)

Radiance of calibration blackbody as a function of wavenumber and its temperature (W·m^{−2}·sr^{−1}·(cm^{−1})^{ −1})

Radiance calculated from Planck’s equation for calibration blackbody as a function of wavenumber and its temperature (W·m^{−2}·sr^{−1}·(cm^{−1})^{ −1})

Radiance calculated from Planck’s equation for heater as a function of wavenumber and its temperature (W·m^{−2}·sr^{−1}·(cm^{−1})^{ −1})

Radiance calculated from Planck’s equation for FTS as a function of wavenumber and its temperature (W·m^{−2}·sr^{−1}·(cm^{−1})^{ −1})

Emissivity of calibration blackbody

Emissivity of heater

Emissivity of FTS

View factor of the heater, as seen from the blackbody aperture

Reflectance of calibration blackbody (

Uncertainty in the calibration blackbody radiance (W·m^{−2}·sr^{−1}·(cm^{−1})^{ −1})

Uncertainty in the calibration blackbody emissivity

Uncertainty in the calibration blackbody Planck radiance, which is a function of blackbody temperature (W·m^{−2}·sr^{−1}·(cm^{−1})^{ −1})

Uncertainty in the heater emissivity

Uncertainty in the heater Planck radiance, which is a function of heater temperature (W·m^{−2}·sr^{−1}·(cm^{−1})^{ −1})

Uncertainty in the view factor of the heater, as seen from the blackbody aperture

uncertainty in the FTS emissivity

Uncertainty in the FTS Planck radiance, which is a function of FTS temperature (W·m^{−2}·sr^{−1}·(cm^{−1})^{ −1})

Uncertainty in the calibration blackbody temperature (K)

Uncertainty in the heater temperature (K)

Uncertainty in the FTS temperature (K)

The regression coefficients which are estimated from computer simulated experiment

The random fitting error

Spectral radiance of calibration blackbody obtained from simulation as a function of wavenumber and its temperature (W·m^{−2}·sr^{−1}·(cm^{−1})^{ −1})

Mean radiance of the calibration blackbody obtained from simulation as a function of wavenumber and its temperature (W·m^{−2}·sr^{−1}·(cm^{−1})^{ −1})

Number of simulation runs

Number of confirmation runs

Uncertainty obtained from Monte Carlo function for i^{th} confirmation run

Predicted uncertainty obtained from the model for the i^{th} confirmation run

Conflicts of Interest

The authors declare no conflicts of interest.

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