Formulation of the System of Isohydric Solutions


The isohydricity (pH constancy) as the property referred to mixtures of acids or bases, is illustrated on a simple example of the solutions: HL (C0, mol/L) and HL (C mol/L) mixed according to titrimetric mode (pH titration). A new derivation of the Michalowski formula C0=C+C2·10PK1 expressing this property is presented, and its applicability for determination of pK1 = – logK1 value is indicated. The principle of the isohydric method of pK1 determination is also outlined.

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Michałowski, T. and G. Asuero, A. (2012) Formulation of the System of Isohydric Solutions. Journal of Analytical Sciences, Methods and Instrumentation, 2, 1-4. doi: 10.4236/jasmi.2012.21001.

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The authors declare no conflicts of interest.


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