1. Introduction
In 1924, De Broglie put the hypothesis that particles should exhibit wave and particle properties simultaneously . Classical mechanics applies specific mathematical equations to describe the motion of particles and wave in separate fashion, so classical mechanics equations are inadequate to implement De Broglie hypothesis, a new mathematical formulas are required to express the new proposed concept De Broglie interpreted his hypothesis by postulating two relations the first one express the energy of the moving particle in terms of the frequency of the claimed associated wave and the second relation express the momentum of a moving particle in terms of the wavelength of the claimed associated wave . The postulated relations given by De Broglie based on the mathematical formulas were given to explain the interaction of light with matter which is known as photoelectric effect, the physicist Albert Einstein assumed that light wave behaves like particles called photons, he proposed mathematical formulas calculate the required amount of photon’s energy in order to release the constrained electrons from the surface of the matter. De Broglie’s relations have been verified experimentally more than once. These proposed mathematical formulas were not obtained from classical mechanics considerations or any mathematical derivation method. Later on, Schrodinger set up a wave equation to express the quantum dynamics of a moving particle in the form of a partial differential equation which is satisfied only by complex wave functions. In this article a mathematical derivation for De Broglie’s relations is given in accordance with classical mechanics equations in addition to a new equation introduced to represents the magnitude of the complementary energy, as well as Schrodinger’s amplitude equation is regarded for sake of simplification and purpose of clearness to achieve a successful convergence process of the classical approach to the quantum approach, the results obtained from convergence process of the classical approach to the quantum approach are implemented to deduce solutions for the general format of Schrodinger’s time dependent equation, consequently a link between classical mechanics and quantum theory established.
2. Applied Methodology
2.1. Particle Potential Energy-Complementary Energy
The total energy of a system of N moving particles
is defined as the summation of the particles kinetic energy
and the total potential energy V
So that
(1)
Equation (1) is rewritten as
(2)
in which
,
,
,
where
is an energy distribution coefficient and
is a complementary energy term. The physical significance for
and
is given in section 4.
and
are related to the particle total energy
and the total energy of the system of particles
by
,
(3)
and
are real functions, i.e.
and
where
is the set of real numbers.
Since
then
,
(4)
Equation (4) represents the complementary energy concept which interprets the impact of a system of particles on each particle in the system. The left hand side of Equation (4) gives the value of the complementary energy for particle j whereas the right hand side is the summation of the complementary energies for the rest N − 1 particles.
Substituting in Equation (2) from Equation (3) and writing
,
,
(5)
in which
is a velocity parameter, yields the expressions for the total potential energy and the particle potential energy as
,
,
(2.1)
The above relation expresses a general format for any potential energy for any moving particle independent completely of the kind of the field it represents.
2.2. Particle Velocities
Expressing Equation (5) as
,
Gives the particle velocity quadratic equation as
,
(6)
The roots of Equation (6) are
given by
,
The roots of Equation (6) result in the existence of two available velocities. Two classical interpretations are given, the first classical interpretation of the above relation is a pair particle velocities prevail along the particle path trajectory. The second classical interpretation of the above relation is one speed for transitional motion and another speed for rotational motion. The quantum interpretation of the above relation is given in detail in section 2.7.
2.3. Particle Mean Velocity
The particle mean velocity,
, is expressed as
,
Expressing the roots of Equation (6) as
,
(7)
in which
,
,
(7.1)
gives
and
to be the deviation from the mean velocity; given the term deviation velocity of particle j.
is substituted by
in all further equations.
A proof that the value of the mean velocity is constant and is given as follows
Rewriting Equation (7) as
,
,
(7.2)
Equation (7.2) is deduced by expanding
, into Taylor series around an extremal point,
, and substituting
(the condition for extremum) in the second term. The terms above the second order are null. The condition for extremum
indicates that if the velocity of the moving particle j reaches the value
then it does not contribute to its energy
, i.e. the moving particle is in a collision free motion or in a perfect collision motion (no change in energy due collision) or both.
2.4. Complementary Energy Value (
)-(Particle-Wave Object)
The explanation of Equation (4) whereas the summation in the right side of the equation calculates the net collective effect of N − 1 particles upon a single particle, based on the particle’s location and particle’s status whether the effect is due to direct contact as in case of collision or via remote influence through an existing field in the space. The left hand side of Equation (4) gives the value of the complementary energy for particle j. For a particle near the surface of the material the right hand side summation represents the required amount of work done by the rest N − 1 particles to pull back the particle away from the surface of the material. The complementary energy can be understood as the potential energy at the boundary of the material which prevents each particle from escaping from the boundary of the system (evaporates).
From Equation (3) in section 2.1 the total energy of particle j is written
In special case
Equation (3) becomes
Substituting in Equation (3) with the kinetic energy and the potential energy of particle j gets
According to the argument given above the value of the complementary energy
is independent form the potential energy value
, so in case the potential energy
of particle j vanishes at certain positions. i.e.
values halt contributing to the total energy of particle j, the complementary energy
still contributing to the total energy of particle j then the above equation is written
where
can be considered as potential energy,
So the general format for any potential energy of a particle j given by Equation (2.1) is adequate to represent the value of the complementary energy of particle j. For a particle j its complementary energy is expressed by the equation
(2.2)
The probabilistic formulation of the quantum theory indicates an assumption of the impossibility to measure an exact value for the velocity but you can measure a probable value some time called expected value or average value,
represents the measured value of the velocity for a moving particle j. Another aspect of the quantum formulation is an assumption of the presence of an associated wave to any moving particle [1] in other word the associated wave adheres the moving particle composing a particle-wave object. The adherence of the wave to the moving particle enables the wave to borrow one of the available speeds of the particle to be the speed of the associated wave, consequently
can represent the speed of the associated wave.
is a representation of complementary energy for the particle-wave object which is a bi-natural for both a moving particle and moving wave and Equation (2.2) is a particle-wave equation. The determination of the complementary energy
requires two velocities values, one for a particle and another for a wave, so
is a potential energy of a combined particle-wave object. Another application for
is to express the motion of a moving object in a continuous medium (fluid, gas, electric field, magnetic field, gravitational field.) by considering the average velocity is the speed of the wave caused in the medium due to the motion of the object in the medium with one of its available speeds. The potential energy replaces the complementary energy in case of single object.
2.5. De Broglie’s Relations-Plank’s Constant (h)
Tiny particles such as electrons, protons, atoms, etc., their velocity value can reach the speed of light or even close to the speed of light, so c the speed of light could be considered an available speed for the tiny particles.
The substitution with the value of the speed of light c in the particle-wave equation for a tiny particle j i.e.
gives
Since the speed of light represents a moving wave of frequency ν and wavelength λ satisfying the relation
the above relation is rewritten as
(8)
Where
(8.1)
(8.2)
In section 2.3 a proof is given indicating that
is a constant extremal value for the energy function
, since
and λ are both constant values this result that the value of h given by relation (8.1) is a constant value which is Plank’s constant [1] [2].
Relation (8.2) is a reformulation of relation (8.1) indicating that the momentum of the wave-particle object is equal to the momentum on a perfect path i.e. the particle-wave object moves as same way like a free motion particle (review section 2.3) [1] [2].
Relation (8) is an expression representing the complementary energy of a moving particle j as a multiplication of a wave frequency ν by a constant value h. Relations (8) and (8.2) are obtained by De Broglies using intuitive empirical method [1] [2].
2.6. Wave Packet-Energy Quantization
In this section the value of the second velocity
is considered to be the rotating velocity for particle j. Using the particle mean velocity equation given in section 2.3 the second velocity with a magnitude
is expressed as
(9)
Since the angular velocity
and
is the distance from the rotating center then, Equation (9) can be rewritten as
where
, is the first wave frequency obtained in the previous section
The above equation in terms of the wave variables is written as
(9.1)
The following are the conversion relations from particle variables to the wave variables:
, is the magnitude of the wave vector given by
, is the phase velocity given by
, is the wave length of the associated wave
In case
,
, where
is a natural number.
In case
,
the magnitude of the wave vector
becomes
which is well known result obtained by quantum method [1].
In case the rotating center inside the particle or on its boundary the rotation is considered spinning, if the rotating center outside the particle the rotation is considered revolving. Reflecting and refracting (bending) of particle-wave object are considered a kind of rotation.
Integrating Equation (9.1) gives
(9.2)
Equation (9.2) is valid in the interval,
,
, and describing the phase of a plane wave propagating along the particle displacement direction sj .
Substituting from (8.1) into the phase velocity relation gives,
, so a dispersion takes place, each velocity generates a corresponding wave with the same wave length λ and two frequencies
related by the relation
the addition of the two waves creates a wave packet [1].
Substituting in Equation (8.2) with the wave length in terms of the distance from the rotating center gives
From Equation (7.2), Equation (8.2), and the above relation the energy of a particle j moving with speed
is
The above formula is known as the energy quantization formula obtained by the methods of quantum mechanics [1] [2].
2.7. Schrodinger’s Formulation
Schrodinger’s formulation describes the motion of moving particles using a wave equation which is a partial differential equation its solution is a wave function . The square value of the wave function results the corresponding probability value for the parameters of the moving particle such as speed, energy, and displacement . In order to switch the deterministic relations to be expressed in probabilistic format the following procedure adopted to achieve successful convergence process.
From section 2.3 the particle mean velocity,
, is expressed as
,
The particle mean velocity relation can be interpreted as follows the probability of the first speed
is
and the probability of the second speed
is
then
is the value of expected speed and that is the quantum interpretation of the particle mean velocity relation. Instead of using the equal fixed probabilities value
for each speed which is a special case, a variable functions can replace the equal fixed probabilities value
. There are two available sets of functions can fully fill the replacing purpose explained previously. The first set is trigonometric functions
where
. The second set is hyperbolic functions
where
in this article the trigonometric functions used to represent the required probabilities.
From section 2.3
,
(7)
in which
,
,
(7.1)
Figure 1 is the geometrical representation of Equation (7.1) is a right triangle its sides
,
, and
. It will be shown the fundamental contribution of the three sides of the triangle as well as the angel
in determining and finding the appropriate structure of the wave function and the wave vector as a solution for Schrodinger’s equation.
Figure 1. Geometrical representation of Equation (7.1).
From Figure 1 the geometrical representation of Equation (7.1)
is written as follows:
Substituting
where
is the displacement of particle j. Specifying the value of
requires three steps, first step is expanding
in power series and second step is equating the expansion with the above relation and third step is adjusting the
ratio to match the value of
. The previous steps will be implemented as follows:
Comparing the left side with right side of the above equation results.
Substituting with
value into
gives.
A wave function
for a particle j is written as:
The same wave function
for a particle j can be obtained also by solving the Schrodinger’s amplitude equation given as [1] [3]:
or
where
The wave function
is the solution of the above Schrodinger’s equation after applying the boundary conditions, to describe the motion of a particle j enclosed in a potential well where the potential energy vanishes inside the well, Also the wave function
is the solution of the problem of passage of particles through the potential barrier. Tunnel effect [1] [3].
Substituting in
with
and From Figure1 the geometrical representation of Equation (7.1)
is written as follows
From section (2.3) the relation between the total energy of particle j
and its potential energy
is given as
,
,
(7.2)
The above formula is valid for values of
and
satisfying the relation
.
which leads to the quadratic equation
the same for
we get the quadratic equation
.
From the expansion of
in power series and the above formula and adjusting the
ratio obtained from Figure 1 the geometrical representation of Equation (7.1) to match
value we get
Comparing the left side with right side of the above equation results
A wave function
for a particle j is written as
The same wave function
for a particle j can be obtained also by solving the Schrodinger’s amplitude equation given as [1].
where
The wave function
is the solution of the above Schrodinger’s equation after applying the boundary conditions, to describe the motion of a particle j in a region where the potential energy has a value
[1].
2.8. Solutions for Time Dependent Schrodinger’s Equation
In this section proofs are given for some wave functions to be solutions for time dependent Schrodinger’s equation based on the results obtained in the previous section.
Some relations required to derive the proposed solutions for time dependent Schrodinger’s equation. The purpose of these relations is to transform the particle parameters to the wave parameters to be adequate to Schrodinger’s equation.
We have the deviation
is given as follows
,
,
(7.1)
From the previous section we have
Using the relation (7.2) and the above relation we get
From the above relations
is rewritten as follows
Now we write the functions
and
in terms of
and
from the previous section and the substitution with value of
given above we get
Using the equality
and multiplying by i we get
,
One dimension functions to be solutions for time dependent Schrodinger’s equation
Is a solution for time dependent Schrodinger’s equation given as [1]
Proof
The first term on the right hand side
The left hand side
Let the frequency
in case the potential energy
the frequency becomes
comparing this result with De Broglie’s relations obtained in section (2.5)
using the relation
we get
is a solution for time dependent Schrodinger’s equation.
Proof
The first term on the right hand side
The left hand side
Proof
The first term on the right hand side
The left hand side
Proof
The first term on the right hand side
The left hand side
Three dimensions functions to be solutions for time dependent Schrodinger’s equation
where
Suggested values for
or
or
is a solution for time dependent Schrodinger’s equation given as [1] [4].
Proof
The first term on the right hand side
Continue the proof the same steps as the proof in one dimension function.
The argument
can be rewritten
where
is the radius vector with components
and
is the wave vector with components
their dot product is given by
,
is the angel between the two vectors
and
.
is a wave function could be used to interpret the spinning motion of the particle.
The following functions are solutions for time dependent Schrodinger’s equation the proof steps as the same proofs given above
where
,
where
where
3. Conclusions
The derivation for De Broglie’s relations, the energy quantization formula, and the wave functions of a solution of Schrodinger’s equation implies the consistent accommodation of the deterministic approach and the probabilistic approach, which led to a successful merge of the classical mechanics and quantum theory and erased completely the boundaries between the two approaches which is the basic purpose for this article.
The particle- wave equation indicates the possibility of the existence of an associated wave to any moving object, A necessary proportional constant is required to be substituted in the particle- wave equation in order to link the particle’s parameters to the wave parameters, Planck’s constant is the adequate constant in case of tiny particles its substitution in the particle- wave equation results De Broglie’s relations. Further investigation is required to apply the particle-wave equation to all moving masses with different sizes, not only tiny particles.
The De Broglie’s wave is a physical wave and the wave function solution of Schrodinger’s equation is a mathematical wave to be used to calculate the probabilities of particle’s parameters. The relation between the two waves can be obtained from the deduced formulas in this article.
The solution for time dependent Schrodinger’s equation in three dimensions shows a wave function could be used to interpret the spinning motion of the particles.
The merging process between particle’s parameters (displacement, velocity, momentum, energy) and wave parameters (frequency, wave length, wave vector, speed) required intermediate parameters (complementary energy, mean velocity, deviation from mean velocity) to successfully achieve the convergence process. The intermediate parameters could be used to make convenient calculations for both particle’s parameters and wave parameters.
The wave nature of the complementary energy is a required necessity to enable the interaction between particles to occur and transmission of energy to be achieved. The communication of a single particle with the rest of the universe is impossible without an associated wave to each particle.
This is the last conclusion and the most interesting which is the motion of the particle-wave object can be represented by the smallest geometric unit a triangle, whose sides represent the particle’s parameters and its angels represent the wave parameters. The analogy between the motion of the particle-wave object and the triangle gives a new deeper understanding of the nature of the quantum phenomena from a geometrical perspective, as well as the correlation between the particle parameters and the wave parameters. The geometrical formulation of the quantum phenomena leads to a fact that solving Schrodinger’s equation is like solving a triangle in trigonometry or plane geometry. Further investigations are required in order to unveil the geometrical foundation of the quantum theory.
4. Discussion
If there is an object that does not radiate thermal energy, magnetic field or electric field it does not mean on the macroscopic and microscopic scale there is no activity for that reason the summation of (
) is zero at the same time each particle has value for(
). It is a mathematical method to express equilibrium of the object without neglecting its internal reactions. It is analogous to some extent to the concept of internal energy in thermodynamics but varies.
The energy distribution coefficient it is the magnitude of the share (quota, portion) of the total energy of the particle in the total energy of the system. which means that the total energy of the system is distributed among the particles.
A definition for the complementary energy is the energy connecting the matter with radiation. The radiation is a wave natured.
The title of the article “A link merges classical mechanics to quantum theory (Part I)”, the link is a mathematical derivation process, starts with expressing the total energy of N moving particles and ends with derivation of De Broglie’s relations and wave functions solution for Schrodinger’s equation which shows the acquaintance with classical mechanics is incomplete, there still unknown aspects, future parts will shed the light on those aspects with collaboration with quantum theory.