Principles of Quantum Mechanics and Laws of Wave Optics from One Mathematical Formula ()
1. Introduction
From the find that a function
$f\left(\stackrel{\to}{r}\right)$ may be expanded into a series of functions
${\text{e}}^{i\stackrel{\to}{k}\stackrel{\to}{r}}$ with coefficients equal to
${\left(2\pi \right)}^{3/2}$ multiplies the Fourier transform
$\stackrel{\u02dc}{f}\left(\stackrel{\to}{k}\right)$ of
$f\left(\stackrel{\to}{r}\right)$ we arrive to obtain that a particle moving with celerity
${\stackrel{\to}{v}}_{\text{0}}$, momentum
${\stackrel{\to}{p}}_{\text{0}}$ creates a wave, confirming the wave-particle duality principle conceived by Planck and Einstein in 1900-1905. Moreover we obtain that
${p}_{0}$ is inversely proportional to the wavelength of this wave conformed with the hypothesis of de Broglie and that the particle’s energy is proportional to the wave’s frequency conformed with the proposition of Planck. The coefficient of proportionality is then identifiable with the Planck’s constant h.
The Exclusion principle of Pauli may be explained by the assimilation of two particles having the same momentum and the same position with only one having double momentum so that the de Broglie wavelength is divided by two which is a paradox.
From the fact that
$\delta \left(\stackrel{\to}{p}-{\stackrel{\to}{p}}_{0}\right)$ represents the momentum-representation of the state
$|{\stackrel{\to}{p}}_{\text{0}}\rangle $ and
${\left(2\pi \right)}^{-\frac{3}{2}}{\text{e}}^{i\text{\hspace{0.05em}}{\hslash}^{-1}{\stackrel{\to}{p}}_{\text{0}}\stackrel{\to}{r}}$ its position-representation we obtain the relation
$\langle \stackrel{\to}{k}|=FT\langle \stackrel{\to}{r}|$ where
$\stackrel{\to}{\mathrm{p}}=\hslash \stackrel{\to}{\mathrm{k}}$. These relations lead to the canonical commutation relations
$\left[{\stackrel{^}{r}}_{j},{\stackrel{^}{p}}_{l}\right]=i\hslash {\delta}_{jl}\stackrel{^}{I}$,
$E=i\hslash {\partial}_{t}$ of Born which in turn lead to the well known Schrӧdinger equations. Utilizing the relation
$\langle \stackrel{\to}{k}|=FT\langle \stackrel{\to}{r}|$ we see also that the Heisenberg’s incertitude relation
$\Delta x\Delta p>\hslash /2$ is a matter of Fourier transform relation between the rectangular function
${a}^{-1}\left(H\left(k+a\right)-H\left(k-a\right)\right)$ and the function
$\mathrm{sin}\left(ax\right)/\left(ax\right)$,
$H\left(x\right)$ being the Heaviside function.
Consider an atom having a discrete spectrum of states each having a value of energy
${E}_{j}$. It is represented by
$\langle E|\alpha \rangle ={\displaystyle \underset{j=1}{\overset{N}{\sum}}\delta \left(E-{E}_{j}\right)}$. By searching the maximum values of
${\left|\langle t|\alpha \rangle \right|}^{2}$ we see that from time to time there have emission/absorption of a wave having frequency
${\nu}_{jk}={h}^{-1}\left({E}_{k}-{E}_{j}\right)$ conformed with the theory of Bohr. Besides we obtain permutation relations between functions of creation and annihilation operators in second quantization.
By the same formula giving quantum mechanics’ principles we realize that the product of a wave
${\text{e}}^{i{\stackrel{\to}{k}}_{\text{0}}\stackrel{\to}{r}}$ and an object described by a function
$f\left(\stackrel{\to}{r}\right)$ is a sum over
${\text{e}}^{i\stackrel{\to}{k}\stackrel{\to}{r}}$ with coefficients equal to
${\left(2\pi \right)}^{3/2}\stackrel{\u02dc}{f}\left(\stackrel{\to}{k}-{\stackrel{\to}{k}}_{0}\right)$. This opens a simple way to calculate the amplitude of diffraction of a wave by a 3D object such as a semi-space which leads to the Descartes, Snell’s laws, Fresnel equations, then by a set of identical objects having different geometric forms such as plane which leads to the Braag’s formula, pyramid, sphere, etc.
Details of the finds are explained successively in the following paragraphs.
2. Obtaining Principles and Hypothesis of Quantum Mechanics
2.1. The Wave-Particle Duality Principle
Let us expand a function
$f\left(\stackrel{\to}{r}\right)$ having Fourier transform on a basis of exponential functions
$f\left(\stackrel{\to}{r}\right)={\displaystyle \underset{\stackrel{\to}{k}}{\sum}c\left(\stackrel{\to}{k}\right){\text{e}}^{i\stackrel{\to}{k}\stackrel{\to}{r}}}$ (2.1.1)
where
$\stackrel{\to}{k}$ belongs to an infinite set of vectors obeying the condition that the scalar product
$\stackrel{\to}{k}\stackrel{\to}{r}$ is dimensionless for the following relation to hold
${\text{e}}^{i\stackrel{\to}{k}\stackrel{\to}{r}}=1\cdot {\text{e}}^{i\stackrel{\to}{k}\stackrel{\to}{r}}={\text{e}}^{i\left(\stackrel{\to}{k}\stackrel{\to}{r}+2\pi \right)}$ (2.1.2)
Under such condition we may write
$\begin{array}{c}{\displaystyle \underset{{R}^{3}}{\int}{\text{e}}^{-i{\stackrel{\to}{k}}_{\text{0}}\stackrel{\to}{r}}f\left(\stackrel{\to}{r}\right)\text{d}\stackrel{\to}{r}}={\displaystyle \underset{\stackrel{\to}{k}}{\sum}c\left(\stackrel{\to}{k}\right)}{\displaystyle \underset{{R}^{3}}{\int}{\text{e}}^{-i{\stackrel{\to}{k}}_{\text{0}}\stackrel{\to}{r}}{\text{e}}^{i\stackrel{\to}{k}\stackrel{\to}{r}}}\text{d}\stackrel{\to}{r}\\ ={\left(2\pi \right)}^{3}{\displaystyle \underset{\stackrel{\to}{k}}{\sum}c\left(\stackrel{\to}{k}\right)\delta \left(\stackrel{\to}{k}-{\stackrel{\to}{k}}_{0}\right)}\\ ={\left(2\pi \right)}^{3}c\left({\stackrel{\to}{k}}_{0}\right)\end{array}$ (2.1.3)
so that we may state the theorem:
“Any function
$f\left(\stackrel{\to}{r}\right)$ having Fourier transform may be written under the form
$f\left(\stackrel{\to}{r}\right)={\left(2\pi \right)}^{3/2}{\displaystyle \underset{\stackrel{\to}{k}}{\sum}\stackrel{\u02dc}{f}\left(\stackrel{\to}{k}\right){\text{e}}^{i\stackrel{\to}{k}\stackrel{\to}{r}}}$ (2.1.4)
where
$\stackrel{\to}{k}\stackrel{\to}{r}$ is dimensionless and
$\stackrel{\u02dc}{f}\left(\stackrel{\to}{k}\right)$ is the Fourier transform of
$f(r\to )$
$\stackrel{\u02dc}{f}\left(\stackrel{\to}{k}\right)=FTf\left(\stackrel{\xaf}{r}\right)={\left(2\pi \right)}^{-3/2}{\displaystyle \underset{{R}^{3}}{\int}{\text{e}}^{-i\stackrel{\to}{k}\stackrel{\to}{r}}f\left(\stackrel{\to}{r}\right)\text{d}\stackrel{\to}{r}}$ (2.1.5)
Now from the well known formulas
$f\left(x+a\right)={\text{e}}^{a{\partial}_{x}}f\left(x\right)$ (2.1.6)
$FT{D}_{x}f\left(x\right)=FT{f}^{\prime}\left(x\right)=ikFTf\left(x\right)$ (2.1.7)
we get
$FT\delta \left(x-a\right)=FT{\text{e}}^{-a{D}_{x}}\delta \left(x\right)={\text{e}}^{-iak}FT\delta \left(x\right)={\text{e}}^{-iak}{\left(2\pi \right)}^{-1/2}$ (2.1.8)
so that by (2.1.4)
$\delta \left(\stackrel{\to}{r}-{\stackrel{\to}{r}}_{0}\right)={\displaystyle \underset{\stackrel{\to}{k}}{\sum}{\text{e}}^{-i{\stackrel{\to}{k}}_{\text{0}}\stackrel{\to}{r}}{\text{e}}^{i\stackrel{\to}{k}\stackrel{\to}{r}}}={\displaystyle \underset{\stackrel{\to}{k}}{\sum}{\text{e}}^{i\stackrel{\to}{k}\left(\stackrel{\to}{r}-{\stackrel{\to}{r}}_{0}\right)}}$ (2.1.9)
Consider a particle situated at the position
${\stackrel{\to}{r}}_{0}$ and having a mass m and a constant celerity
${\stackrel{\to}{v}}_{\text{0}}$. Defining
${\stackrel{\to}{k}}_{0}=\frac{2\pi}{{\lambda}_{0}}\frac{{\stackrel{\to}{v}}_{\text{0}}}{{\nu}_{\text{0}}}=\frac{2\pi}{{\lambda}_{0}}\stackrel{\to}{n}$ (2.1.10)
where
${\lambda}_{0}$ has the dimension of a length as it must be for
${\stackrel{\to}{k}}_{\text{0}}\stackrel{\to}{r}$ to be dimensionless we see from (2.1.9) that the formula
$\delta \left(\stackrel{\to}{k}-{\stackrel{\to}{k}}_{0}\right)\delta \left(\stackrel{\to}{r}-{\stackrel{\to}{r}}_{0}\right)={\text{e}}^{i{\stackrel{\to}{k}}_{0}\left(\stackrel{\to}{r}-{\stackrel{\to}{r}}_{0}\right)}=\mathrm{exp}i\left(\frac{2\pi}{{\lambda}_{\text{0}}}\left(\stackrel{\to}{r}-{\stackrel{\to}{r}}_{0}\right)\stackrel{\to}{n}\right)$ (2.1.11)
represents at the same time this particle and a wave. Thank to the property
${\text{e}}^{\pm i2\pi}=1$ this wave has a wavelength
${\lambda}_{0}$ and consequently a period
${T}_{0}={\lambda}_{0}/{v}_{0}$ (2.1.12)
The wave function of this particle is then within a multiplicative constant
${\Psi}_{0}\left(\stackrel{\to}{r},t\right)=A\mathrm{exp}i\left({\stackrel{\to}{k}}_{\text{0}}\left(\stackrel{\to}{r}-{\stackrel{\to}{r}}_{0}\right)-\frac{2\pi}{{T}_{0}}t\right)$ (2.1.13)
This is the insight of the principle of wave-particle duality conceived by Planck in 1900 [1] and Einstein in 1905 [2]. It constitutes the first quantization of quantum mechanics.
2.2. The de Broglie Particle-Wave Hypothesis and the Planck-Einstein Relation
As
$\stackrel{\to}{k}\text{//}\stackrel{\to}{v}\text{//}\stackrel{\to}{p}=m\stackrel{\to}{v}$ (2.2.1)
we may define a universal constant
$\theta $ having dimension
$M{L}^{2}{T}^{-1}$ then link
$\stackrel{\to}{p}$ with
$\stackrel{\to}{k}$ by the relation
$\stackrel{\to}{p}=\theta \stackrel{\to}{k}=\theta \frac{2\pi}{\lambda}\frac{\stackrel{\to}{v}}{\nu}=\theta \frac{2\pi}{\lambda}\stackrel{\to}{n}$ (2.2.2)
in order to get the form of the relation between momentum and associated wavelength
$p=\theta k=\theta \frac{2\pi}{\lambda}$ (2.2.3)
in accordance with the hypothesis proposed in 1923 by de Broglie [3].
The wave function of the considered particle may then be put under the form
${\Psi}_{0}\left(\stackrel{\to}{r},t\right)=A\mathrm{exp}i{\theta}^{-1}\left({\stackrel{\to}{p}}_{\text{0}}\left(\stackrel{\to}{r}-{\stackrel{\to}{r}}_{0}\right)-\frac{2\pi \theta}{{T}_{0}}t\right)$ (2.2.4)
By dimensional consideration we see that the quantity
$\frac{2\pi \theta}{{T}_{0}}$ is an energy that we baptize
${E}_{0}$ and propose to assimilate it with the energy of the quoted particle
${E}_{0}=\frac{2\pi \theta}{{T}_{0}}$ (2.2.5)
By comparison with the formulae of Planck-Einstein [1] [2] and de Broglie [3]
$E=\frac{h}{T}$,
$p=\frac{h}{\lambda}$ (2.2.6)
we get the identifications
$\theta =\frac{h}{2\pi}=\hslash $ (2.2.7)
$\stackrel{\to}{p}=\hslash \stackrel{\to}{k}$ (2.2.8)
and see that
$\stackrel{\to}{k}$ is the commonly called wave-vector of a wave.
From now all we say that
$\stackrel{\to}{k}$ and
$\stackrel{\to}{r}$ are Fourier transform reciprocal as so as
$\frac{2\pi}{T}={\hslash}^{-1}E$ and the time t. The Planck constant h was measured by Millikan [4] in 1916. The best current value for h is
$6.62607004\times {10}^{-34}{\text{m}}^{\text{2}}\cdot \text{kg}/\mathrm{sec}$ and is officially utilized from the date 20-05-2019 on to define the value of the kilogram.
2.3. The Pauli Exclusion Principle
A consequence of the relation (2.2.4) and the de Broglie hypothesis (2.2.6) we see that if two particles have the same value of momentum
$\stackrel{\to}{p}$ and the same position they may be assimilated to one particle with momentum
$2\stackrel{\to}{p}$ so that the dual wave must have its wavelength divided by 2. This leads to a paradox and confirms the Exclusion principle of Pauli [5]. For photons with momentum
$p=h\nu /c$ too small, two times of it is quasi equal to it so that there is no paradox, i.e. many photons may occupy one position.
2.4. Obtaining the Fourier Transform Relation between Bras
$\langle \stackrel{\to}{k}|$ and
$\langle \stackrel{\to}{r}|$
In a Hilbert space of Dirac kets and bras let according to (2.1.13)
$\langle \stackrel{\to}{r}|{\stackrel{\to}{k}}_{0}\rangle ={\left(2\pi \right)}^{-3/2}\mathrm{exp}\left(i{\stackrel{\to}{k}}_{\text{0}}\stackrel{\to}{r}\right)$ (2.4.1)
be the position-representation of a state having a definite wave-vector
${\stackrel{\to}{k}}_{\text{0}}$.
From the formula
$FT{\text{e}}^{i{\stackrel{\to}{k}}_{\text{0}}\stackrel{\to}{r}}={\left(2\pi \right)}^{-3/2}{\displaystyle \underset{{R}^{3}}{\int}{\text{e}}^{-i\left(\stackrel{\to}{k}-{\stackrel{\to}{k}}_{0}\right)\stackrel{\to}{r}}\text{d}\stackrel{\to}{r}}={\left(2\pi \right)}^{3/2}\delta \left(\stackrel{\to}{k}-{\stackrel{\to}{k}}_{0}\right)$ (2.4.2)
and (2.4.1) we have
$FT\langle \stackrel{\to}{r}|{\stackrel{\to}{k}}_{0}\rangle =FT{\left(2\pi \right)}^{-3/2}{\text{e}}^{i{\stackrel{\to}{k}}_{\text{0}}\stackrel{\to}{r}}=\delta \left(\stackrel{\to}{k}-{\stackrel{\to}{k}}_{0}\right)=\langle \stackrel{\to}{k}|{\stackrel{\to}{k}}_{0}\rangle $ (2.4.3)
so that, because
${\stackrel{\to}{k}}_{0}$ is arbitrary, we get the interesting relation
$\langle \stackrel{\to}{k}|=FT\langle \stackrel{\to}{r}|$ (2.4.4)
which gives precision to the latent idea in many researchers that there exists somehow a Fourier relation between momentum and position:
“In quantum mechanics the wave-vector bra
$\langle \stackrel{\to}{k}|$ is the Fourier transform of the position bra
$\langle \stackrel{\to}{r}|$”.
From (2.4.4) we get the relation between momentum-representation and position-representation of a state
$\langle \stackrel{\to}{k}|\Psi \rangle =FT\langle \stackrel{\to}{r}|\Psi \rangle $ (2.4.5)
2.5. The Canonical Commutation Postulated by Born
In the Hilbert space of states besides
$\stackrel{^}{X}$ and
${\stackrel{^}{P}}_{x}$ let us formally define another operator
${\stackrel{^}{D}}_{x}$
by the relation
${\stackrel{^}{D}}_{x}\stackrel{^}{X}-\stackrel{^}{X}{\stackrel{^}{D}}_{x}\equiv \stackrel{^}{I}$ (2.5.1)
where
$\stackrel{^}{I}$ is the identity operator.
Now, in the space of functions let
$\stackrel{\u2323}{X}$ be the operator of multiplication by x and
${\stackrel{\u2323}{D}}_{x}$ the derivative operator
$\stackrel{\u2323}{X}f\left(x\right)=xf\left(x\right)$ ;
${\stackrel{\u2323}{D}}_{x}f\left(x\right)={f}^{\prime}\left(x\right)$ (2.5.2)
verifying
$\left[{\stackrel{\u2323}{D}}_{x},\stackrel{\u2323}{X}\right]\equiv {\stackrel{\u2323}{D}}_{x}\stackrel{\u2323}{X}-\stackrel{\u2323}{X}{\stackrel{\u2323}{D}}_{x}\equiv \stackrel{\u2323}{I}$ (2.5.3)
We must be attentive on the fact that the operators
$\stackrel{\u2323}{X},{\stackrel{\u2323}{D}}_{x},{\stackrel{\u2323}{P}}_{x},{\stackrel{\u2323}{D}}_{p}$ act on functions and
$\stackrel{^}{X},{\stackrel{^}{D}}_{x},{\stackrel{^}{P}}_{x},{\stackrel{^}{D}}_{{p}_{x}}$ act on bras and kets.
From (2.5.1), (2.5.3) we get
$\langle x|{\stackrel{^}{D}}_{x}\stackrel{^}{X}-\stackrel{^}{X}{\stackrel{^}{D}}_{x}|{x}_{\text{'}}{}_{0}\rangle =\left({x}_{\text{'}}{}_{0}-x\right)\langle x|{\stackrel{^}{D}}_{x}|{x}_{0}\rangle =\delta \left(x-{x}_{\text{'}}{}_{0}\right)$ (2.5.4)
${\stackrel{\u2323}{D}}_{x}\left(\stackrel{\u2323}{X}-{x}_{0}\right)\delta \left(x-{x}_{\text{'}}{}_{0}\right)=0$ (2.5.5)
$\left({\stackrel{\u2323}{D}}_{x}\stackrel{\u2323}{X}-\stackrel{\u2323}{X}{\stackrel{\u2323}{D}}_{x}\right)\delta \left(x-{x}_{\text{'}}{}_{0}\right)=\left({x}_{0}-x\right){\stackrel{\u2323}{D}}_{x}\delta \left(x-{x}_{\text{'}}{}_{0}\right)=\delta \left(x-{x}_{\text{'}}{}_{0}\right)$ (2.5.6)
so that
$\langle x|{\stackrel{^}{D}}_{x}|{x}_{0}\rangle ={\stackrel{\u2323}{D}}_{x}\langle x|{x}_{0}\rangle $ (2.5.7)
Besides we have also
$\langle x|\stackrel{^}{X}|{x}_{0}\rangle =x\delta \left(x-{x}_{0}\right)=\stackrel{\u2323}{X}\langle x|{x}_{0}\rangle $ (2.5.8)
so that, as
${x}_{0}$ is arbitrary,
$\langle x|{\stackrel{^}{D}}_{x}\equiv {\stackrel{\u2323}{D}}_{x}\langle x|$ ;
$\langle x|\stackrel{^}{X}\equiv \stackrel{\u2323}{X}\text{\hspace{0.05em}}\langle x|$ (2.5.9)
The above relations associated with (2.4.4) and
$FTxf\left(x\right)={\left(2\pi \right)}^{-1/2}{\displaystyle {\int}_{-\infty}^{\infty}i{\partial}_{k}{\text{e}}^{-ikx}f\left(x\right)\text{d}x}=i{\partial}_{k}F\left(x\right)$ (2.5.9)
lead to
$\begin{array}{c}\langle k|\stackrel{^}{X}|{k}_{0}\rangle =FT\langle x|\stackrel{^}{X}|{k}_{0}\rangle =FTx\langle x|{k}_{0}\rangle \\ =i{\partial}_{k}FT\langle x|{k}_{0}\rangle =i{\partial}_{k}\langle k|{k}_{0}\rangle =\langle k|i{\stackrel{^}{D}}_{k}|{k}_{0}\rangle \end{array}$ (2.5.10)
i.e.
$\stackrel{^}{X}\equiv i{\stackrel{^}{D}}_{k}\equiv i\hslash {\stackrel{^}{D}}_{p}$ (2.5.11)
Similarly by repeating the reasoning with
${\stackrel{^}{P}}_{x},{\stackrel{^}{D}}_{{p}_{x}}$ we get
${\stackrel{^}{P}}_{x}=-i\hslash {\stackrel{^}{D}}_{x}$ (2.5.12)
Extension to 3D space gives
$\stackrel{^}{r}\equiv i{\stackrel{^}{\nabla}}_{k}\equiv i\hslash {\stackrel{^}{\nabla}}_{p}$ (2.5.13)
and finally the commutation relations
$\left[{\stackrel{^}{r}}_{j},{\stackrel{^}{p}}_{l}\right]=-i\hslash \left[{\stackrel{^}{r}}_{j},{\stackrel{^}{\nabla}}_{l}\right]=i\hslash {\delta}_{jl}\stackrel{^}{I}$ (2.5.14)
which have been called quantum conditions and postulated by Born in 1925 [6].
Similarly from the fact that
$\frac{2\pi}{T}={\hslash}^{-1}E$ and t are Fourier reciprocal we have
$E=i\hslash {\partial}_{t}$ (2.5.15)
2.6. The Schrödinger Equations
From the relations (2.5.6) we may also get an important proposition:
“The eigenvalue equation
$A\left(\stackrel{^}{X},\stackrel{^}{P}\right)|\alpha \rangle =a|\alpha \rangle $
of an arbitrary operator
$A\left(\stackrel{^}{X},\stackrel{^}{P}\right)$ leads to the differential equation for the function
$\langle x|\alpha \rangle $
$\langle x|A\left(\stackrel{^}{X},\stackrel{^}{P}\right)|\alpha \rangle =A\left(\stackrel{\u2323}{X},-i\hslash {\stackrel{\u2323}{D}}_{x}\right)\langle x|\alpha \rangle =a\langle x|\alpha \rangle $ (2.6.1)
For example, with
$A\left(\stackrel{^}{X},\stackrel{^}{P}\right)\equiv \frac{1}{2m}{\stackrel{^}{P}}^{2}+V\left(\stackrel{^}{X}\right)$ (2.6.2)
we obtain the well known time independent Schrödinger equation [7]
$\left(\frac{-{\hslash}^{2}}{2m}{\stackrel{\u2323}{D}}_{x}^{2}+V\left(x\right)\right)\Psi \left(x\right)=E\Psi \left(x\right)$ (2.6.3)
As
$\frac{2\pi}{T}={\hslash}^{-1}E$ and t are Fourier transform reciprocal we get the time dependent Schrödinger equation
(2.6.4)
2.7. The Heisenberg Uncertainty Principle
Let be the function equal to zero for and to for as illustrated by Figure 1.
A state where there is incertitude on the wave-number k
(2.7.1)
corresponds to the momentum-representation
(2.7.2)
Utilizing the Heaviside function we may write
(2.7.3)
Thank to (2.1.6), (2.1.7) and the property
(2.7.4)
we get by Fourier transform of (2.7.3)
(2.7.5)
so that by (2.7.2)
(2.7.6)
(2.7.7)
The graph of has the form (Figure 2).
The function has maximum value for, vanishes for . It and its squared are equal nearly to half of their maxima for or.
We may then write that
(2.7.8)
Because the relation (2.7.6) is conformed with the uncertainty principle announced by Heisenberg [8] and proven somehow by Kennard [9] in 1927.
(2.7.9)
Similarly because the couple are reciprocal so as we get
(2.7.10)
2.8. Emission of Photons from Atoms Following Bohr
Consider a state which has many stable values for its energy and suppose that is the sum of individual states each of them having only one value of energy or one frequency
(2.8.1)
By Fourier transform we get
(2.8.2)
so that
(2.8.3)
By (2.8.3) we see that the probability for observing at the instant t is maximal for
(2.8.4)
In other word we see that from time to time there may have emission/absorption of waves with frequencies
(2.8.5)
This result accords with the theory on the constitution of atoms and molecules of Bohr [10] in 1913.
2.9. Obtaining Permutation Relations between Functions of Creation and Annihilation Operators
Let be two operators obeying the condition
(2.9.1)
We have
(2.9.2)
because at each time we change AB into BA we must add.
So, let be an entire function and its derivative function we clearly have
(2.9.3)
Now from (2.9.3)
(2.9.4)
so that by recursion we get
(2.9.5)
From (2.9.5) we can’t sum over because of the mixed coefficient under the summation. After thinking we replace (2.9.5) with the following formula
(2.9.6)
so that if is an entire function we get the fundamental identity between operators obeying the sole condition
(2.9.7)
and its dual
(2.9.8)
For examples we have successively
(2.9.9)
(2.9.10)
Defining the creation and the annihilation operators by
(2.9.11)
we get from (2.9.8), (2.9.9), (2.9.10),
(2.9.12)
(2.9.13)
Closing this paragraph we propose from (2.9.6) the new version of the Newton’s binomial formula
(2.9.14)
3. Obtaining Laws of Wave Optics
3.1. Diffraction by a 3D Object Centered at the Origin of Axis System
Consider an object occupied a limited domain D in space and represented by the object function which may be discontinuous
(3.1.1)
From the formula (2.1.4) we see that the coexistence of a wave and this object may be represented by
(3.1.2)
Equation (3.1.2) gives rise to the main theorem in wave optics
“The amplitude of diffraction of a wave into a wave by the form of an object is equal to multiplies the Fourier transform of the object function calculated for the deviation of the wave-vector”.
3.2. Diffraction by Systems of Identical Objects Centered at the Positions
Consider a set of objects centered at the points. Utilizing (2.1.6), (2.1.7) we have
(3.2.1)
(3.2.2)
and get a useful formula giving the amplitude of diffraction in some direction of a plane wave by a set of identical objects
(3.2.3)
3.3. Applications
3.3.1. Diffraction of by a Semi Space
The semi space under the plane Oxy is described by the object function
(3.3.1)
From the theorem (2.1.4) we see that
(3.3.2)
so that there are diffracted waves only for
(3.3.3)
Equations (3.3.3) gives the Descartes law of reflection [11] which implies that and must be symmetric as shown Figure 3. Moreover if the diffracted wave is situated in a medium where the refractive index is n so that we get the Snell’s law for refraction [11]
(3.3.4)
3.3.2. Obtaining the Fresnel Formulae
Now, let denoted the amplitudes of the incident, the refracted and the reflected waves; the upper and lower semi-space refraction indices.
The amplitudes are proportional to a and respectively to
, (3.3.5)
Remarking that the Fourier transform of a Heaviside function is
(3.3.6)
we get
(3.3.7)
Figure 3. Diffraction by the half space under the plane Oxy.
In order to calculate the coefficients μ, ν we will make use of the law of conservation of energies. The incoming density of energy at the interface Oxy is proportional to, to the inclination and the duration of time an incoming photon is in the vicinity of it, i.e. to or. Similarly for the density of outgoing energies so that
(3.3.8)
The above equations and the formula
(3.3.9)
lead by (3.2.3) to the following
(3.3.10)
· Taken we get and there is total reflection.
· Taken we get the Fresnel formulae [11]
(3.3.11)
· Taken we get the second Fresnel formulae [11]
(3.3.12)
From (3.3.12) we find again the Brewster’s condition for total polarization, [11].
3.3.3. Diffraction by a Sphere
The equation of a sphere centered at O and having radius R as shown in Figure 4 is
(3.3.13)
Its Fourier transform is invariant in a rotation around the origin so that
Figure 4. Deflection of waves by a sphere.
(3.3.14)
As conclusion we see that in a diffraction by a sphere the amplitude of diffraction is inversely proportional to with and there is extinction if
(3.3.15)
Let be the deviation angle in a diffraction as shown Figure 5, we have extinction for such that
(3.3.16)
For example, for and hemoglobin, there is extinction if
3.3.4. Diffraction of a Plane Wave by Parallel Planes
From (3.2.3) we obtain for example the amplitudes of diffraction of a plane wave by parallel planes perpendicular to Oz at the points as shown Figure 6
(3.3.17)
The maximum amplitudes of diffraction correspond, because and have opposite projections on Oz as shown Figure 6, to
(3.3.18)
(3.3.19)
The formula (3.3.19) is identical with the Braag’s formula [11]. Apart from the above applications of the formula (3.1.2) for studying wave optics we have many other interesting applications in Ref [12].
Figure 6. Diffraction by equidistant parallel planes.
4. Remarks and Conclusions
Someone has said that “Physics is the studies of Nature, how matter and radiation behave, move and interact thorough space and time. Mathematics, on the other hand, is logical deductive reasoning based on initial assumption. There are many different systems of mathematics that can describe the same physical phenomenon.” Accordingly this work which improves and completes a previous work [13] is only one attempt for understanding systematically quasi all the principles and hypothesis of quantum mechanics as so as many aspects of wave optics taught in universities. The main remark is that these quantum principles and laws of optics may be deduced from only one simple formula associated with the property which leads to quantization.
May this work brings closer students to modern physics!
Acknowledgements
The author acknowledges Prof. Geneste J.P. for reading and appreciating this work at the World conference on quantum mechanics and nuclear engineering holt in 2019 September at Paris. He thanks warmly the reviewer for giving many judicious remarks and for judging this work as meaningful. He thanks Dr. Feltus Chr. at Luxembourg LIST for laborious writing assistance. He dedicates this work to the Ho Chi Minh-city University of Natural Sciences and the Université libre de Bruxelles where he was formed in the past.