1. Introduction
Ferrites are ferromagnetic material containing predominantly iron oxides along with other oxides of barium, strontium, manganese, nickel, zinc, lithium and cadmium higher than 50%. The recycling of these materials and separating them using external magnet is applicable easily [1]. Previous studies indicate that spinel ferrite is a type of ferrites which has a formula MFe2O4 (M donates divalent cation as Mg2+, Ni2+, Zn2+, Cd2+, Mn2+ and Co2+). Much attention and scientific interest have been paid to spinel ferrites as they have various chemical and physical properties for different applications in a wide range of technology. In particularly, MgFe2O4 is one of the spinel ferrite families of inverse spinel type; it has cubic structure and is a soft magnetic n-type semiconducting material [2]. Spinel ferrites are of great interest due to having diverse chemical and physical properties for various technological applications. In particularly, MgFe2O4 based materials have found applications in microwave devices, computer memory chips and high-density recording media [3]. MgFe2O4 based materials can be used as catalyst [4], inorganic pigment [5] [6], humidity sensor [7], gas sensor [8] [9], hyperthermia [10] [11], low magnetic materials [12] [13], semiconductors [14] [15], and anode material for lithium ion batteries [16]. Nano-Ferrites can be prepared using several techniques, such as polymeric precursors, micro emulsion, reverse micelle, hydrothermal, co-precipitation, sol-gel and solution combustion methods [2]. Sol-gel auto combustion synthesis is low annealing temperature, fast and effective method for producing fine and homogeneous Nano-sized ferrites with good chemical purity and improved physical properties [17]. The thermal and chemical stability of ferrite materials such as magnesium ferrite and its active sites plays an important role in the adsorption of various pollutants from aqueous media [18]. One of the most important pollutants is the radioactive isotopes such as technetium.
Technetium (99Tc) is a pure beta emitter radionuclide that has a long half-life (2.13 × l05 years) with the maximum decay energy of 0.294 MeV and it causes a long-term radiation risk to humanity. A great attention shall be paid to 99Tc during safety assessment of radioactivity in the environment, in decommissioning of nuclear facilities and management of nuclear waste as it has high mobility, high fission yield, and long half-life [19].
There diverse sources of 99Tc such as fallout from nuclear weapons tests, discharges from nuclear power plants, nuclear medicine and radiobiology, resulted in raising the amount of 99Tc released into the environment [19].
All of these activities generate large volumes of low and intermediate radioactive waste which can cause a significant impact on the environment if disposed without a suitable treatment. So, immobilization of long-lived radionuclides, such as 99Tc into a relatively small volume waste is a vital for long term permanent disposal.
Um & Serne, in 2005 [20] studied the behavior of 99Tc in the ground water and showed that it may be exist in the +III to +VII oxidation states under pH and Eh values typical of most subsurface groundwaters, the dominant 99Tc oxidation state in oxic ground waters is the highly mobile pertechnetate anion [Tc(VII)O4]−. Mobility of the pertechnetate anion is attributed to its inability to form stable aqueous complexes or solid phases under circumneutral-to basic pH conditions [20].
The objective of the present work is the synthesis of low-cost adsorbent like MgFe2O4 nanoparticles using sol-gel auto combustion method and study the effect of using different fuels such as Urea, Oxalic acid and Citric acid, moreover the effect of changing the calcination temperatures on the crystallite size and the morphology of the obtained products. The work has been extended to explore the possibility for the removal of pertechnetate,
from a synthetic Low Level Radioactive Liquid Waste (LLRLW) by the prepared Nano-materials (MgFe2O4). The different parameters influencing on the adsorption process was performed in order to control the process along with examining the isotherm models, kinetics, and the thermodynamics of the reactions.
2. Experimental
2.1. Materials and Reagents
All chemicals were analytical grade, purchased and used as received without further purification: Magnesium nitrate Mg(NO3)2∙6H2O Merck; Ferric nitrate Fe(NO3)2∙6H2O, Merck; Urea NH2CONH2; Fluka. Oxalic acid C2H2O4∙2H2O; Sigma-Aldrich; Citric acid HOC(COOH)(CH2COOH)2 Sigma-Aldrich; Ammonium hydroxide 25% NH3 in H2O, Sigma-Aldrich and
radioactive waste was extracted from previously used 99mTc generator /columns collected from the nuclear medicine centers using diluted nitric acid.
2.2. Preparation of MgFe2O4 Nanostructures
Magnesium ferrite, MgFe2O4, nanostructures were synthesized via sol-gel auto combustion method [21] [22] [23] in which an aqueous solution of magnesium nitrate (Mg(NO3)2∙6H2O) was added to a stirring aqueous solution of ferric nitrate (Fe(NO3)2∙6H2O) and the reaction was heated up at 60˚C, and magnetically stirred for 10 min to the hot stirring solution an aqueous solution of Urea was added with molarity ratios between metal nitrate and the fuels (1:2). The solution was heated at 80˚C and stirred for one hour until the gel obtained. The produced solution was dried at 200˚C for 2 h. The produced foamy powder was ground and then, calcined at various temperatures 600˚C and 800˚C to give MgFe2O4 nanostructures referred as a600 and A800, respectively. The produced magnesium ferrite samples (B and C) were prepared by applying similar conditions using Oxalic and Citric acids as a fuel, and the calcined products at 600˚C and 800˚C referred as (b600, B800) and (c600, C800) respectively. The synthesized samples were characterized for crystal phase identification by Powder X-Ray Diffraction (XRD) spectroscopy. The morphology was determined by the Field Emission Scanning Electron Microscopy (FE-SEM) and Fourier Transform Infrared (FTIR) spectroscopy are recorded using KBr pellets on a BRUKER® Tensor 27 FT-IR spectrometer, in the range of 4000 - 400 cm−1.
2.3. Adsorption Studies
Batch experiments were carried out to examine the sorption of pertechnetate,
from aqueous solution by the synthesized Nano MgFe2O4. For the sorption determination, a certain weight (50 mg) of the investigated material (MgFe2O4) contacted with 10 ml of solution contain
at different activity concentration from 2.13 to 15.58 Bq/vial for 24 hours. The sample suspensions were shaken at room temperature (25˚C), then centrifuged at 4000 rpm for 10 minutes. The activity concentration of the obtained solution was determined by Liquid Scintillation Counter (LSC) (type: Packard, USA, model 3720) by mixing 5 ml of the supernatant with 5 ml of ultima gold liquid scintillation cocktail and feeding the measuring vials to the Liquid Scintillation Counter (LSC). The adsorption capacity of the adsorbent (qt, Bq/g); was calculated from Equation (1) [24], where, C0 is the initial
concentration, Ct is the
concentration in solution at a pre-defined time t, V (L) is the volume of the
solution, and m (g) is the mass of MgFe2O4 adsorbent. Moreover, Equation (2) [24] was employed to estimate the removal percent (%R) of the
.
(1)
(2)
Various factors have been investigated such as contact time (20 - 120 min), pH (2 - 9), competing cation concentration KCl (0.05 - 0.55 g), temperature (25˚C - 55˚C), and initial
activity concentration of 951 CPM/vial (3.17 Bq/ml). The equilibrium adsorption capacity of MgFe2O4 adsorbent, qe (Bq/g) can be determined from Equation (3).
(3)
where: Ce (Bq/l) is the
concentration at equilibrium in the supernatant after separation of the adsorbent and V, m, and C0 have the same meaning as in Equations (1) and (2).
3. Results and Discussion
3.1. Structural Characterization
X-Ray Diffraction
The XRD patterns of magnesium ferrite samples produced by calcination of the combusted precursors at 600 and 800˚C are shown in Figures 1(a)-(c) and Figures 2(a)-(c), respectively. It is clearly observed that the calcination temperature 600˚C was not enough to produce a pure phase of MgFe2O4 with samples (a) and (b) as in Figure 1 which prepared using Urea and Oxalic acid as fuels respectively. The sample (a) showed a characteristic peak of hematite at 2θ = 35.48 corresponding to (JCPDS File No. 79-1741). The pattern sample (b) has some intermediate products of Magnesium oxide and hematite that evidenced from their reflection patterns at (2θ = 78.74, 2θ = 74.70) indexed to (JCPDS File No. 87-0652) and at (2θ = 33.11, 2θ = 49.41) indexed to (JCPDS File No. 89-0598), respectively. A similar approach is used for sample (c) Figure 1 revealed the production of single phase of magnesium ferrite with a relatively low amount of impurities.
The diffraction peaks of samples (a) and (c) were consistent very well with the cubic MgFe2O4 with cell parameters; a = 8.386 Å and Vcell = 589.81 Å3 (JCPDS File No. 088-1937). But for sample (b), when oxalic acid is used as a fuel, the diffraction peaks of sample (b) was indexed well with the cubic MgFe2O4 with cell parameters; a = 8.380 Å and Vcell = 588.61 Å3 (JCPDS File No. 088-1935). The same results of getting impure phase with urea fuel and obtaining pure phase with citric acid fuel was reported by Druc et al. in 2013 [25]. On the other hand, the calcination temperature for the three samples was raised to 800˚C to investigate its effect on the phase composition of the combustion products of the three fuels. Figures 2(a)-(c) shows the XRD patterns of the produced magnesium ferrite samples by calcination of the ignited products at 800˚C, it is obvious from Figure 2 that the calcination temperature at 800˚C was enough to produce a crystalline single product with the three fuels and all the diffraction peaks in Figure 2 are consistent well the cubic MgFe2O4 (JCPDS File No. 088-1937). Moreover, the crystallite size (D, nm) of magnesium ferrite products was calculated using the Debye-Scherer Equation (4) [26].
Figure 1. XRD patterns of MgFe2O4 samples calcined at 600˚C prepared by Urea (a), Oxalic acid (b) or Citric acid (c).
Figure 2. XRD patterns of MgFe2O4 samples calcined at 800˚C prepared by Urea (a), Oxalic acid (b) or Citric acid (c).
(4)
where, λ (nm) is the X-ray radiation wavelength, β is the diffraction peak full width at half maximum (FWHM), and θB is the Bragg diffraction angle. The average crystallite size of the prepared MgFe2O4 nanoparticles calcined at 600˚C was about 10.41, 15.15 and 13.53 nm for samples a600, b600 and c600 respectively. Additionally, the crystallite size was increased to 18.88, 18.56 and 15.22 nm on increasing the calcination temperature to 800˚C for samples A800, B800 and C800 respectively. It can be concluded that, changing of the used fuel has a remarkable effect on both the particle size and the phase of the synthesized Nano-MgFe2O4, since using the citric acid fuel produced pure MgFe2O4 nanostructure with the smallest crystallite size at lower temperature (600˚C). Therefore, Citric acid is the optimum fuel in the present work.
FT-IR Analysis Nanoparticles
FT-IR spectroscopy is one of the most important and widely used analytical methods for obtaining information about the presence of certain functional groups in the structure of the magnetic nanomaterials. Figure 3 shows FT-IR spectra (A-C) for samples A800, B800, and C800 prepared by Urea, Oxalic acid and Citric acid as a fuel respectively and annealed at 800˚C. The IR spectra of the samples showed a strong absorption band at 567, 563 and 568 cm−1 for sample A, B, and C, respectively, which is characteristic and indicates the formation of MgFe2O4.
In ferrites crystal structure the metal ions have two characteristic different sub
Figure 3. FT-IR spectra of MgFe2O4 products calcined at 800˚C prepared by Urea (a), Oxalic acid (b) or Citric acid (c).
lattices, known as tetrahedral and octahedral according to the geometrical configuration of the oxygen nearest neighbors. The metal-oxygen band at 567, 563 and 568 cm−1 corresponds to the intrinsic stretching vibrations of the metal at the tetrahedral site [27]. Sample B800 shows a weak absorption band at 1336 cm−1 that is related to carbonate ions [27]. The band at wavenumber 1425 and 1421 for samples B800 and C800 respectively is a characteristic absorption peak for
. However, the IR spectra also showed abroad vibration band at 3421 and 3434 cm−1 for the B800, and C800 samples, respectively, that can be assigned to the OH stretching vibrations of water molecules (physical adsorbed molecular water) while their bending mode appeared at 1641and 1635 cm−1 for the B800, and C800 respectively [28].
Field Emission Scanning Electron Microscopy (FE-SEM) of MgFe2O4 Nanoparticles
Magnesium ferrite MgFe2O4 nano-structures were observed using a scanning electron microscope are shown in Figures 4(a)-(c), which denoted as a800, b800 and c800 referred to the used fuels Urea, Oxalic acid and Citric acid respectively in the preparation process. It is observed that the micrograph of sample (a800) in Figure 4 shows aggregates of wool or cotton of the spherical with average crystallite size about 20 μm. On the other hand, Figure 4(b) & Figure 4(c) revealed that the products (b800 and c800) are composed of small single spheres, bulk agglomerates of sphere like structures and foamy structures with average size of 20 μm. The image illustrated that the spheres in the micrograph of sample b800 are relatively smaller than that in sample c800. The aggregates in the SEM images of the three samples could be attributed to the interaction between the nanoparticles due to the magnetic nature of the MgFe2O4 samples. In cases of nanocrystalline
Figure 4. FE-SEM image of MgFe2O4 products calcined at 800˚C prepared by Urea (a), Oxalic acid (b) or Citric acid (c) as a fuel.
spinel ferrites, it has been observed that there is a tendency for the nanoparticles to agglomerate as reported by Naseri et al., in 2014 [29]. From obtained results it can be concluded that the fuel type in the combustion process could affect the morphology of the final product.
3.2. Batch Adsorption Experiment
Effect of solution pH
The influence of the initial pH of the solution on the removal percent of the investigated isotope (
) was investigated in the pH range from 2 to 9 (Figure 5). The experimental data revealed that the removal percentage of
is high at low pH values, it reaches the maximum removal% at pH ~2 (%R = 99.02%) followed by a plateaued over a wide pH range from pH 3 to 7 (%R = 98.69% - 98.59%), Afterward, the removal percentage reduces sharply for
on increasing the pH values to 9. The behavior can be explained by considering the surface charge of the MgFe2O4 nanoparticles and the
anions at different pH values. At lower pH values, the MgFe2O4 adsorbent surfaces (hydrous oxide (MOH)) will be probably covered by protons forming positively charged particles MOH+2. However, at higher pH values, hydroxide ions are available in high concentrations and may react with the hydrous oxide forming negatively charged deprotonated oxide (MO−) [25] [30]. The adsorption process may be controlled by the electrostatic interactions between the negatively charged pertechnetate anions and the positively charged MgFe2O4 adsorbent. This behavior enhancing the adsorption process at lower pH values, but the adsorption efficiency percent decreased at higher pH values due to the competition between the high concentrations of OH− ions and the negatively charged
anions [31].
Effect of contact time
The influence of contact time on the adsorption efficiency of
anions by MgFe2O4 nano-adsorbent was studied using 0.05 g MgFe2O4 Nano-adsorbent and initial concentration of 128 CPM/vial to 951 CPM/vial (0.43 Bq/ml to 3.17 Bq/ml) for
. Figure 6 represents the
removal percentage against shaking time ranged from 20 to 120 min. The sorption of the investigated isotope
increases with time to reach a saturation level 98.84% for 100 min. depending on the nature of the isotope and selectivity of the prepared Nano adsorbent. The instantaneous removal percent of the investigated isotope by MgFe2O4 indicates that the mechanism of the sorption may be ion exchange [32].
Figure 5. Effect of pH on
removal percent using MgFe2O4 nano-adsorbent.
Figure 6. Effect of contact time on
removal percent using MgFe2O4 nano-adsorbent.
Effect of temperature
The effect of different temperature (25˚C, 35˚C, 45˚C and 55˚C) on the adsorption of
was investigated at initial concentration of 951 CPM/vial (3.17 Bq/ml) for
.and 0.05 g from the nano-MgFe2O4 Figure 7, shows a relatively decrease in the removal percentages of
on MgFe2O4 this may be attributed to the increasing mobility of
ions as the temperature increases, causing small amounts of the ions escapes from the solid phase to the liquid phase [27]. This in turn, means that the reaction may be has an exothermic nature and the adsorption process is favored at low temperatures.
Effect of competing ion concentration
The effect of ionic strength on the adsorption of
on MgFe2O4 was investigated utilizing KCl salt at different weight from 0.05 to 0.55 g. The results shown in Figure 8 reveal that, the solution ionic strength has a negative effect on
ions removal percentage, as increasing the ionic strength decreases the
ions adsorption percentage. The significant decrease of removal percentage may be due to the competition between the
ions and chloride ions in the solution. In other words, as a result of the electrostatic attraction between the negatively charged
ions and the positively charged MgFe2O4
Figure 7. Effect of temperature on
removal percent using MgFe2O4 nano-adsorbent.
Figure 8. Effect of KCl concentration on
removal percent using MgFe2O4 nano-adsorbent.
adsorbent surface, the increase in the solution ionic strength will result in a reduction of the adsorption capacity and this agree with the investigators Ali et al., in 2016 [33] and Reddad et al., in 2002 [34].
Effect of initial
activity concentration
activity concentration ranged from 128 CPM/vial to 951 CPM/vial (0.43 Bq/ml to 3.17 Bq/ml) and utilizing 0.05 g MgFe2O4 as adsorbent. The adsorption capacity increased with increasing the initial activity concentration for
and it reached 186.4 CPM/g (3.11 Bq/g) corresponding to activity 951 CPM/vial (3.17 Bq/ml) (Figure 9). This behavior could be assigned to the higher driving force at more
ions that ease the diffusion of the ions from the solution to the positively charged MgFe2O4 nanoparticles surfaces, and hence more interactions between
ions and the active sites of MgFe2O4 sorbent [35].
3.3. Adsorption Isotherms
Adsorption isotherm is the relationship at equilibrium between the quantity of adsorbate per unit of adsorbent (qe) and its equilibrium solution concentration (Ce) at a constant temperature. To determine the adsorption capacity of the MgFe2O4 nanoparticles, the equilibrium data for the adsorption of
on MgFe2O4 nanoparticles are analyzed in the light of Langmuir and Freundlich adsorption isotherm models [36] [37].
Langmuir isotherm model
Formation of a monolayer adsorbate on the outer surface of the adsorbent, and no further adsorption takes place again, is the assumption of Langmuir isotherm model. It is applicable for monolayer adsorption onto adsorbent surface that has a finite number of identical sites and no transmigration of adsorbate in the plane of the surface. According to these assumptions, the linear equation of Langmuir isotherm model can be written as follows [36].
(5)
Figure 9. Effect of initial
concentration on the adsorption capacity of MgFe2O4 nano-adsorbent.
where: Ce is the concentration of
anions solution (CPM/l) at equilibrium, the constant Q0 refers to the adsorption capacity (CPM/g) and b, Langmuir constant that is related to the energy of adsorption. Linear plot of Ce/qe versus Ce shows Langmuir isotherm (Figure 10). Values of Q0 and b were calculated from the slope and intercept of the linear plots and are presented in Table 1. Moreover, the equilibrium parameter RL which is characteristic of Langmuir isotherm can be, defined as:
(6)
where: b is the Langmuir constant and C0 is the initial
concentration CPM/vial or (Bq/ml), RL value indicates the adsorption nature to be either favorable if 0 < RL < 1, linear if RL = 1, unfavorable if RL > 1 and irreversible if RL = 0 [38]. Table 1 shows RL values between zero and one, which indicate favorable adsorption process.
Freundlich isotherm model:
Freundlich isotherm model assumes that the adsorption takes place on a heterogeneous surface of the adsorbent and the linearized form of this model can be given by Equation (7) [37].
(7)
where: Kf is the Freundlich constant (CPM/g) which represents the relative adsorption capacity of the adsorbent. (1/n) is the heterogeneity factor and it is a function of the strength of adsorption in the adsorption process and n has various values depending on the heterogeneity of the sorbent. If n lies between one and ten, this indicate a favorable sorption process [39]. 1/n and lnKf values were calculated from the slope and intercept of the linear plots of lnqe versus lnCe which shows Freundlich isotherm (Figure 11) and are presented in Table 1.
Figure 10. Langmuir isotherm for adsorption of
on MgFe2O4 nano-adsorbent.
Table 1. Langmuir and Freundlich constants and R2 values obtained for removal of
by MgFe2O4 nano-particles.
Figure 11. Freundlich isotherm for adsorption of
on MgFe2O4 nano-adsorbent.
From Table 1, it is observed that, the heterogeneity parameter, 1/n, for
(1/n = 0.793, n = 1.261), which indicates a favorable sorption process as (n) lies between one and ten [39]. Moreover, the correlation coefficient (R2) values of Freundlich isotherm for
is closer to unity and greater than that in Langmuir isotherm, So, we conclude that the adsorption of
by MgFe2O4 as adsorbent fits Freundlich isotherm model and this in turn suggests that the adsorption process occurs as a multilayer
molecules adsorb onto the heterogeneous adsorbent surface.
3.4. Kinetics Adsorption Models
Pseudo first and second order reaction rate models were used to describe the adsorption behavior of the reaction at which the
anions is removed from aqueous solutions. Pseudo first order rate equation of Lagergen is given by Equation (8) [40].
(8)
where: qe and qt are the amounts of
anions adsorbed (CPM/g) at equilibrium and at time t (min), respectively and K1,ads is the rate constant of pseudo first order adsorption (min−1). Values of K1,ads were calculated from the plots of
versus t (Figure 12).The rate equation for pseudo-second order model is given by equation (9) [41].
(9)
where: k2,ads (g/CPM min) is the pseudo second order rate constant and its value was obtained from the plots of t/qt versus t (Figure 13). Table 2 lists the rate constants, calculated equilibrium adsorption capacity qe(cal) and experimental equilibrium adsorption capacity qe(exp) for
obtained using the pseudo-first and second order models. It is obvious that qe value calculated from pseudo first order kinetic model was too small compared to the experimental value for
anions. However, the calculated qe from pseudo second order
Figure 12. Pseudo-first-order plots for adsorption of
on MgFe2O4 nano-adsorbent.
Figure 13. Pseudo-second-order plots for adsorption of
on MgFe2O4 nano-adsorbent.
Table 2. Pseudo first and second order reaction rate models’ parameters for adsorption.
kinetic model was relatively close to the experimental value. Additionally, the correlation coefficient (R2) values of pseudo second order model is closer to unity. These results show that the pseudo second order adsorption mechanism is predominant and adsorption process of
anions appeared to controlled by the chemisorption process.
anions can be ionized in solution to form negative ions and the nano-MgFe2O4 carry a positive charge, which may lead to a chemical reaction through electrostatic interaction between a positive charge at the surface of MgFe2O4 nanoparticles and the negative charge on pertechnetate anions [42].
3.5. Thermodynamic Studies for Adsorption
on MgFe2O4
Van’t Hoff Equation (10), was used to calculate the thermodynamic parameters such as change in enthalpy (∆Ho), change in entropy (∆So) and change in free energy (∆Go). Adsorption of
on MgFe2O4, at different temperatures were determined by using Equations (11) & (12) and illustrated in Figure 14. The values of ∆Ho and ∆So were calculated from Figure 14 and reported in Table 3.
(10)
(11)
(12)
where: Kd is the equilibrium constant, CAe is the solid phase concentration at equilibrium (mg/L), T is the temperature in kelvin and R is the gas constant. Plotting lnKd against 1/T gives a straight line with slope and intercept equal to―∆Ho/R and ∆So/R, respectively. The values of ∆Ho and ∆So were calculated from Figure 14 and reported in Table 3. The negative values of ∆Ho indicate the exothermic nature of adsorption process. The negative value of entropy change (∆So) corresponds to a decrease in degree of freedom of the adsorbed species. This suggests the decrease in concentration of adsorbate in solid solution interface indicating an increase in adsorbate concentration on the solid phase. This is the
Figure 14. Van’t Hoff plot for adsorption of
on MgFe2O4 nano-adsorbent.
Table 3. Thermodynamic parameters for adsorption of
on MgFe2O4 nanoparticles.
normal effect of chemical adsorption phenomenon, which takes place through electrostatic attraction. Gibbs free energy of adsorption (∆Go) was calculated from Equation (12) and the values are given in Table 3. The negative value of ∆Go indicates that the adsorption of
on Nano-magnesium ferrite is a spontaneous process, whereby no energy input from outside of the system is required. However, the values of ∆Go decreased with increasing of temperature suggesting that adsorption became less favorable at higher temperatures. As the temperature increases, the mobility of
anions increases, causing the anions to escape from the solid phase to the liquid phase. Therefore, the amount of
anions that can be adsorbed will decrease. The increased mobility of
anions at elevated temperature may be reflected in the values of Kd (Table 3). As the temperature increased the values of Kd decreased indicating a lower affinity of the MgFe2O4 nanoparticles towards
anions at higher temperatures [43] [44].
4. Conclusion
Low cost adsorbent MgFe2O4 nanoparticles were prepared successfully. The prepared pure phase produced by using citric acid as a fuel was tested for the removal of
anions from low level liquid waste and showed high removal percentage reached 98.84% within equilibrium time 100 minutes. The removal efficiency was decreased with increasing the added KCl dose. The rate of the reaction is pseudo second order with R2 (0.99). The reaction followed Freundlich isotherm model with R2 (0.95) which indicated to chemisorption process. The negative value of enthalpy (∆Ho) indicates the exothermic nature of the reaction, and the negative value of the change in free energy (∆Go) illustrates that the adsorption of
anions on Nano-MgFe2O4 is a spontaneous process. Finally, it can be concluded that MgFe2O4 nanoparticles are an efficient adsorbent for removal of
anions from low level radioactive liquid waste.