Spectroscopic Studies of Nanocomposites Based on PEO/PVDF Blend Loaded by SWCNTs


Novel nanocomposites of PEO/PVDF loaded by different contents of SWCNTs were prepared. From UV-Vis spectra, the estimated values of absorption edge, absorption coefficient, energy of tail and extinction coefficient were calculated. The exponential decay tail at low energy is due to the presence of localized states in the energy band gap. The shift of Raman spectra indicates the possibility of SWCNTs to be attached with OH group in the side chain of polymer molecules. The X-ray measurements indicate that the addition of SWCNTs is a rich amorphous region in polymeric matrices and complete complexation between PEO/PVDF blend and SWCNTs. The SEM images show smooth surface of PEO/PVDF and they become rough with single rod with a good distribution within surface region in polymeric matrices after loading SWCNTs. TEM images showed that SWCNTs were dispersed well in polymeric matrices. The broken ends of nanotubes were showing that the SWCNTs were broken apart rather than from at the fracture surface. The films show some defects like rags on the tube walls. There are some black regions in TEM images attributed to amorphous nature carbon. The prepared nanocomposites are very useful in technical application.

Share and Cite:

Alhusiki-Alghamdi, H. and Alghunaim, N. (2015) Spectroscopic Studies of Nanocomposites Based on PEO/PVDF Blend Loaded by SWCNTs. Journal of Modern Physics, 6, 414-424. doi: 10.4236/jmp.2015.64045.

Conflicts of Interest

The authors declare no conflicts of interest.


[1] supova, M., Martynkova, G.S. and Barabaszova, K. (2011) Science of Advanced Materials, 3, 1-25.
[2] Tjong, S.C. (2006) Materials Science and Engineering: R: Reports, 53, 73-197.
[3] Utracki, L.A. (2007) Polymers for Advanced Technologies, 18, 1-37.
[4] Chen, C.Q., Pei, Y.T. and De Hosson, J.T.M. (2012) Scripta Materialia, 67, 947-950.
[5] Wu, Z., Zhang, Y.W., Jhon, M.H., Gao, H. and Srolovitz, D.J. (2012) Nano Letters, 12, 910-914.
[6] Sha, Z.D., He, L.C., Xu, S., Pei, Q.X., Liu, Z.S., Zhang, Y.W. and Wang, T.J. (2014) Scripta Materialia, 93, 36-39.
[7] Iijima, S. (1991) Nature, 354, 56-58.
[8] Dhand, C., Arya, S.K., Singh, S.P., Singh, B.P., Datta, M. and Malhotra, B.D. (2008) Carbon, 46, 1727-1735.
[9] Popov, V.N. (2004) Materials Science and Engineering: R: Reports, 43, 61-102.
[10] Odom, T.W. (2001) Australian Journal of Chemistry, 54, 601.
[11] Paiva, M.C., Zhou, B., Fernando, K.A.S., Lin, Y., Kennedy, J.M. and Sun, Y.P. (2004) Carbon, 42, 2849-2854.
[12] Liu, L., Barber, A.H., Nuriel, S. and Wagner, H.D. (2005) Advanced Functional Materials, 15, 975-980.
[13] Dow, J.D. and Redfield, D. (1972) Physical Review B, 5, 594.
[14] Abdelrazek, E.M. (2008) Physica B, 403, 2137-2142.
[15] Reddy, C.V.S., Zhu, Q.Y., Mai, L.Q. and Chen, W. (2006) Journal of Applied Electrochemistry, 36, 1051-1056.
[16] Sharma, P., Sharma, V. and Katyl, S.C. (2006) Chalcogenide Letters, 3, 73-79.
[17] Wood, D.L. and Tauc, J. (1972) Physical Review B, 5, 3144.
[18] Urbach, F. (1953) Physical Review, 92, 1324.
[19] Altaf, M. and Chaudhry, M.A. (2000) Journal of the Korean Physical Society, 36, 265.
[20] Mott, N.F. and Davis, E.A. (1971) Electronic Processes in Non-Crystalline Solids. Clarendon Press, Oxford.
[21] Dwivedi, D.K., Pathak, H.P., Shukla, R.K. and Kumar, A. (2013) American Journal of Materials Science and Engineering, 1, 46-49.
[22] Dresselhaus, M.S., Dresselhaus, G., Saito, R. and Jorio, A. (2005) Physics Reports, 409, 47-99.
[23] Dresselhaus, M.S., Dresselhausc, G., Jorio, A., Filho, A.G.S. and Saito, R. (2002) Carbon, 40, 2043-2061.
[24] Dresselhaus, M.S. and Eklund, P.C. (2000) Advances in Physics, 49, 705-814.
[25] Maxfield, J. and Shepherd, I.W. (1975) Polymer, 16, 505-509.
[26] Mattsson, B., Ericson, H., Torell, L.M. and Sundholm, F. (2000) Electrochimica Acta, 45, 1405-1408.
[27] Mattsson, B., Ericson, H., Torell, L.M. and Sundholm, F. (1999) Journal of Polymer Science Part A: Polymer Chemistry, 37, 3317-3327.
[28] Lebedev, S.M., Gefle, O.S. and Tkachenko, S.N. (2011) Russian Physics Journal, 54, 679-685.
[29] Wang, Y., Wang, J., Wang, F., Li, S. and Xiao, J. (2008) Polymer Bulletin, 60, 647-655.
[30] Mihaylova, M.D., Krestev, V.P., Kresteva, M.N., Amzil, A. and Berlinova, I.V. (2001) European Polymer Journal, 37, 233-239.

Copyright © 2023 by authors and Scientific Research Publishing Inc.

Creative Commons License

This work and the related PDF file are licensed under a Creative Commons Attribution 4.0 International License.