Synthesis and Characterization of Polyethylene Oxide Incorporated with Cadmium Sulphide Nanoparticles

DOI: 10.4236/ampc.2015.52008   PDF   HTML   XML   2,967 Downloads   3,829 Views   Citations


System of polyethylene oxide (PEO) and PEO incorporated with 2.5 and 5 wt% of cadmium sulphide (CdS) nanoparticles were synthesized by simple trend chemical techniques and casting method. Characterization and investigation of the samples has been done by different techniques such as: X-ray, UV-visible, photoluminescence (PL) and Transmission Electron Microscope (TEM) techniques. The change of the structural has been interpreted in terms of the structural modifications of the PEO polymeric matrices. The physical properties of nanoparticles were found to relate the size. The crystallite sizes of cadmium sulphide crystals were estimated from the peaks of the X-ray diffraction (XRD) and TEM tools. The average particle size found by TEM is 44 nm. The absorption spectra showed absorption edge at 448 nm for all the samples. The particle size was estimated by theory and was found to be nearly the same as that obtained by TEM. The optical properties of the samples were estimated by photoluminescence and UV visible spectroscopy.


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Alhusiki-Alghamdi, H. and Alghunaim, N. (2015) Synthesis and Characterization of Polyethylene Oxide Incorporated with Cadmium Sulphide Nanoparticles. Advances in Materials Physics and Chemistry, 5, 53-59. doi: 10.4236/ampc.2015.52008.

Conflicts of Interest

The authors declare no conflicts of interest.


[1] Zang, J.X., Zhao, G.L. and Han, G.R. (2007) Preparation of CdS Nanoparticles by Hydrothermal Method in Micro-emulsion. Frontiers of Chemistry in China, 2, 98-101.
[2] Shrivastava, S. and Verma, B. (2007) Preparation and Characterization of Chemically Deposited (Cd0.7-Zn0.3)S: CdCl2,Gd Nanocrystalline Films. Crystal Research and Technology, 42, 466-470.
[3] Ajibade, P.A. and Onwudiwe, D.C. (2013) Optical and Structural Characterization of ZnS, CdS, and HgS Nanoparticles from N-Alkyl-N-Phenyl Dithiocarbamate Complexes. Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 43, 10-18.
[4] Tong, H. and Zhu, Y.J.(2006) Synthesis of CdS Nano-crystals Based on Low-Temperature Thermolysis of One Single-Source Organometallic Precursor. Nanotechnology, 17, 845-851.
[5] Kulkarni, S.K., Winkler, U., Deshmukh, N., Borse, P.H., Fink, R. and Umbach, E. (2001) Investigations on Chemically Capped CdS, ZnS and ZnCdS Nanoparticles. Applied Surface Science, 169-170, 438-446.
[6] Marandi, M., Taghavinia, N., Zad, A.I. and Mahdavi, S.M. (2006) Fine Tuning of the Size of CdS Nanoparticles Synthesized by a Photochemical Method. Nanotechnology, 17, 1230-1235.
[7] Merkoci, A., Marin, S., Neda, M.T.C., Pumera, M., Ros, J. and Alegret, S. (2006) Crystal and Electrochemical Properties of Water Dispersed CdS Nanocrystals Obtained via Reverse Micelles and Arrested Precipitation. Nanotechnology, 17, 2553-2559.
[8] Prabhu, R.R. and Khadar, M.A. (2005) Characterization of Chemically Synthesized CdS Nanoparticles. Pramana: Journal of Physics, 65, 801-807.
[9] Lee, H.L., Mohammed, I.A., Belmahi, M., Assouar, M.B., Rinnert, H. and Alnot, M. (2010) Thermal and Optical Properties of CdS Nanoparticles in Thermotropic Liquid Crystal Monomers. Materials, 3, 2069-2086.
[10] Bansal, P., Jaggi, N. and Rohilla, S.K. (2012) Green Synthesis of CdS Nanoparticles and Effect of Capping Agent Concentration on Crystallite Size. Research Journal of Chemical Sciences, 2, 69-71.
[11] Mercy, A., Selvaraj, R.S., Boaz, B.M., Anandhi, A. and Kanagadura, R. (2013) Synthesis, Structural and Optical Characterization of Cadmium Sulphide Nanoparticles. Indian Journal of Pure and Applied Physics, 51, 448-452.
[12] Alonso, C.M., Castaneda, C.A.R., Romero, P.M., Monroy, C.S.C. and Hu, H. (2014) Cadmium Sulfide Nanoparticles Synthesized by Microwave Heating for Hybrid Solar Cell Applications. International Journal of Photoenergy, 1, 1-11.
[13] El-Tantawy, F., Abdel-Kader, K.M., Kaneko, F. and Sung, Y.K. (2004) Physical Properties of CdS-Poly(Vinyl Alcohol) Nanoconducting Composite Synthesized by Organosol Techniques and Novel Application Potential. European Polymer Journal, 40, 415-430.
[14] Antolini, F., Pentimalli, M., Di Luccio, T., Terzi, R., Schioppa, M., Re, M., Mirenghi, L. and Tapfer, L. (2005) Structural Characterization of CdS Nanoparticles Grown in Polystyrene Matrix by Thermolytic Synthesis. Materials Letters, 59, 3181-3187.
[15] Kandasamy, K., Singh, H.B. and Kulshreshtha, S.K. (2009) Synthesis and Characterization of CdS and CdSe Nanoparticles Prepared from Novel Intramolecularly Stabilized Single-Source Precursors. Journal of Chemical Sciences, 121, 293-296.
[16] Vishwakarma, P., Ramrakhiani, M., Singh, P. and Bisen, D.P. (2011) Synthesis and Electroluminescence Studies of Manganese Doped Cadmium Sulfide Nanoparticles. The Open Nanoscience Journal, 5, 34-40.
[17] Liu, S.H., Qian, X.F., Yin, J., Ma, X.D., Yuan, J.Y. and Zhu, Z.K. (2003) Preparation and Characterization of Polymer-Capped CdS Nanocrystals. Journal of Physics and Chemistry of Solids, 64, 455-458.
[18] Chowdhury, S., Ahmed, G.A., Mohanta, D., Do-lui, S.K., Avasthi, D.K. and Choudhury, A. (2005) Luminescence Study of Bare and Coated CdS Quantum Dots: Effect of SHI Irradiation and Ageing. Nuclear Instruments and Methods in Physics Research Section B, 240, 690-696.
[19] Ghanbari, D. and Niasari, M.S. (2012) The Effect of CdS/Organic Nanostructure as Additive on the Thermal Stability of ABS Polymer. High Temperature Materials and Processes, 31, 133-138.
[20] Urbach, F. (1953) The Long-Wavelength Edge of Photographic Sensitivity and of the Electronic Absorytion of Solids. Physical Review, 92, 1324-1324.
[21] Altaf, M. and Chaudhry, M.A. (2005) Effect of Li2O on the Refractive Index and Optical Band Gap of Cadmium Phosphate Glasses. Glass Physics and Chemistry, 9, 597-601.
[22] Wu, C.L. and Zhao, Y.B. (2007) CdS Quantum Dots as Fluorescence Probes for the Sensitive and Selective Detection of Highly Reactive HSe Ions in Aqueous Solution. Analytical and Bioanalytical Chemistry, 388, 717-722.

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