Chemical Constituents from Caesalpinia férrea: Identification and 1H and 13C Resonance Assignment

Abstract

In a phytochemical investigation of Caesalpinia ferrea (Leguminosae), four aromatic compounds (1-4) have been isolated and identified. Their structures have been assigned based on data provided by spectroscopic techniques, including 2D NMR experiments. Compounds 3 and 4 are being reported for the first time for Cesalpina ferrea.

Share and Cite:

Magalhães, I. , Pinto, F. , Filho, R. , Ferreira, D. , de Lemos, T. and Monte, F. (2014) Chemical Constituents from Caesalpinia férrea: Identification and 1H and 13C Resonance Assignment. American Journal of Analytical Chemistry, 5, 688-694. doi: 10.4236/ajac.2014.510077.

Conflicts of Interest

The authors declare no conflicts of interest.

References

[1] Wu, M., Wang, Y., Zhang, M., Huo, C., Dong, M., Shi, Q. and Kiota, H. (2011) Chemical Constituents of Pants from the Genus Caesalpinia. Chemistry & Biodiversity, 8, 1370-1399.
http://dx.doi.org/10.1002/cbdv.201000176
[2] Pranithanchai, W., Karalai, C., Ponglimanont, C., Subhadhirasakul, S. and Chantrapromma, K. (2009) Cassanediterpenoids from the Stem of Caesalpiniapul cherrima. Phytochemistry, 70, 300-304.
http://dx.doi.org/10.1016/j.phytochem.2008.12.006
[3] Cavalheiros, M.G., Farias, D.F., Fernandes, G.S., Nunes, E.P., Cavalcanti, E.F., Vasconcelos, I.M., Melo, V.M.M. and Carvalho, A.F.U. (2009) Atividades biológicas e enzimáticas do extrato aquoso de sementes de Caesalpinia férrea Mart., Leguminoseae. Revista Brasileira de Farmaconosia, 19, 586-591.
http://dx.doi.org/10.1590/S0102-695X2009000400014
[4] Pires, A.M. (2010) Estudo Fitoquímico de Abarema cochliacarpos (Leguminosae). Dr. Tese, Universidade Federal do Ceará, Fortaleza.
[5] Souza Filho, A.P.S., Santos, R.A., Santos, L.S., Guilhon, G.M.P., Santos, A.S., Arruda, M.S.P., Muller, A.H. and Arruida, A.C. (2006) Allelophatic Potential of Myrcia guianense. Planta Daninha, 24.
[6] Alves, C.Q. (2007) Flavonoides Antioxidantes e Derivados do ácido gálico Isolados de Cenostigma gardnerianum Tul (Leguminoseae). Dr. Tese, Universidade Federal do Ceará, Fortaleza.
[7] He, K., Timmermann, B.N., Aladesanmi, A.J. and Zeng, L. (1996) A Biflavonoid from Dysoxylum lenticelare. Phyto-chemsitry, 42, 1199-1201.
[8] Markham, K.R., Sheppard, C. and Geiger, H. (1987) Carbon-13 NMR of Flavonoids. Part. IV. Carbon-13 NMR Studies of Some Naturally Occurring Amentoflavone and Hinokifalvone Bioflavonoids. Phytochemsitry, 26, 3335-3337.
http://dx.doi.org/10.1016/S0031-9422(00)82499-1
[9] Zheng, J., Zheng, Y., Zhi, H., Dai, Y., Fang, Y., Du, Z., Zhang, K., Li., M., Wu, L. and Fan, M. (2011) New 3',8'-Linked Bifalvonoids from Selaginellauncinata Displaying Protective Effect against Anoxia. Molecules, 16, 6206-6314.
http://dx.doi.org/10.3390/molecules16086206
[10] Sivakumar, B., Murugan, R., Baskaran, A., Khadangale, B.P., Murugan, S. and Senthilkumar, U.P. (2013) Identification and Characterization of Process-Related Impurities of Trans-Resveratrol. Scientia Pharmaceutica, 81, 683-695.

Copyright © 2023 by authors and Scientific Research Publishing Inc.

Creative Commons License

This work and the related PDF file are licensed under a Creative Commons Attribution 4.0 International License.