Geochemistry of the Rare Earth Elements (REE) Distribution in Terengganu Coastal Waters: A Study Case from Redang Island Marine Sediment

A. Nor Antonina, N. A. M. Shazili, B. Y. Kamaruzzaman, M. C. Ong, Y. Rosnan, F. N. Sharifah

Department of Marine Science, Faculty of Maritime Studies and Marine Science, University Malaysia Terengganu, Kuala Terengganu, Malaysia.
Department of Marine Science, Faculty of Maritime Studies and Marine Science, University Malaysia Terengganu,Kuala Terengganu, Malaysia.
Institute of Oceanography and Maritime Studies, Kulliyyah of Science, International Islamic University Malaysia,Kuantan, Malaysia.

DOI: 10.4236/ojms.2013.33017                

Abstract

A study on the rare earth elements (REEs) of Redang Island marine sediments was conducted in August 2011 during the premonsoon season. Bottom sediments were collected from 27 sampling stations on board UMT Discovery II vessel using a Smith McIntyre grab and analyzed for rare earth elements (REEs) using inductively coupled plasma mass spectrometry (ICP-MS). Results showed that the REEs patterns in sediments reflected the source rock patterns with an overall order of abundance such as: light rare earth elements (LREE) > middle rare earth element (MREE) > high rare earth elements (HREE). The chondrite normalized patterns of REEs showed enrichment of LREEs over HREEs with La/Yb of 13.6 while the chondrite normalized value showed low (Gd/Yb)N ratios (2.12) which was illustrated in the flat HREE pattern. The chondrite normalized REE patterns of sediments showed the enrichment of LREE and depletion of HREE. From our findings, REEs concentrations in the study area were found to be of geogenic origins and the distributions were not influenced by anthropogenic sources.

Keywords

Rare Earth Elements; Marine Sediments; Redang Island; Malaysia

Conflicts of Interest

The authors declare no conflicts of interest.

References

[1]	H. Elderfield, R. Upstill-Goddard and E. R. Sholkovitz, “The Rare Earth Elements in Rivers, Estuaries and Coas tal Seas and Their Significance to the Composition of Ocean Waters,” Geochimica et Cosmochimica Acta, Vol. 54, No. 4, 1990, pp. 971-991. doi:10.1016/0016-7037(90)90432-K
[2]	E. R. Sholkovitz, “Chemical Evolution of Rare Earth Ele ments: Fractionation between Colloidal and Solution Phases of Filtered River Water,” Earth and Planetary Science Letter, Vol. 114, No. 1, 1992, pp. 77-84. doi:10.1016/0012-821X(92)90152-L
[3]	D. Rousseau D. B. Dupré, J. Gaillardet and C. J. Allègre, “Major and Trace Elements of River-Borne Material: The Congo Basin,” Geochimica et Cosmochimica Acta, Vol. 60, No. 8, 1996, pp. 1301-1321. doi:10.1016/0016-7037(96)00043-9
[4]	R. Ramesh, A. L. Ramanathan, S. Ramesh, R. Purvaja and V. Subramanian, “Distribution of Rare Earth Ele ments and Heavy Metals in the Surficial Sediments of the Himalayan River System,” Geochemical Journal, Vol. 34, 2000, pp. 295-319. doi:10.2343/geochemj.34.295
[5]	Y. Nozaki, D. Lerche, D. S. Alibo and A. Snidvongs, “The Estuarine Geochemistry of Rare Earth Elements and Indium in the Chao Phraya River, Thailand,” Geochimica et Cosmochimica Acta, Vol. 64, No. 23, 2000, pp. 3983 3994. doi:10.1016/S0016-7037(00)00473-7
[6]	P. Singh and V. Rajamani, “REE Geochemistry of Recent Clastic Sediments from the Kaveri Floodplains, Southern India: Implication to Source Area Weathering and Sedi mentary Processes,” Geochimica et Cosmochimica Acta, Vol. 65, 2001, pp. 3093-3108. doi:10.1016/S0016-7037(01)00636-6
[7]	A. M. Shiller, “Seasonality of Dissolved Rare Earth Ele ments in the Lower Mississippi River,” Geochemistry, Geophysics and Geosystems, Vol. 3, No. 11, 2002, pp. 1068-1082. doi:10.1029/2002GC000372
[8]	M. A. Kimoto, X. C. Nearing, D. Zhang and M. Powell, “Applicability of Rare Earth Element Oxides as a Sedi ment Tracer for Coarse-Textured Soils,” Catena, Vol. 65, No. 3, 2006, pp. 214-221. doi:10.1016/j.catena.2005.10.002
[9]	A. P. Jones, F. Wall and C. T. Williams, “Rare Earth Mi nerals Chemistry, Origin and Ore Deposits. Series: The Mineralogical Society Series,” Vol. 7, Springer Publisher, 1996.
[10]	Z. L. Song, C. Q. Liu, G. L. Han, Z. L. Wang, Z. Z. Zhu and C. Yang, “Enrichment and Release of Rare Earth Elements during Weathering of Sedimentary Rocks in Wujiang Catchments, Southwest China,” Journal of Rare Earths, Vol. 24, No. 4, 2006, pp. 491-496. doi:10.1016/S1002-0721(06)60149-X
[11]	K. Sultan and N. A. M. Shazili, “Rare Earth Elements in Tropical Surface Water, Soil and Sediments of the Ter engganu River Basin, Malaysia,” Journal of Rare Earths, Vol. 27, No. 6, 2009, pp. 1072-1078. doi:10.1016/S1002-0721(08)60391-9
[12]	T. T. Khoo, B. S. Yaw, T. Kimura and J. H. Kim, “Geol ogy and Paleontology of the Redang Islands, Terengganu, Peninsular Malaysia,” Journal of Southeast Asian Earth Sciences, Vol. 2, No. 3-4, 1988, pp. 123-130. doi:10.1016/0743-9547(88)90023-2
[13]	P. Kulkarni, S. Chellam, J. B. Flanagan and R. K. M. Jayanty, “Microwave Digestion: ICPMS for Elemental Analysis in Ambient Airbone Fine Particulate Matter: Rare Earth Elements and Validation Using a Filter Borne Fine Particle Certified Reference Material,” Analytica Chimica Acta, Vol. 599, No. 2, 2007, pp. 170-176. doi:10.1016/j.aca.2007.08.014
[14]	A. B. Ronov, Y. A. Balashov and Y. P. Girin, “Regulari ties of Rare Earth Element Distribution in the Sedimen tary Shell and in the Crust of the Earth,” Sedimentology, Vol. 21, 1974, pp. 171-193. doi:10.1111/j.1365-3091.1974.tb02055.x
[15]	E. Anders and N. Grevesse, “Abundances of the Elements: Meteoritic and Solar,” Geochimica et Cosmochimica Acta, Vol. 53, No. 1, 1989, pp. 197-214. doi:10.1016/0016-7037(89)90286-X.
[16]	R. I. Khadijeh Saraee, S. B. Elias, A. K. Wood and A. M. Reza, “Rare Earth Elements Distribution in Marine Sedi ments of Malaysia Coasts,” Journal of Rare Earths, Vol. 27, No. 6, 2009, pp. 1066-1077. doi:10.1016/S1002-0721(08)60390-7
[17]	G. Bao and Q. Li, “Geochemistry of Rare Earth Elements in Ferromanganese Nodules (Crusts) of the South China Sea,” Oceanologia et Limnologia Sinica, Vol. 24, No. 3, 1993, pp. 304-309.
[18]	R. W. Murray, T. Buchholtz, M. R. Brink, D. L. Jones, D. C. Gerlach and G. P. Russ, “Rare Earth Elements as Indi cators of Different Marine Depositional Environments in Chert and Shale,” Geology, Vol. 18, 1990, pp. 268-272.
[19]	R. H. Byrne and K. H. Kim, “Rare Earth Precipitation and Co-Precipitation Behavior: The Limiting Role of on Dissolved Rare Earth Concentrations in Seawater,” Geochimica Cosmochimica Acta, Vol. 57, No. 3, 1993, pp. 519-526. doi:10.1016/0016-7037(93)90364-3