Synthesis, Spectral Characterization and Ligation of N-[2-(Phenylseleno)ethyl]phthalimide

DOI: 10.4236/jcpt.2013.31005   PDF   HTML   XML   4,235 Downloads   7,399 Views   Citations


PhSe-Na+ generated in situ by reduction of PhSeSePh, with sodium borohydride on reaction with N-(2-bromoethyl) phthalimide in N2 atmosphere results in the formation of N-[2-(phenylseleno)ethyl]phthalimide (L1). The title compound has been characterized by elemental analysis, FT-IR, 1H and 13C NMR techniques. The crystal structure of L1 has been solved by direct methods and refined by full-matrix least squares. The ligand L1 crystallize in the monoclinic space group. Selenium forms two Se-C linkages, one is due to Se-Calkyl and the other one to Se-Caryl. Further, the ligation reaction of L1 with complex 1 is also explored whose identities are characterized by spectroscopic techniques.

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R. Rastogi, S. Srivastava, S. Asolia and R. Butcher, "Synthesis, Spectral Characterization and Ligation of N-[2-(Phenylseleno)ethyl]phthalimide," Journal of Crystallization Process and Technology, Vol. 3 No. 1, 2013, pp. 31-34. doi: 10.4236/jcpt.2013.31005.

Conflicts of Interest

The authors declare no conflicts of interest.


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