Clay Minerals as Climate Change Indicators—A Case Study

A. R. Chaudhri, Mahavir Singh

Department of Geology, Kurukshetra University, Kurukshetra, India.

DOI: 10.4236/ajcc.2012.14020                

Abstract

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The clay mineralogy of the Late Pliocene-Early Pleistocene Pinjor Formation of the type area, northwestern Himalaya, India has been investigated to understand the paleoclimatic conditions and paleotectonic regime prevailing in the frontal Himalayan terrain during 2.5 Ma to 1.7 Ma. The clay minerals were investigated by X-ray diffraction analysis and scanning electron microscope studies. Study of the oriented aggregates of 47 representative clay samples of the Pinjor Formation of the type area reveals that illite is the most dominant mineral followed by chlorite, kaolinite, vermiculite and mixed layer clay minerals. The distribution of the clay minerals in the three lithostratigraphic units of the Formation, namely the Kona Clay Member, the Tanda Bhagwanpur Wacke Member and the Chauki Nadah Pebbly Bed Member which are well exposed along the Berwala-Mandhna section, the Kona-Karaundanwala section and the Ghaggar River-Chauki Nadah section, is nearly uniform suggesting thereby the prevalence of similar sedimentation environments in the Himalayan foreland basin. The presence of illite and kaolinite suggests their derivation from crystalline rocks containing felspar and mica as also from pre-existing soils and sedimentary rocks. Further, the paleoclimatic conditions were moderate. Presence of chlorite suggests the weathering of intermediate and basic crystalline rocks and low grade metamorphic rocks in the positive areas. The presence of kaolinite in the Pinjor Formation is mainly attributed to the weathering and subsequent leaching of the mineral from granitic and basic rocks in the hinterland. Vermiculite has been mainly formed by weathering and transformation of biotite. Warm and humid climatic conditions prevailed for a major part during the deposition of the detritus which favored weathering and transformation of minerals. During the terminal phase of sedimentation there was renewed tectonic activity which had a significant impact on climate as precipitation and mechanical weathering rates increased substantially. Post 1.7 Ma there was a marked shift in temperature patterns and subsequent cooling of the landmass, which resulted in a decreased vegetation cover and a subsequent decrease in animal population thriving on it.

Keywords

Clay Minerals; Climate; Pinjor; Siwalik; Himalaya; India

Conflicts of Interest

The authors declare no conflicts of interest.

References

[1]	R. S. Chaudhri, “Fifty Years of Research on Sustainable Resource Management in Shivaliks,” In: S. P. Mittal, R. K. Aggarwal and J. S. Samra, Eds., Geology of the Siwalik Group of Western and Central Himalaya, Central Soil and Water Conservation Research and Training Institute, Research Centre, Chandigarh, 2000, pp. 3-18.
[2]	B. Parkash, R. P. Sharma and A. K. Roy, “The Siwalik Group Molasse, Sediments Shed by Collision of Continental Plates,” Sedimentary Geology, Vol. 251, No. 2, 1980, pp. 127-159. doi:10.1016/0037-0738(80)90058-5
[3]	J. J. Fripiat, “Advanced Techniques for Clay Mineral Analysis,” Elsevier Scientific Publication Company, Amsterdam, 1982, pp. 235.
[4]	R. S. Chaudhri and G. T. S. Gill, “Clay Mineralogy of the Siwalik Group of the Simla Hills, Northwestern Himalaya,” Journal of Geological Society of India, Vol. 24, 1983, pp. 159-165.
[5]	V. Raiverman, S. V. Kunte and A. Mukherjea, “Basin Geometry, Cenozoic Sedimentation and Hydrocarbon Prospects in Northwestern Himalaya and Indo-Gangetic Plains,” Petroleum Asian Journal, Vol. 6, 1983, pp. 6792.
[6]	R. S. Chaudhri and N. Ramanujam, “Clay Mineralogy of the Tal Formation of the Mussoorie Hills, Kumaon Himalaya,” Publication Centre Advance Study of Geology, Panjab University, Chandigarh, 1985.
[7]	R. S. Chaudhri and H. S. Grewal, “Clay Mineral Assemblage of the Jaunsar Group of Northwestern Himalaya,” Indian Journal of Earth Sciences, Vol. 15, 1988, pp. 228233.
[8]	H. Chamley, “Clay Sedimentology,” Springer-Verlag, Berlin, 1989.
[9]	D. W. Burbank, L. A. Derry and C. France-Lanord, “Reduced Himalayan Sediments Production 8 Myr Ago despite an Intensified Monsoon,” Nature, Vol. 364, No. 6432, 1993, pp. 48-50. doi:10.1038/364048a0
[10]	T. N. Bagati and R. Kumar, “Clay Mineralogy of Middle Siwalik Sequence in Mohand Area, Dehradun: Implication for Climate and Source Area,” In: R. Kumar, S. K. Ghosh and N. R. Phadtare, Eds., Siwalik Foreland Basin of Himalaya, Himalayan Geology, Special Publication, 1994, pp. 219-228.
[11]	A. Delgado and E. Reyes, “Oxygen and Hydrogen Isotope Composition in Clay Minerals: A Potential SingleMineral Geothermometer,” Geochimica et Cosmochimica Acta, Vol. 60, No. 21, 1996, pp. 4285-4289. doi:10.1016/S0016-7037(96)00260-8
[12]	A. R. Chaudhri, “Clay Mineralogy of the Nagthat Formation of the Chakrata Hills, Northwestern Himalaya,” Journal of Indian Association of Sedimentologist, Vol. 12, No. 2, 1997, pp. 261-266.
[13]	V. Raiverman and N. Suresh, “Clay Minerals Distribution in the Cenozoic Sequence of the Western Himalayan Foothills,” Journal of Indian Association of Sedimentologist, Vol. 16, No. 1, 1997, pp. 63-75.
[14]	L. A. Stern, C. P. Chamberlain, R. C. Reynolds and G. D. Johnson, “Oxygen Isotope Evidence of Climate Change from Pedogenic Clay Minerals in the Himalayan Molasse,” Geochimica et Cosmochimica Acta, Vol. 61, No. 4, 1997, pp. 731-744. doi:10.1016/S0016-7037(96)00367-5
[15]	N. Suresh, S. K. Ghosh, R. Kumar and S. J. Sangode, “Clay Mineral Distribution Pattern in Late Neogene Fluvial Sediments of Subathu Sub-Basin, Central Sector of Himalayan Foreland Basin: Implication for Provenance and Climatic Condition,” Sedimentary Geology, Vol. 163, No. 3-4, 2004, pp. 265-278. doi:10.1016/j.sedgeo.2003.07.006
[16]	S. Ahmed and S. I. Hasnain, “Textural, Mineralogical and Geochemical Characteristics of Sediment and Soil at High Altitude Catchment in the Garhwal Himalaya,” Geological Survey of India, Vol. 69, 2007, pp. 291-294.
[17]	L. J. Poppe, V. F. Paskevich, J. C. Hathaway and D. S. Blackwood, “A Laboratory Manual for X-Ray Powder Diffraction,” USGS Open File Report, 2002, pp. 1-41.
[18]	G. Switzer, J. M. Axelrod, M. L. Lindbergh and E. S. Larsen, “Tables of d-Spacings for Angle 2θ Cukα, Cukα1, Cukα2, Fekα, Fekα1 Fekα2,” United States Geological Survey Circulation, Reston, 1948.
[19]	G. M. Griffin, “Interpretation of X-Ray Diffraction Data,” In: R. E. Carver, Ed., Procedures in Sedimentary Petrology, Wiley Interscience, New York, 1971, pp. 541-569.
[20]	G. Brown, “The X-Ray Identification and Crystal Structure of Clay Minerals—A Symposium,” Mineralogical Society of London, London, 1961.
[21]	G. W. Brindley and G. Brown, “Crystal Structures of Clay Minerals and Their X-Ray Identification,” Mineralogical Society of London, London, 1980.
[22]	S. W. Bailey, G. W. Brindley, D. S. Fanning, H. Kodama and R. T. Martin, “Report of the Clay Mineral Society, Nomenclature Committee for 1982 and 1983,” Clays and Clay Minerals, Vol. 32, No. 3, 1984, pp. 239-240. doi:10.1346/CCMN.1984.0320316
[23]	G. Millot, “Geology of Clays,” Springer-Verlag, New York, 1970.
[24]	R. M. Quigley and R. T. Martin “Chloritised Weathering Products of the New England Glacial Till,” Clays and Clay Minerals, Vol. 10, 1963, pp. 107-116. doi:10.1346/CCMN.1961.0100110
[25]	J. J. Griffin and E. D. Goldberg, “Clay Mineral Distribution in the Pacific Ocean,” In: M. N. Hill, Ed., The Sea, Interscience Publishers, New York, 1963, pp. 728-741.
[26]	W. A. Deer, R. A. Howie and J. Zussman, “Rock-Forming Minerals,” John Wiley and Sons, New York, 1962, pp. 1-270.
[27]	G. Millot, “Geologic des Argles,” Mason and Cie., Paris, 1964.
[28]	C. E. Weaver, “Geologic Interpretation of Argillaceous Sediments, Pt.1, Origin and Significance of Clay Minerals in Sedimentary Rocks,” Bulletin of American Association of Petroleum Geology, Vol. 42, No. 2, 1958, pp. 254-271.
[29]	I. Barshad, “The Effect of a Variation in Precipitation on the Nature of Clay Minerals Formation in Soils from Acid and Basic Igneous Rocks,” In: L. Heller and A. Weiss, Eds., Proceedings of International Clay Conference, Israel Programme of Scientific Translation, Jerusalem, 1966, pp. 167-173.
[30]	I. Barshad and F. M. Kishk, “Chemical Composition of Soil Vermiculite Clays as Related to Their Genesis,” Contribution Mineral Petroleum, Vol. 24, No. 2, 1969, pp. 136-155. doi:10.1007/BF00376887
[31]	M. Singh, “Heavy Mineral Assemblage of the Pinjor Formation of the Northwestern Himalaya and Its Significance in Deciphering the Provenance of the Sediments,” Geosciences, Vol. 2, No. 6, 2012, pp. 157-163, DOI:10.5923/j.geo.20120206.02.
[32]	R. M. Garrels and C. L. Christ, “Solutions, Minerals, and Equilibria,” Freeman, Cooper and Company, San Francisco, 1965.
[33]	A. R. Chaudhri, “Tectonic Morphometric Studies as a Tool for Terrain Characterization in Himalayan Foothill Region—A Case Study,” Journal of Geological Society of India, Vol. 79, No. 2, 2012, pp. 210-218. doi:10.1007/s12594-012-0025-z
[34]	H. Sakai, W. Yahagi, R. Fujii, T. Hayashi and B. N. Upreti, “Pleistocene Rapid Uplift of the Himalayan Frontal Ranges Recorded in the Kathmandu and Siwalik Basins,” Palaeogeography, Palaeoclimatology, Palaeoecology, Vol. 241, No. 1, 2006, pp. 16-27. doi:10.1016/j.palaeo.2006.06.017
[35]	M. E. Raymo, W. F. Ruddiman and P. N. Froelich, “Influence of Late Cenozoic Mountain Building on Ocean Geochemical Cycles,” Geology, Vol. 16, No. 7, 1988, pp. 649-653. doi:10.1130/0091-7613(1988)016<0649:IOLCMB>2.3.CO;2
[36]	W. F. Ruddiman, “Tectonic Uplift and Climate Change,” Plenum Press, New York. 1997.
[37]	D. Kroon, T. Steens and S. R. Troelstra, “Onset of Monsoonal Related Upwelling in the Western Arabian Sea as Revealed by Planktonice Foraminifers,” Process Ocean Drilling Program Sciences Results, Vol. 117, 1991, pp. 257-263.
[38]	D. K. Rea, “Delivery of Himalayan Sediment to the Northern Indian Ocean and Its Relation to Global Climate, Sea Level, Uplift and Seawater Strontium,” In: R. A. Duncan, D. K. Rea, R. B. Kidd, U. von Rad and J. K. Weise, Eds., Synthesis of results from Scientific Drilling, AGU, Washington, 1992, pp. 387-402. doi:10.1029/GM070p0387
[39]	K. Amano and A. Tyra, “Two-Phase Uplift of Higher Himalayas since 17 Ma,” Geology, Vol. 20, No. 5, 1992, pp. 391-394. doi:10.1130/0091-7613(1992)020<0391:TPUOHH>2.3.CO;2
[40]	L. A. Derry and C. F. Lanord, “Himalayan Weathering and Erosion Fluxes; Climate and Tectonic Controls,” In: W. F. Ruddiman, Ed., Tectonic Uplift and Climate Change, Plenum, New York, 1997, pp. 290-312. doi:10.1007/978-1-4615-5935-1_12
[41]	P. D. Clift, L. Giosan, J. Blusztajn, I. H. Campbell, C. Allen, M. Pringle, A. R. Tabrez, M. Danish, M. M. Rabbani, A. Alizai, A. Carter and A. Luckge, “Holocene Erosion of Lesser Himalaya Triggered by Intensified Summer Monsoon,” Bulletin of Geological Society of America, Vol. 36, No. 1, 2008, pp. 79-82.
[42]	K. V. Hodges, C. Wobus, K. Ruhl, T. Schildgen and K. Whipple, “Quaternary Deformation, River Steepening, and Heavy Precipitation at the Front of the Higher Himalayan Ranges,” Earth and Planetary Science Letters, Vol. 220, No. 3-4, 2004, pp. 379-389, doi:10.1016/S0012-821X(04)00063-9
[43]	C. Wobus, A. Heimsath, K. Whipple and K. Hodges, “Active Out-Of-Sequence Thrust Faulting in the Central Nepalese Himalaya,” Nature, Vol. 434, No. 7036, 2005, pp. 1008-1011.
[44]	D. W. Burbank, A. E. Blythe, J. Putkonen, B. Pratt-Sitaula, E. Gabet, M. Oskins, A. Barros and T. P. Ojha, “Decoupling of Erosion and Precipitation in the Himalayas,” Nature, Vol. 426, No. 6967, 2003, pp. 652-655.
[45]	D. W. Burbank and G. D. Johnson, “The Late Cenozoic Chronology and Stratigraphic Development of the Kashmir Intermontane Basin, Northwestern Himalaya,” Palaeogeography, Palaeoclimatology, Palaeoecology, Vol. 43, No. 3-4, 1983, pp. 205-235. doi:10.1016/0031-0182(83)90012-3
[46]	R. S. Chaudhri, “Petrogenesis of Cenozoic Sediments of Northwestern Himalayas,” Geological Magazine, Vol. 108, No. 1, 1971, pp. 43-48. doi:10.1017/S0016756800050949
[47]	R. S. Chaudhri, “Heavy Mineral Distribution in the Pre-Cenozoic Sedimentary and Metasedimentary Formations of Solon-Kandaghat-Chail Region, Himachal Himalaya,” Symposium Sediment, Sedimentation and Sedimentary Environment, 1975, pp. 48-57.
[48]	M. L. Jackson, “Frequency Distribution of Clay Minerals in Major Soil Groups as Related to Factors of Soil Formation,” Clays and Clay Minerals, Vol. 6, 1959, pp. 133143. doi:10.1346/CCMN.1957.0060111
[49]	P. M. Hurley, D. G. Brookins, W. H. Pinson, S. R. Hearth and H. W. Fairbairn, “K-Ar Age Studies of Mississippi and Other River Sediments,” Geological Society of America Bulletin, Vol. 72, No. 12, 1961, pp. 1807-1816. doi:10.1130/0016-7606(1961)72[1807:KASOMA]2.0.CO;2
[50]	H. D. Foth and L. M. Truck, “Fundamentals of Soil Science,” Wiley Eastern Pvt. Ltd., New Delhi, 1973, pp. 1-454.
[51]	H. Milne and J. W. Earley, “Effect of Source and Environment on Clay Minerals,” Bulletin of American Association of Petroleum Geology, Vol. 42, No. 2, 1958, pp. 328-338.
[52]	H. F. Shaw, “Clay Minerals in Sediments and Sedimentary Rocks,” In: G. D. Hobson, Ed., Developments in Petroleum Geology, Allied Sciences Publication Ltd., London, 1980, pp. 53-85.
[53]	B. Velde, “Diagenetic Reactions in Clays,” In: A. Parker and B. W. Sellwood, Eds., Sediment Diagenesis, D. Reidel Publication Company, Dordrecht, 1983, pp. 215-268. doi:10.1007/978-94-009-7259-9_4
[54]	R. S. Chaudhri and C. K. Kalita, “X-Ray Study of Clay Minerals of the Krol Formation of the Mussoorie Hills, Kumaon Himalaya,” Indian Journal of Earth Sciences, Vol. 12, No. 4, 1985, pp. 239-248.
[55]	M. Singh, “Sedimentology of the Pinjor Formation Exposed in the Type Area Pinjore and Surrounding Regions,” Ph.D. Thesis, Kurukshetra University, Kurukshetra, 2009.
[56]	S. Clemens, W. Prell, D. Murray, G. Shimmield and G. Weedon, “Forcing Mechanisms of the Indian Ocean Monsoon,” Nature, Vol. 353, No. 6346, 1991, pp. 720-725. doi:10.1038/353720a0
[57]	J. Overpeck, D. Anderson, S. Trumbore and W. Prell, “The Southwest Indian Monsoon over the Last 18,000 Years,” Climate Dynamics, Vol. 12, No. 3, 1996, pp. 213225. doi:10.1007/BF00211619
[58]	H. Pang, Y. He, Z. Zhang, A. Lu and J. Gu, “The Origin of Summer Monsoon Rainfall at New Delhi by Deuterium Excess,” Hydrology and Earth System Sciences, Vol. 8, No. 1, 2004, pp. 115-118. doi:10.5194/hess-8-115-2004
[59]	M. T. Hren, M. Pagani, D. M. Erwin and M. Brandon, “Biomarker Reconstruction of the Early Eocene Paleotopography and Paleoclimate of the Northern Sierra Nevada,” Geology, Vol. 38, No. 1, 2010, pp. 7-10. doi:10.1130/G30215.1