Crystallization and Characterization of a New NonLinear Optical Crystal: L Proline Succinate (LPS)
P. Paramasivam, C. Ramachandra Raja
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DOI: 10.4236/jcpt.2012.21004   PDF   HTML     7,351 Downloads   16,229 Views   Citations

Abstract

In this analysis, the single crystal of L-Proline Succinate (LPS) has been successfully synthesized and the purity of ma- terial has been increased by repeated recrystallization process. Single crystal was grown by adopting the method of growing in a slow evaporation solution using water as solvent at room temperature. The LPS single crystal has been synthesized by taking equimolar quantity of L-Proline and succinic acid, by mixing them thoroughly using deionized water. The prepared concentrated solution was placed in an undisturbed condition, and the solution was inspected regu- larly. The single crystal has been harvested over a period of 1 month. The same crystal was characterized by different techniques for finding its suitability for device fabrications. The grown crystal was characterized by Single crystal XRD, Powder XRD, FTIR, UV-vis-NIR, DTA/TGA and SHG analyses, respectively. The observed results from various char- acterization show the suitability for NLO application. The second harmonic generation of this grown crystal was checked using Kurtz Perry technique which showed positive results. The UV cut-off wavelength and the decomposition temperature of this grown crystal were found to be good when compared with the existing organic crystals.

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P. Paramasivam and C. Raja, "Crystallization and Characterization of a New NonLinear Optical Crystal: L Proline Succinate (LPS)," Journal of Crystallization Process and Technology, Vol. 2 No. 1, 2012, pp. 21-24. doi: 10.4236/jcpt.2012.21004.

Conflicts of Interest

The authors declare no conflicts of interest.

References

[1] T. M. Kolev, D. Y. Yancheva and S. I. Stoyanov, “Syn- thesis and Spectral Elucidation of Some Pyridinium Be- taines of Squaric Acid: Potential Materials for Nonlinear Optical Appli-cations,” Advanced Functional Materials, Vol. 14, No. 8, 2004, pp. 799-805.
[2] B. Gutierrez, N. Rubio and C. Minguillon, “Evaluation of L-Proline Derivatives as Chiral Carriers in the Separation of Enantiomers by Membrane Techniques,” Journal of desalination, Vol. 200, No. 1-3, 2006, pp. 117-119.
[3] R. Hierle, J. Badan and J. Zyss, “Growth and Characterization of a New Material for Nonlinear Optics: Methy l-3-Nitro-4-Pyridine-1-Oxide (POM),” Journal of Crystal growth, Vol. 69, No. 2-3, 1984, pp. 545-554. doi:10.1016/0022-0248(84)90366-X
[4] T. kolev, B. Stambo-liyska and D. Yancheva, “Spectral and Structural Study of Two Acceptor-Substituted Pyri- dinium-Betaines of Squaric Acid: Promising Chromophores for Nonlinear Optical Applications,” Chemical Phy- sics, Vol. 324, No. 2-3, 2006, pp. 489-496. doi:10.1016/j.chemphys.2005.11.014
[5] F. Q. Meng, M. K. Lu, J. Chen, S. J. Zhang and H. Zeng, “Characterization of Linear and Nonlinear Optical Prop- erties of a New Single Crystal,” Solid State Communica- tions, Vol. 101, No. 12, 1997, pp. 925-928. doi:10.1016/S0038-1098(96)00702-8
[6] K. V. Krishna and M. Arivazhagan, “Vibrational and Nor- mal Coordinate Analysis of Xanthine and Hypoxanthine,” Indian Journal of Pure & Applied Physics, Vol. 42, No. 12, 2004, pp. 411-418.
[7] G. Socrates, “Infrared and Raman Characteristic Group Frequen-cies,” 3rd Edition, Wiley, Chichester, 2001.
[8] G. Varaasyi, “Assignments for Vibrational Spectra of Seven Hundred Ben-zene Derivatives,” Wiley, New York, 1974.
[9] S. Gunase-karan and D. Uthra, “Fourier Transform Infrared and Fourier Transform Raman Spectra and Normal Coordinate Analysis of Ethyleneimine,” Indian Journal of Pure & Applied Physics, Vol. 46, No. 2, 2008, pp. 100- 105.
[10] S. Krishnan, C. J. Raj, R. Robert, A. Ramanand and S. J. Das, “Growth and Characte-rization of Succinic Acid Single Crystals,” Crystal Research Technology, Vol. 42, No. 11, 2007, pp. 1087-1090. doi:10.1002/crat.200710981
[11] S. A. M. Britto Dhas and S. Natarajan, “Growth and Cha- racterization of L-Prolinium Tar-trate—A New Organic NLO Material,” Crystal Research Technology, Vol. 42, No. 5, 2007, pp. 471-476. doi:10.1002/crat.200610850
[12] C. R. Raja, P. Paramasivam and N. Vijayan, “Synthesis, Growth and Characterization of a New Nonlinear Optical Material: 4-Phenylpyridinium Hydrogen Squarate (4PHS),” Spectrochimica Acta Part A, Vol. 69, No. 4, 2008, pp. 1146-1149. doi:10.1016/j.saa.2007.06.014
[13] V. Krishnakumar, L. G. Prasad, R. Nagalakshmi, P. Mut- husamy, “Physicochemical Properties of Organic Non- linear Optical Crystal for Frequency Doubling: Glycine Acetamide,” Materials Letters, Vol. 63, No. 15, 2009, pp. 1255-1257. doi:10.1016/j.matlet.2009.02.052
[14] S. A. M. Britto Dhas and S. Natarajan, “Growth and Characterization of a New Organic NLO Material: Glycine Nitrate,” Optics Communications, Vol. 278, No. 2, 2007, pp. 434-438. doi:10.1016/j.optcom.2007.06.052
[15] T. Balakrishnan, R. R. Babu and K. Ramamurthi, “Grow- th, Structural, Optical and Thermal Properties of γ-Gly- cine Crystal,” Spectrochimica Acta Part A, Vol. 69, No. 4, 2008, pp. 1114-1118. doi:10.1016/j.saa.2007.06.025

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