International Journal of Organic Chemistry

Volume 7, Issue 2 (June 2017)

ISSN Print: 2161-4687   ISSN Online: 2161-4695

Google-based Impact Factor: 1.15  Citations  

Synthesis of Chiral Schiff Base Metal Complex Inducing CD and Elucidation of Structure of Adsorption on Surface of Gold Nanoparticles

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DOI: 10.4236/ijoc.2017.72013    2,138 Downloads   4,334 Views  Citations

ABSTRACT

We have prepared supramolecular systems of chiral Schiff base Ni(II), Cu(II), Zn(II) complexes and colloidal gold nanoparticles (AuNP) of 10 nm diameters. They demonstrated that direct adsorption of chiral Schiff base metal complex on the surface of AuNP owing to observation of clear induced CD spectra for the first time. We observed and discussed induced CD bands on AuNP from chiral Schiff base Ni(II), Cu(II), Zn(II) complexes.

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Oshima, M. , Matsuno, M. , Yuki, T. , Nobumitsu, S. , Haraguchi, T. and Akitsu, T. (2017) Synthesis of Chiral Schiff Base Metal Complex Inducing CD and Elucidation of Structure of Adsorption on Surface of Gold Nanoparticles. International Journal of Organic Chemistry, 7, 153-170. doi: 10.4236/ijoc.2017.72013.

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