Direct Colorimetric Detection of Hydrogen Peroxide Using 4-Nitrophenyl Boronic Acid or Its Pinacol Ester - American Journal of Analytical Chemistry

AJAC > Vol.2 No.8, December 2011

American Journal of Analytical Chemistry

Volume 2, Issue 8 (December 2011)

ISSN Print: 2156-8251 ISSN Online: 2156-8278

Google-based Impact Factor: 1.71 Citations h5-index & Ranking

Direct Colorimetric Detection of Hydrogen Peroxide Using 4-Nitrophenyl Boronic Acid or Its Pinacol Ester ()

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Download as PDF (Size: 923KB) PP. 879-884

DOI: 10.4236/ajac.2011.28101 10,073 Downloads 19,819 Views Citations

Author(s)

Gregory Su, Yibin Wei, Maolin Guo

Affiliation(s)

ABSTRACT

A colorimetric method for the direct determination of hydrogen peroxide in aqueous solution is described. H2O2 stoichiometrically converts 4-nitrophenyl boronic acid or 4-nitrophenyl boronic acid pinacol ester into 4-nitrophenol, which can be quantified by measuring the absorption at 400 nm in neutral or basic media. The reactions proceed fast under basic conditions and complete in 2 minutes to at pH 11 and 80?C. The linear range for the colorimetric method extends beyond 1.0 to 40 µM H2O2, and the limit of detection is ~1.0 µM H2O2. This method offers a convenient and practical process for rapid determination of hydrogen peroxide in aqueous media. Compared to many other techniques in H2O2 detection, this process is a direct measurement of H2O2, and is relatively unaffected by the presence of various salts, metal ions and the chelator EDTA.

KEYWORDS

Hydrogen Peroxide Detection, 4-Nitrophenyl Boronic Acid, 4-Nitrophenyl Boronic Acid Pinacol Ester, 4-Nitrophenol, Colorimetric Method

Share and Cite:

Su, G. , Wei, Y. and Guo, M. (2011) Direct Colorimetric Detection of Hydrogen Peroxide Using 4-Nitrophenyl Boronic Acid or Its Pinacol Ester. American Journal of Analytical Chemistry, 2, 879-884. doi: 10.4236/ajac.2011.28101.

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