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Dicyclopentamethylenethiuram Disulfide as Precursor of Mononuclear Complexes: Oxidative Cleavage of Metal-Metal Bond in [CpMo(CO)3]2 and Molecular Structure of cis-[CpMo(CO)2{S2C-N(CH2)5}]

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DOI: 10.4236/csta.2017.64006    414 Downloads   741 Views Citations

ABSTRACT

The reaction of [CpMo(CO)3]2 with dicyclopentamethylenethiuram disulfide in refluxing xylene resulted a novel mono nuclear complex,
cis-[(CpMo(CO)2{S2C-N(CH2)5}] as red crystals in moderate yield. The compound was formed by the oxidative cleavage of metal-metal bond in [CpMo(CO)3]2 together with a reductive sulfur-sulfur bond scission in the ligand.

Cite this paper

Karim, M. , Islam, S. , RafikulIslam, M. , Karim, M. and Siddiquee, T. (2017) Dicyclopentamethylenethiuram Disulfide as Precursor of Mononuclear Complexes: Oxidative Cleavage of Metal-Metal Bond in [CpMo(CO)3]2 and Molecular Structure of cis-[CpMo(CO)2{S2C-N(CH2)5}]. Crystal Structure Theory and Applications, 6, 67-72. doi: 10.4236/csta.2017.64006.

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