Synthesis and Characterization of New Chiral Monoanionic [ON] Ancillary Phenolate Ligands

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DOI: 10.4236/ijoc.2014.43020    3,723 Downloads   4,802 Views  Citations

ABSTRACT

Three new chiral monoanionic [ON] ancillary phenolate ligands with varying pendant arms have been synthesized in moderate to high yields (50% - 85%) via Mannich-type condensation reaction of chiral substituted phenol, formaldehyde and (+)-bis-[(R)-1-phenylethyl]amine. These new organic compounds were fully characterized via nuclear magnetic resonance spectroscopy (1H and 13C) and elemental analysis. The newly synthesized ligands are suitable candidates for metal-catalyzed ring-opening of lactones and asymmetric catalysis.

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Binda, P. and Glover, L. (2014) Synthesis and Characterization of New Chiral Monoanionic [ON] Ancillary Phenolate Ligands. International Journal of Organic Chemistry, 4, 182-188. doi: 10.4236/ijoc.2014.43020.

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