The employment of maximum power point tracking techniques in the photovoltaic power systems is well known and even of immense importance. There are various techniques to track the maximum power point reported in several literatures. In such context, there is an increasing interest in developing a more appropriate and effective maximum power point tracking control methodology to ensure that the photovoltaic arrays guarantee as much of their available output power as possible to the load for any temperature and solar radiation levels. In this paper, theoretical details of the work, carried out to develop and implement a maximum power point tracking controller using neural networks for a stand-alone photovoltaic system, are presented. Attention has been also paid to the command of the power converter to achieve maximum power point tracking. Simulations results, using Matlab/Simulink software, presented for this approach under rapid variation of insolation and temperature conditions, confirm the effectiveness of the proposed method both in terms of efficiency and fast response time. Negligible oscillations around the maximum power point and easy implementation are the main advantages of the proposed maximum power point tracking (MPPT) control method.