La2O3 Catalyzed Oxidation of Alcohols

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DOI: 10.4236/ijoc.2011.12008    7,236 Downloads   14,592 Views  Citations

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ABSTRACT

A variety of aromatic, aliphatic and conjugated alcohols were transformed to the corresponding carboxylic acids and ketones with a quantitative conversion in high yields with 70% t-BuOOH solution is water in the presence of catalytic amounts of La2O3. This method possesses a wide range of capabilities since it can be used with other functional groups which may not tolerate oxidative conditions, involves fairly simple method for work-up, exhibits chemoselectivity and proceeds under ambient conditions. The resulting products are obtained in good yields within reasonable time.

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Gowda, R. and Chakraborty, D. (2011) La2O3 Catalyzed Oxidation of Alcohols. International Journal of Organic Chemistry, 1, 41-46. doi: 10.4236/ijoc.2011.12008.

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