Unification of the Quadratic Model Equations of the Inhibition Characteristics of Acidified Ocimum Basilicum on the Corrosion Behaviour of Mild Steel

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DOI: 10.4236/jmmce.2013.16057    3,689 Downloads   5,545 Views  Citations

ABSTRACT

An attempt has been made at unifying the resulting quadratic models from the study of the correlation behavior of the inhibition characteristics of acidified ocimum basilicum on conventional mild steel. Weight-loss corrosion technique was employed in obtaining the corrosion penetration rate using the equation: cpr = . Subsequently, the quadratic models were developed by using a computer-aided statistical modeling technique (International Business Machine (IBM)’s SPSS version 17.0). The results obtained showed a nearly perfect positive correlation with a correlation coefficient in the range of 0.986 ≤ R ≤ 0.996 which depicts that R ≥ 1. Also, the coefficient of determination fell within the range of 0.972 ≤ R2 ≤ 0.992 showing that approximately 97% to 99% of the total variation in passivation rate was accounted for by corresponding variation in exposure time, leaving out only between 3% and 1% to extraneous factors that are not incorporated into the model equations. The equations were further unified into a generalized form using MathCAD 7.0 and the resulting equation was y = 1.032 - 0.002t + 1.899 × 10-6t2 with a R2 value of 0.935 indicating a well-correlated relationship. With this, a new frontier on corrosion studies has emerged typifying a classical departure from previously long-held assumption that corrosion behaviours at room temperature were only logarithmic.

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M. Nwankwo, P. Nwobasi, P. Offor and N. Idenyi, "Unification of the Quadratic Model Equations of the Inhibition Characteristics of Acidified Ocimum Basilicum on the Corrosion Behaviour of Mild Steel," Journal of Minerals and Materials Characterization and Engineering, Vol. 1 No. 6, 2013, pp. 367-373. doi: 10.4236/jmmce.2013.16057.

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