Dr. Alvaro J. Pardey
Chemistry
Department, Faculty of Science
Universidad
Central de Venezuela, Venezuela
Retired
Professor
Email: alvaro.pardey@ciens.ucv.ve, alvaro.pardey@gmail.com
Qualifications
1985 Ph.D.,
University of California, Inorganic Chemistry
1975 B.Sc., Universidad de los
Andes, Department of Chemistry, Venezuela
Publications(selected)
-
A. J. Pardey, B. Morillo, J. E. Yánez, J.
Alvarez, M. C. Ortega, C. Longo, “Kinetics study of the hydrodechlorination of
chlorobenzene catalyzed by an immobilized copper catalyst”, Catal. Lett., 104, 141-150 (2005).
-
G. C. Uzcátegui, F. Hung, M. C. Ortega, A. J. Pardey, C. Longo, P. Aguirre, S.
A. Moya, “Reppe reaction catalyzed by soluble carbonylrhodium complexes”, J. Chil. Chem. Soc., 50, 647-650 (2005).
-
D.
Moronta, M. Martín-Landrove, C. Gago, A. J. Pardey, “Proposition of two layered ionic
structures, with xy disorder but z ordered, in a quasi-liquid system”, Rev. Mex.
Fis., 52, 208-210 (2006).
-
A. J.
Pardey, F. Hung-Low, G. C. Uzcátegui, M. C. Ortega, C. Longo, “Mechanism
of the hydroxycarbonylation of 1-hexene catalyzed by immobilized rhodium complexes of pyridine ligands”, React. Kinet. Catal. Lett., 88, 203-208 (2006).
-
F. Hung-Low, G. C. Uzcátegui, M. C. Ortega,
J. Alvarez, A. J. Pardey, C.
Longo, “Catalyst Concentration Effect on the Hydroesterification and
Hydroformylation-Acetalization of 1-Hexene by a Rh Complex”, React. Kinet. Catal. Lett., 88, 143-148 (2006).
-
A. J. Pardey, J. Yánez, A. B. Rivas, J.
Alvarez, M. C. Ortega, C. Longo, R. P. Feazell, “Reduction of Nitrobenzene Catalyzed by Immobilized Copper Catalyst under
Carbon Monoxide and Water”, J. Coord. Chem.,
59, 1719-1728 (2006).
-
M. E. Farkas, E. Rodríguez, C. Longo, M.
Monasterios, M. C. Ortega, A. B. Rivas, R. López, A. J. Pardey, S. A. Moya,
“Reduction of 5-Nitrofurans compounds catalyzed by [Rh(COD)(2-pic)2]PF6 complex immobilized on
poly(4-vinylpyridine) under water gas shift reaction conditions. A relationship
with antibacterial activity”, J. Chil.
Chem. Soc., 51, 829-835 (2006).
-
A. J. Pardey, M. A Moreno, M. Lutz, M. Haukka, R. Atencio, “Undecacarbonyl(pirydine-kN)-tetrahedro-tetrairidium
(4Ir-Ir)”, Acta Cryst. E, 62, m838-m840
(2006).
-
J. Gajardo, J. C. Araya, S. A. Moya, A. J. Pardey, V. Guerchais, H. Le Bozec, P. Aguirre, “New polynuclear carbonyl ruthenium(II) complexes
derived from 1,8-naphthyridine”, Appl. Organometal. Chem., 20, 272-276 (2006).
-
F.
Hung-Low, G. C. Uzcátegui, M. C. Ortega, J. Alvarez, A. J. Pardey, C. Longo, “Hidroesterificación e
hidroformilación-acetalization de 1-hexeno en etanol catalizada por complejos
de rodio inmovilizados en poli(4-vinilpiridina)”. Ciencia, 15, 85-92 (2007).
-
M. Bartolini, J. Molina, P. Sojo, M. C.
Ortega, A. J. Pardey, C. Longo,
S. A. Moya, R. P. Feazell, “Nitrobenzene Reduction by Soluble Carbonylrhodium
Complexes of Methyl and Dimethyl Pyridine Ligands”, J. Chil. Chem. Soc., 52, 1254-1256 (2007).
-
M. A. F. Hernandez-Gruel, G. Gracia-Arruego, A.
B. Rivas, I. T. Dobrinovich, F. J. Lahoz, A. J. Pardey, L. A. Oro, J. J.
Pérez-Torrente, “Novel Gem-Dithiolate-Bridged
Rhodium Hydroformylation Catalyst: Bridging the Gap in Dinuclear Rhodium
Thiolate Chemistry”, Eur. J. Inorg. Chem., 5677-5683 (2007).
-
A. J.
Pardey, N. Manosalva, M. Bartolini, J. Molina, M. C. Ortega, L. D’Ornelas, C. Chinea, C. Scott, P. Betancourt, C. Urbina, D.
Moronta, R. P. Feazell, “Synthesis, characterization and catalytic
properties of coordination complexes based on [Mo(CO)3(CH3CN)3]
and poly(4-vinylpyridine)”, Catal. Lett., 122, 274-280 (2008).
-
G. Gascón, M. C. Ortega, J. D. Suárez, A. J. Pardey,
C. Longo, “Catalysis of the water gas shift reaction by cis-[Rh(co)2(amine)2](pf6) complexes in an aqueous
tetrabutylammonium hydrogensulfate solution”, React. Kinet. Catal. Lett., 94, 85-89 (2008).
-
A. B.
Rivas, J. M. Gascón, F. J. Lahoz, A. J. Pardey, L. A. Oro, J. J. Pérez-Torrente,
“Synthesis, Structural Characterization and Ligand
Replacement Reactions of Gem-Dithiolato-Bridged Rhodium and Iridium Complexes”, Inorg. Chem., 47, 6090-6104
(2008).
-
S. A. Moya, J. Gajardo, J. C.
Araya, J. J.
Cornejo, V. Guerchais, H. Le
Bozec, J. C. Bayón,
A. J.
Pardey, P. Aguirre, “Synthesis
and characterization of new complexes of the type [Ru(CO)2Cl2 (2-phenyl-1,8-naphthyridine-kN) (2-phenyl-1,8-naphthyridine-kN”, Preliminary applications in homogeneous catalysis”, Appl. Organometal. Chem., 22, 471-478 (2008).
-
G. Gascón, M. C. Ortega, J. D. Suárez, A.
J. Pardey, C. Longo, S. A. Moya, “Carbonylation of 1-hexene catalyzed by cis-[Rh(CO)2(amine)2](PF6)
complexes in aqueous tetrabutylammonium hydrogensulfate solutions”, J. Mol. Catal. A, 291, 49-56 (2008).
-
A. J.
Pardey, J. D. Suárez, G. Gascón, M. C. Ortega, C. Longo, S. A. Moya,
“Carbonylation of naphtha by a rhodium complex immobilized on
poly(4-vinylpyridine)”, Catal. Lett. 126, 112-118 (2008).
-
A. B. Rivas, J. J. Pérez-Torrente, A. J. Pardey, A. M.
Masdeu-Bultó, M. Dieguez, L. A. Oro, “Hydroformylation of
oct-1-ene catalyzed by dinuclear gem-dithiolato-bridged rhodium(I) complexes and phosphorous donor ligands”, J. Mol. Catal. A, 300, 121-131 (2009).
-
R. Vargas, A. B. Rivas, J. D. Suárez, I.
Chaparros, M. C. Ortega, A.
J. Pardey, C. Longo, J. Pérez Torrente,
L. A. Oro, “Hydroformylation
of hex-1-ene by a dinuclear gem-dithiolato-bridged rhodium
catalyst under CO/H2O conditions”, Catal. Lett., 130, 470-475 (2009).
-
P. J. Baricelli, S. Ricardes, L. G. Melean, V.
Guanipa, M. Rodriguez, C. Romero, A. J. Pardey, S. A. Moya, M. Rosales, “Mo(CO)3(NCMe)(PPh3)2:
Synthesis, X-ray structure and evaluation of its catalytic activity for the
homogeneous hydrogenation of olefins and their mixtures”, J. Organometal. Chem., 694, 3381-3385 (2009).
-
A. J. Pardey, C. Longo, “Catalysis by rhodium complexes bearing pyridine ligands:
Mechanistic aspects”. Review paper. Coord.
Chem. Rev., 254, 254-272 (2010).
-
A. J. Pardey, J. D. Suarez,
M. C. Ortega, C. Longo, J. J. Perez-Torrente, L. A Oro, “Hydroformylation of
synthetic naphtha catalyzed by dinuclear gem-dithiolato-bridged rhodium(I)
complex”, The Open
Catalysis Journal, 3, 44-49 (2010).
-
S. A. Moya, R. Pastene, R. Sartori, R. Schmidt, C. Díaz, E. Santander, P. Aguirre, A. J. Pardey, C. Longo,
P. J. Baricelli, “Synthesis,
characterization and preliminary catalytic properties of new copper(I)
complexes of [Cu(pyrazolyl)2]X type”, J. Chil.Chem. Soc., 55(4), 479-482 (2010).
-
D. M. Venuti, M. Ortega, A. Pardey, C. Longo,
“Producción de derivados oxigenados del ciclohexeno a través de reacciones de
carbonilación catalizadas por agregados de rodio soportados en
poli(4-vinilpiridina)”, Ciencia, 22,
79 - 85, (2014).