Surface chemistry,
study of chemical reactions in which the reactants are first adsorbed onto a
surface medium (see adsorption) that then acts as a catalyst for the reaction;
after the reaction the products are desorbed and the surface is left unchanged.
Since the entire reaction takes place on the surface, the amount of surface
area of catalyst per unit weight determines the effectiveness of the surface in
the reaction. Some silica surfaces have over 200 square meters of surface area
per gram. An example of a surface reaction is the reaction of an unsaturated
organic molecule with hydrogen on finely divided platinum or with bromine on
finely divided silica. Enzyme reactions can, in principle, also be considered
surface reactions, since the reaction takes place on the enzyme surface after
the enzyme has bound the reactants; however, usually only heterogeneous
(two-phase) reactions are considered true surface reactions, while enzyme
reactions are homogeneous (one-phase) systems.
In the present
book, ten typical literatures about surface chemistry published on
international authoritative journals were selected to introduce the worldwide
newest progress, which contains reviews or original researches on surface
science, geochemistry, electrochemistry, chemical engineering, ect.
We hope this book can demonstrate advances in surface chemistry as well as give
references to the researchers, students and other related people.