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https://doi.org/10.1016/j.corsci.2011.05.008

has been cited by the following article:

• TITLE: Synthesis and Characterization of Superhydrophobic-Superoleophobic and Anti-Corrosion Coatings via Sol-Gel Process

  AUTHORS: Mohammad Reza Heshmati, Sahar Amiri, Maryam Hosseini-Zori

  KEYWORDS: Super-Hydrophobic, Super-Oleophobic, Sol-Gel, Perfluoroalkyl Polymer (1H, 1H, 2H, 2H)-Perfluorooctyltriethoxysilane, Contact Angle

  JOURNAL NAME: Open Journal of Organic Polymer Materials, Vol.10 No.1, January 8, 2020

  ABSTRACT: Superoleophobic nanocomposite coatings with improved hydrophobic properties were obtained by incorporation of a perfluoroalkyl polymer in hybrid sol-gel matrix containing silica and titania nanoparticles. SiO2 and TiO2 nanoparticles were synthesized based on sol-gel precursors utilizing tetraethyl orthosilicate, 3-glycidoxypropyl trimethoxysilane, and tetra (n-butyl orthotitanate). SEM and EDX images of the coating demonstrated that a Silica nanosphere had been aggregated in superporous structure. The analysis results show that nano-sized inorganic particles (10 - 20 nm) have a uniform distribution and dispersion. By increasing the PFOTES, the oleophobicity of coatings increased due to lowering of surface energy in the presence of fluoropolymer. Results of EIS measurement show that PFOTES and TiO2 nanoparticles increased anti-corrosion property of hybrid coatings. This method introduces a simple way to produce water- and oil-repellent self-cleaning coatings on large areas of different substrates like glass, ceramic, metal and composites.