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has been cited by the following article:

• TITLE: Fabrication of Microspheres Based on Poly(4-butyltriphenylamine) Blends with Poly(methyl methacrylate) and Block Copolymer by Solvent Evaporation Method

  AUTHORS: Hossein Taherzadeh, Kenji Ogino

  KEYWORDS: Microsphere, Morphology, Polymer Blend, Block Copolymer, Poly(4-butyltriphenylamine)

  JOURNAL NAME: Open Journal of Organic Polymer Materials, Vol.5 No.2, March 23, 2015

  ABSTRACT: Micron-sized polymer particles from single poly(4-butyltriphenylamine) (PBTPA) homopolymer, binary polymer blend [PBTPA/poly(methyl methacrylate) (PMMA)], and ternary polymer blend (PBTPA/PBTPA-b-PMMA/PMMA) via a solvent evaporation method, and the surface morphologies and inside structure of resulting particles were investigated. Spherical homopolymer particles with smooth surface were resulted from PBTPA with low molecular weight. In the case of binary blends (PBTPA/PMMA = 1/1), Janus (low molecular weight) and dumbbell (high molecular weight) type morphologies were observed. The particles based on ternary blends containing PBTPA-b-PMMA showed core-shell type morphologies (PMMA; core, PBTPA; shell). Degree of engulfment of PMMArich domain increased with the content of the block copolymer. The decrease of domain size was not observed although the block copolymer had a suitable structure as a compatibilizer for the blend. It was also found that the initial concentration of polymer solution had an effect on the final morphology.