M. A. Hughes and R. K. Biswas, “The Kinetics of Vanadium(IV) Extraction in the Acidic Sulphate-D2EHPAn-Heptane System Using the Rotating Diffusion Cell Technique,” Hydrometallurgy, Vol. 26, No. 3, 1991, pp. 281-297. doi:10.1016/0304-386X(91)90005-7

has been cited by the following article:

• TITLE: Liquid-Liquid Extraction of V(IV) from Sulphate Medium by Cyanex 301 Dissolved in Kerosene

  AUTHORS: Ranjit Kumar Biswas, Aneek Krishna Karmakar

  KEYWORDS: Extraction Equilibrium; Vanadium(IV); Cyanex 301; Kerosene; Sulphate

  JOURNAL NAME: International Journal of Nonferrous Metallurgy, Vol.2 No.1, January 25, 2013

  ABSTRACT: The equilibrium of extraction of V(IV) in the V(IV)- SO42- (H+, Na+)-Cyanex 301 (HA)-kerosene system has been studied. Significant extraction occurs above pH 1 within 10 min. CD (extraction ratio at constant pH(eq) and [HA](o,eq)) value is slightly decreased with increasing [V(IV)](ini). CD is found to be directly proportional to [H+]-n (n ≤ 2), [HA] 2 and (1+1.58 [SO42-]). The process is endothermic (DH = 16 kJ/mol). Apparent Kexvalues at 303 K are 10-1.419 and 10-0.94 in 0.10 and 1.50 mol/L SO42- medium, respectively. The loading capacity is calculated to be7.87 gV(IV) per100 g Cyanex 301. Kerosene appears as the best diluent. Stripping to the extents of 100%, 94% and 97.7% are possible in single stage by 1 mol/L H2SO4, HCl and HNO3, respectively. Separations of V(IV) from Cu(II) (at pH 0), Zn(II) (at pH 0.5) and Fe(III) (at pH 1.0) by Cyanex 301 are possible.