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http://dx.doi.org/10.1007/s00216-002-1243-9

has been cited by the following article:

• TITLE: Homogeneous Liquid-Liquid Extraction (HoLLE) of Palladium in Real Plating Wastewater for Recovery

  AUTHORS: Takeshi Kato, Shukuro Igarashi, Osamu Ohno, Shotaro Saito, Ryo Ando

  KEYWORDS: Homogeneous Liquid-Liquid Extraction, HoLLE, Zonyl FSA, Surfactant, Real Plating Wastewater

  JOURNAL NAME: Journal of Environmental Protection, Vol.7 No.2, February 26, 2016

  ABSTRACT: On the basis of homogeneous liquid-liquid extraction (HoLLE) with Zonyl FSA to plating water containing 1 mg palladium, 96.6% of the palladium was extracted into the sedimented liquid phase. After phase separation, the volume ratio (Va/Vs) of the aqueous phase (Va) and the sedimented liquid phase (Vs) was 556 (50 mL → 0.09 mL). The assessment of the potential implementation of this procedure to wastewater treatment showed that HoLLE was satisfactorily achieved when the volume was scaled up to 1000 mL. Moreover, HoLLE was conducted to real palladium plating wastewater generated in the plating industry. 94.5% of the palladium was extracted into the sedimented liquid phase. After phase separation, the volume ratio (Va/Vs) of the aqueous phase (Va) and the sedimented liquid phase (Vs) was 500 (50 mL → 0.1 mL). In addition, HoLLE could separate palladium from coexisting metals in real plating wastewater. This knowledge is expected to lead to the development of new separation and concentration technologies of rare metals from real plating wastewater.