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Author(s): |
Zhong-qiang Zhang, College of Chemical Engineering, HengShui University, HeBei Province, HengShui City, 053000, P.R. China
Zhan-rong Liu, College of Chemical Engineering, ShiJiaZhuang University, HeBei Province, ShiJiaZhuang City, 050035, P.R. China
Shu-qiong Wang, College of Chemical Engineering, HengShui University, HeBei Province, HengShui City, 053000, P.R. China
Shu-ping Zhang, HengShui Vocational Technology College, HeBei Province, HengShui City, 053000, P.R. China |
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Abstract: |
Zn2(bim)4 and Co2(bim)4 (bim=benzimidazole ion) were prepared by the solvothermal method. They are all 2D structures. Zn2 (bim)4 is connected to 2D structure by the unit Zn (bim)4. Zn（II）is connected by four bims (bim= benzimidazole ion). Zn2 (bim)4 is gridding structure. The molecular formula is C28N8Zn2H20, The crystal system of Zn2 (bim)4 is: The space group of Zn2 (bim)4 is C2/c, a = 16.1013(4) ?, b =16.0993(4) ? , c = 19.7514(5)? ,α = 90.00°, β = 96.257(2)°, γ = 90.00°, V = 5089.5(2) ?3 , Z = 8. Zn2 (bim)4 and Co 2 (bim)4 were the same structures that were proved by XRPD, IR, ICP, element analyse and TGA. The Fluorescence properties of Zn2 (bim)4 and Co2 (bim)4 were investigated.
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