Proceedings of the 7th National Conference on Functional Materials and Applications (FMA 2010 E-BOOK)

Changsha,China,10.16-10.18,2010

ISBN: 978-1-935068-41-9 Scientific Research Publishing, USA

E-Book 2313pp Pub. Date: October 2010

Category: Chemistry & Materials Science

Price: $360

Title: The Catalytic Properties for Synthesis of Ethylene Glycol Diacetate of Amidoxime Fibers Supported-Fe(III) Complex
Source: Proceedings of the 7th National Conference on Functional Materials and Applications (FMA 2010 E-BOOK) (pp 666-669)
Author(s): Ya Huang, college of Bioengineering & Chemical Engineering, Anhui Polytechnic University,,Wuhu,China
Zhi-chuan Wu, college of Bioengineering & Chemical Engineering, Anhui Polytechnic University,,Wuhu,China
Yao Xu, college of Bioengineering & Chemical Engineering, Anhui Polytechnic University,,Wuhu,China
Qi Wu, college of Bioengineering & Chemical Engineering, Anhui Polytechnic University,,Wuhu,China
Lan-lan Wang, college of Bioengineering & Chemical Engineering, Anhui Polytechnic University,,Wuhu,China
Abstract: Amidoxime Fibers Supported-Fe(III) Complex(AOFs-Fe(III)) was synthesized by reaction of Amidoxime fibers and Fe2(SO4)3 solution. Its Catalytic performance for Synthesis of Ethylene Glycol Diacetate was investigated under different conditions. The results show that AOFs-Fe(III) has a high catalytic activity for the reaction, repeated use and regeneration. The optimum conditions were as followed: the molar ratio of acid and alcohol was 6:1, the amount of cyclohexane was 20ml, the reaction time was 4.5h and the amount of catalyst was 1g. Under optimum conditions, the yield of products was 39.7%. The product was characterized by refractive index and FTIR.
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