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Coordination Interaction between Rare Earth and/or Transition Metal Centers and Thiophene Series Oligomer Derivatives in Ultrathin Langmuir-Blodgett Films

DOI: 10.4236/jmp.2013.412A3002    3,666 Downloads   5,495 Views   Citations

ABSTRACT

It has been shown by thermodynamic and electro-chemical methods that coordination interactions are involved in the process of incorporation of rare-earth elements and/or Fe into Langmuir monolayers of oligomer with alkyl fragment. A coordination mechanism, which is responsible for self-organization of octahedral Fe(II)-complexes of nano-cyclic ligands obtained from oligomer of thiophene pyrrole series derivatives in compressed Langmuir monolayers has been proposed. It has been established that a coordinational-polymeric hexagonal network of nano-cyclic ligands with metal centers is formed at the phase transition when compressing the Langmuir monolayers of thiophene pyrrole series oligomer with alkyl fragment on surface of subphase with rare-earth (Sm, Er, Ce) and/or Fe ions.

Conflicts of Interest

The authors declare no conflicts of interest.

Cite this paper

H. Grushevskaya, I. Lipnevich and T. Orekhovskaya, "Coordination Interaction between Rare Earth and/or Transition Metal Centers and Thiophene Series Oligomer Derivatives in Ultrathin Langmuir-Blodgett Films," Journal of Modern Physics, Vol. 4 No. 12C, 2013, pp. 7-17. doi: 10.4236/jmp.2013.412A3002.

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