Forming Stages of Polycrystalline TiN Films Depending on the Nitrogen Concentration in Mixed Gas
Anna L. Kameneva
.
DOI: 10.4236/msa.2011.21002   PDF    HTML     7,738 Downloads   11,477 Views   Citations

Abstract

The influence of nitrogen concentration in mixed gas on temperature conditions, structure and phase composition of the TiN film deposited by arc spraying has been investigated. By electron microscopic investigations and X-ray diffraction phase analysis was recognized forming stages and structuring process of the film with main cubic phase (111) TiN. It was discovered that forming stages and process of structuring of ion-plasma TiN films are affected by both film temperature and its rate of heating.

Share and Cite:

A. Kameneva, "Forming Stages of Polycrystalline TiN Films Depending on the Nitrogen Concentration in Mixed Gas," Materials Sciences and Applications, Vol. 2 No. 1, 2011, pp. 6-13. doi: 10.4236/msa.2011.21002.

Conflicts of Interest

The authors declare no conflicts of interest.

References

[1] A. F. Belyanin and M. I. Samoylovich, “Diamond and Diamond-Like Materials Films: Formation, Structure and Applications in Electronics,” (In Russia), CRTI Technomash, Moscow, 2004.
[2] P. H. Mayrhofer, F. Kunc, J. Musil and C. Mitterer, “A Comparative Study on Reactive and Non-Reactive Unbalanced Magnetron Sputter Deposition of TiN Coatings,” Thin Solid Films, Vol. 415, No. 1-2, 2002, pp. 151-159. doi:10.1016/S0040-6090(02)00511-4
[3] J. Musil, “Hard and Superhard Nanocomposite Coatings,” Surface and Coatings Technology, Vol. 125, No. 1-3, 2000, pp. 322-330. doi:10.1016/S0257-8972(99)00586-1
[4] I. Petrov, P. B. Varna, L. Hultman and J. E. Greene, “Microstructural Evolution during Film Growth,” Journal of Vacuum Science and Technology A, Vol. 21, No. 5, 2003, pp. 117-128. doi:10.1116/1.1601610
[5] J. Thornton, “High-Rate Thick-Film Growth,” Annual Review of Materials Science, Vol. 7, 1977, pp. 239-260. doi:10.1146/annurev.ms.07.080177.001323
[6] R. Messier, A. P. Giri and R. A. Roy, “Revised Structure Zone Model for Thin Film Physical Structure,” Journal of Vacuum Science and Technology A, Vol. 2, 1984, pp. 500-503. doi:10.1116/1.572604
[7] J. A. Thornton, “The Microstructure of Sputter-Deposited Coatings,” Journal of Vacuum Science and Technology A, Vol. 4, No. 6, 1986, pp. 3059-3056. doi:10.1116/1.573628
[8] P. B. Barna and M. Adamik, “Fundamental Structure Forming Phenomena of Policrystalline Films and the Structure Zone Models,” Thin Solid Films, Vol. 317, 1998, pp. 27-33. doi:10.1016/S0040-6090(97)00503-8
[9] S. Kadlec, J. Musil and J. Vysko?il, “Growth and Properties of Hard Coating Prepared by Physical Vapor Deposition Methods,” Surface and Coatings Technology, Vol. 54-55, 1992, pp. 287-296.
[10] L. I. Maissel, “Handbook of Thin Films,” McGraw-Hill, New York, 1983.
[11] R. Messier, “Toward Quantification of Thin Film Morphology,” Journal of Vacuum Science and Technology A, Vol. 4, No. 3, 1986, pp. 490-495. doi:10.1116/1.573866
[12] M. Stüber, H. Leiste, S. Ulrich, H. Holleck and D. Schild, “Microstructure and Properties of Low Friction TiC-C Nanocomposite Coatings Deposited by Magnetron Sputtering,” Surface and Coatings Technology, Vol. 150, No. 2-3, 2002, pp. 218-226. doi:10.1016/S0257-8972(01)01493-1
[13] V. N. Antsiferov and A. L. Kameneva, “Experimental Study of the Structure of Multicomponent Nanostructured Coatings on the Basis of Ti-Zr-N Alloys Formed by Ionic Plasma Methods,” Russian Journal of Non-Ferrous Metals, Vol. 48, No. 6, 2007, pp. 488-495. doi:10.3103/S1067821207060211
[14] D. V. Shtansky, E. A. Levashov, K. Kaneko and Y. Ikuhara, “Characterization of Nanostructured Multiphase Ti-Al-B-N Thin Films with Extremely Small Grain Size,” Surface and Coatings Technology, Vol. 148, No. 2-3, 2001, pp. 206-215. doi:10.1016/S0257-8972(01)01341-X
[15] D. V. Shtansky, E. A. Levashov, A. N. Sheveiko and J. J. Moore, “Synthesis and Characterization of Ti-Si-C-N Films,” Metallurgical and Materials Transaction A, Vol. 30, No. 9, 1999, pp. 2439-2447. doi:10.1007/s11661-999-0252-0
[16] A. Gupper, A. Fernandez, С. Fernandez-Ramos, F. Hofer, С. Mitterer and P. Warbichler, “Characterization of Nanocomposite Coatings in the System Ti-B-N by Analytical Electron Microscopy and X-Ray Photoelectron Spectroscopy,” Monatshefte für Chemie/Chemical Monthly, Vol. 133, No. 6, 2002, pp. 837-848.
[17] T. P. Mollart, P. N. Gibson and M. A. Baker, “An EXAFS and XRD Study of the Structure of Nanocrystalline Ti-B-N Thin Films,” Journal of Physics D: Applied Physics, Vol. 30, No. 13, 1997, pp. 1827-1832. doi:10.1088/0022-3727/30/13/001
[18] W. Gissler. “Structure and Properties of Ti-B-N Coatings,” Surface and Coatings Technology, Vol. 68-69, 1994, pp. 556-563. doi:10.1016/0257-8972(94)90217-8
[19] J. Musil, F. Kunc, H. Zeman and H. Polakova, “Relationships between Hardness, Young’s Modulus and Elastic Recovery in Hard Nanocomposite Coatings,” Surface and Coatings Technology, Vol. 154, No. 2-3, 2002, pp. 304-313. doi:10.1016/S0257-8972(01)01714-5

Copyright © 2024 by authors and Scientific Research Publishing Inc.

Creative Commons License

This work and the related PDF file are licensed under a Creative Commons Attribution 4.0 International License.