Synthesis of La/N Co-Doped SrTiO3 Using Polymerized Complex Method for Visible Light Photocatalysis

Abstract

Lanthanum and nitrogen co-doped SrTiO3 was synthesized using polymerized complex method with Ti(OC3H7)4, SrCl2·6H2O and La(NO3)3·6H2O as starting materials followed by calcinations in NH3. Ethylene glycol and anhydrous citric acid were used as the precursors of synthesis. The samples were characterized using XRD, TEM, DRS, BET, EDX and XPS. The cubic-perovskite type of La/N co-doped SrTiO3 nanoparticle could be successfully synthesized. The photocatalytic activity of SrTiO3 for DeNOx ability in visible light region (λ > 510 nm) could be improved by co-doping of La3+ and N3_. The high visible light photocatalytic activity of this substance was caused by a narrow band gap energy that enables to absorb visible light.

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Sulaeman, U. , Yin, S. and Sato, T. (2013) Synthesis of La/N Co-Doped SrTiO3 Using Polymerized Complex Method for Visible Light Photocatalysis. Advances in Nanoparticles, 2, 6-10. doi: 10.4236/anp.2013.21002.

Conflicts of Interest

The authors declare no conflicts of interest.

References

[1] Y. Sun, J. Liu and Z. Li, “Design of Highly Ordered Ag-SrTiO3 Nanotube Arrays for Photocatalytic Degradation of Methyl Orange,” Journal Solid State Chemistry, Vol. 184, No. 8, 2011, pp. 1924-1930. doi:10.1016/j.jssc.2011.05.037
[2] G. Wang, Y. Qin, J. Cheng and Y. Wang, “Influence of Zn Doping on the Photocatalytic Property of SrTiO3,” Journal of Fuel Chemistry and Technology, Vol. 38, No. 4, 2010, pp. 502-507. doi:10.1016/S1872-5813(10)60042-4
[3] J. Wang, S. Yin, M. Komatsu, Q. Zhang, F. Saito and T. Sato, “Preparation and Characterization of Nitrogen Doped SrTiO3 Photocatalyst,” Journal of Photochemistry and Photobiology A: Chemistry, Vol. 165, No. 1-3, 2004, pp. 149-156. doi:10.1016/j.jphotochem.2004.02.022
[4] A. Jia, Z. Su, L. Lou and S. Liu, “Synthesis and Characterization of Highly-Active Nickel and Lanthanum Co Doped SrTiO3,” Solid State Science, Vol. 12, No. 7, 2010, pp. 1140-1145. doi:10.1016/j.solidstatesciences.2010.04.005
[5] J. Wang, H. Li, H. Li, S. Yin and T. Sato, “Preparation and Photocatalytic Activity of Visible Light-Active Sulfur and Nitrogen Co-Doped SrTiO3,” Solid State Science, Vol. 11, No. 1, 2009, pp. 182-188. doi:10.1016/j.solidstatesciences.2008.04.010
[6] T. Ohno, T. Tsubota, Y. Nakamura and K. Sayama, “Pre paration of S, C Cation-Codoped SrTiO3 and Its Photocatalytic Activity under Visible Light,” Applied Catalysis A: General, Vol. 288, No. 1-2, 2005, pp. 74-79. doi:10.1016/j.apcata.2005.04.035
[7] M. Miyauchi, M. Takashio and H. Tobimatsu, “Photocatalytic Activity of SrTiO3 Codoped with Nitrogen and Lanthanum under Visible Light Illumination,” Langmuir, Vol. 20, No. 1, 2004, pp. 232-236. doi:10.1021/la0353125
[8] J. Wang, S. Yin, M. Komatsu and T. Sato, “Lanthanum and Nitrogen Co-Doped SrTiO3 Powders as Visible Light Sensitive Photocatalyst,” Journal of the European Ceramic Society, Vol. 25, No. 13, 2005, pp. 3207-3212. doi:10.1016/j.jeurceramsoc.2004.07.027
[9] A. Kasahara, K. Nukumizu, G. Hitoki, T. Takata, J.N. Kondo, M. Hara, H. Kobayashi and K. Domen, “Photoreactions on LaTiO2N under Visible Light Irradiation,” The Journal of Physical Chemistry A, Vol. 106, No. 29, 2002, pp. 6750-6753. doi:10.1021/jp025961+
[10] S. Farhikhteh, A. Maghsoudipour and B. Raissi, “Synthesis of Nanocrystalline YSZ (ZrO2-8Y2O3) Powder by Polymerized Complex Method,” Journal of Alloys and Com pounds, Vol. 491, No. 1-2, 2010, pp. 402-405. doi:10.1016/j.jallcom.2009.10.196
[11] J. P. Zhao, M. H. Quan and L. Zhang, “Preparation of Potassium Lithium Niobate Powders with Low Li Content via the Pechini Method,” Ceramics International, Vol. 32, No. 7, 2006, pp. 843-846. doi:10.1016/j.ceramint.2005.05.010
[12] S. Qiu, H. Fan and X. Zheng, “Pb(Zr0.95Ti0.05)O3 Powders Synthesized by Pechini Method: Effect of Molecular Weight of Polyester on the Phase and Morphology,” Journal of Sol-Gel Science and Technology, Vol. 42, No.1, 2007, pp. 21-26. doi:10.1007/s10971-006-1509-3
[13] B. Dcullity, “Elements of X-Ray Diffraction,” 3rd Edition, Addison-Wesley Publishing Co., Boston, 1976.
[14] S. X. Liu, X. Y. Chen and X. Chen, “Preparation of N-Doped Visible Light Response Nanosize TiO2 Photocatalyst Using the Acid-Catalyzed Hydrolysis Method,” Chinese Journal of Catalysis, Vol. 27, No. 8, 2006, pp. 697-702. doi:10.1016/S1872-2067(06)60037-5
[15] D. C. Cronemeyer, “Infrared Absorption of Reduced Rutile TiO2 Single Crystals,” Physical Review, Vol. 113, No. 5, 1959, pp. 1222-1226. doi:10.1103/PhysRev.113.1222
[16] A. J. Nelson, T. Buuren, T. M. Willey, C. Bostedt, J. J. Adams, K. I. Schaffers, L. Terminello and T. A. Callcott, “Electronic Structure of Lanthanum Calcium Oxoborate LaCa4O(BO3)3,” Journal of Electron Spectroscopy and Re lated Phenomena, Vol. 137-140, No. 2004, pp. 541-546.
[17] S. Mart?nez-Mendez, Y. Henr?quez, O. Dom?nguez, L. D’Ornelas and H. Krentzien, “Catalytic Properties of Silica Supported Titanium, Vanadium and Niobium Oxide Nanoparticles towards the Oxidation of Saturated and Unsaturated Hydrocarbons,” Journal of Molecular Catalysis A: Chemical, Vol. 252, No. 1-2, 2006, pp. 226 234. doi:10.1016/j.molcata.2006.02.041
[18] M. Ziolek and I. Nowak, “Characterization Techniques Employed in the Study of Niobium and Tantalum-Containing Materials,” Catalysis Today, Vol. 78, No. 1-4, 2003, pp. 543-553. doi:10.1016/S0920-5861(02)00353-X
[19] R. E. Tanner, Y. Liang and E. I. Altman, “Structure and Chemical Reactivity of Adsorbed Carboxylic Acids on Anatase TiO2(0 0 1),” Surface Science, Vol. 506, No. 3, 2002, pp. 251-271. doi:10.1016/S0039-6028(02)01388-2
[20] M. Z. Atashbar, H. T. Sun, B. Gong, W. Wlodarski and R. Lam, “XPS Study of Nb-Doped Oxygen Sensing TiO2 Thin Films Prepared by Sol-Gel Method,” Thin Solid Films, Vol. 326, No. 1-2, 1998, pp. 238-244. doi:10.1016/S0040-6090(98)00534-3

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