Volatile Organic Compounds in Alberta, Canada Residences—Evidence from Community Surveys

Abstract

The impact of the built environment on public health is complex, involving several determinants of health including indoor air quality. People who spend the most time indoors can be exposed to indoor air pollutants for long periods of time. These are often the same people who are most susceptible to adverse effects if exposures are high enough (young children, elderly, and chronically ill, especially those suffering from respiratory diseases). An analysis of data on selected indoor volatile organic compounds (VOCs) from community studies in Alberta, Canada was undertaken. Measures of typical (central tendency) and high end (upper limit) indoor concentrations were estimated from seven studies in Alberta. Best estimates of central tendency indoor concentrations for 12 VOCs—benzene, ethylbenzene, o-xylene, 3-methylhexane, heptane, octane, nonane, decane, 1,1,1-trichloroethane, carbon tetrachloride, tetrachloroethylene, and 1,2,4-trimethylbenzene—were less than 5 μg/m3. Best estimates of central tendency indoor concentrations for three VOCs—toluene, m/p-xylene, and limonene—were greater than 5 μg/m3. In the case of best estimates of upper limit indoor concentrations—benzene, ethylbenzene, o-xylene, hexane, 3-methylhexane, heptane, octane, nonane, carbon tetrachloride, and tetrachloroethylene had upper limit concentrations less than 15 μg/m3. Best estimates of upper limit indoor concentrations for toluene, m/p xylene, decane, limonene, 1,1,1-trichloroethane, and 1,2,4-trimethylbenzene were greater than 15 μg/m3. Upper limit concentrations observed inside Alberta residences were about 4 to 10 times higher than typical concentrations for most of the VOCs observed. Upper limit indoor concentrations for carbon tetrachloride and benzene in Alberta are similar to or greater than levels judged by US EPA to imply a concern for potential cancer effects. This indicates that some homes in Alberta can have levels of carbon tetrachloride and benzene that may be of concern from a public health point-of-view.

Share and Cite:

W. Kindzierski, "Volatile Organic Compounds in Alberta, Canada Residences—Evidence from Community Surveys," Journal of Environmental Protection, Vol. 3 No. 9A, 2012, pp. 1176-1187. doi: 10.4236/jep.2012.329136.

Conflicts of Interest

The authors declare no conflicts of interest.

References

[1] Alberta Treasury Board and Finance, “Alberta Demographic Spotlight—Recent Demographic Trends in Al- berta’s Economic Regions,” Government of Alberta, Ed- monton, 2011. www.finance.alberta.ca/aboutalberta/demographic_spotlights.html
[2] Agriculture and Rural Development, “Agroclimatic Atlas of Alberta: Climate of Alberta,” Government of Alberta, Edmonton, 2007. www1.agric.gov.ab.ca/$department/deptdocs.nsf/all/sag6299
[3] W. R. Ott, “Exposure Analysis: A Receptor-Oriented Science,” In: W. R. Ott, A. C. Steinemann and L. A. Wallace, Eds., Exposure Analysis, CRC Press, Boca Raton, 2007, pp. 3-32.
[4] J. A. Leech, K. Wilby, E. McMullen and K. Laporte, “The Canadian Human Activity Pattern Survey: Report of Methods and Population Surveyed,” Chronic Diseases in Canada, Vol. 17, No. 3, 1996, pp. 118-123.
[5] J. Heinrish, “Influence of Indoor Factors in Dwellings on the Development of Childhood Asthma,” International Journal of Hygiene and Environmental Health, Vol. 214, No. 1, 2011, pp. 1-25. doi:10.1016/j.ijheh.2010.08.009
[6] P. J. Franklin, “Indoor Air Quality and Respiratory Health of Children,” Paediatric Respiratory Reviews, Vol. 8, No. 4, 2007, pp. 281-286. doi:10.1016/j.prrv.2007.08.007
[7] C. J. Weschler, “Changes in Indoor Pollutants since the 1950s,” Atmospheric Environment, Vol. 43, No. 1, 2009, pp. 153-169. doi:10.1016/j.atmosenv.2008.09.044
[8] R. W. Clapp, G. K. Howe and M. M. Jacobs, “Environmental and Occupational Causes of Cancer: A Review of Recent Scientific Literature,” Lowell Center for Sustainable Production, University of Massachusetts, Lowell, 2005. www.sustainableproduction.org/downloads/Causes%20of%20Cancer.pdf
[9] United States Environment Protection Agency, “Technical Background Document to Support Rulemaking Pur- suant to the Clean Air Act Section 112 (g)—Ranking of Pollutants with Respect to Hazard to Human Health,” United States Environment Protection Agency, Research Triangle Park, 1994.
[10] Alberta Health & Wellness, “Wood Buffalo Environmental Association Human Exposure Monitoring Pro- gram: Part I—Methods Report, Part II—2005 Monitoring Year Results,” Alberta Health & Wellness, Edmonton, 2005. www.health.alberta.ca/newsroom/publications.html
[11] R. K. Miyagawa, “Personal Air Sampling of Volatile Organic Compounds in Fort McKay, Alberta,” Master Thesis, University of Alberta, Edmonton, 2001. www.collectionscanada.gc.ca
[12] G. Hoeksema, “Atmospheric BTEX in Fort McKay, AB: A Comparison with Baseline Measurements,” Master Thesis, University of Alberta, Edmonton, 2007. www.collectionscanada.gc.ca
[13] Alberta Health & Wellness, “The Grande Prairie and Area Community Exposure and Health Effects Assess- ment Program,” Alberta Health & Wellness, Edmonton, 2002. http://www.health.alberta.ca/newsroom/publications.html
[14] Alberta Health & Wellness, “Fort Saskatchewan and Area Community Exposure and Health Effects Assessment Program,” 2003. http://www.health.alberta.ca/newsroom/publications.html
[15] S. M. Probert, “Community Sampling of Volatile Organic Compounds in the Capital Health Region: A Health Perspective,” Master Thesis, University of Alberta, Edmon- ton, 2000. www.collectionscanada.gc.ca
[16] Alberta Health & Wellness, “Wabamun and Area Com- munity Exposure and Health Effects Assessment Program,” 2006. http://www.health.alberta.ca/newsroom/publications.html
[17] R. W. Whitmore, “Design of Surveys for Residential and Personal Monitoring of Hazardous Substances,” Atmos- pheric Environment, Vol. 22, No. 10, 1988, pp. 2077- 2084. doi:10.1016/0004-6981(88)90119-9
[18] D. J. Casley and K. Kumar, “The Collection, Analysis, and Use of Monitoring and Evaluation Data,” Johns Hop- kins University Press, Baltimore, 1988.
[19] United States Environment Protection Agency, “Guidance for Choosing a Sampling Design for Environmental Data Collection, EPA QA/G-5S. EPA/240/R-02/005,” United States Environment Protection Agency, Washington DC, 2002.
[20] R. L. Scheaffer, W. Mendenhall and R. L. Ott, “Elementary Survey Sampling,” 5th Edition, Duxbury Press, New York, 1996.
[21] 3M, “Organic Vapor Monitor Sampling and Analysis Guide: Organic Vapor Monitors 3500/3510 and Organic Vapor Monitors 3520/3530,” 3M Occupational Health and Environmental Safety Division, St. Paul, 1998.
[22] R. M. Byanju, M. B. Gewali and K. Manandhar, “Passive Sampling of Ambient Nitrogen Dioxide Using Local Tubes,” Journal of Environmental Protection, Vol. 3, No. 2, 2012, pp. 177-186. doi:10.4236/jep.2012.32022
[23] P. Fellin and R. Otson, “Assessment of the Influence of Climatic Factors on Concentration Levels of Volatile Or- ganic Compounds (VOCs) in Canadian Homes,” Atmospheric Environment, Vol. 28, No. 22, 1994, pp. 3581- 3586. doi:10.1016/1352-2310(94)00204-X
[24] I. Burstyn, X. You, N. Cherry and A. Senthilselvan, “De- terminants of Airborne Benzene Concentrations in Rural Areas of Western Canada,” Atmospheric Environment, Vol. 41, No. 36, 2007, pp. 7778-7787. doi:10.1016/j.atmosenv.2007.06.011
[25] C. W. Chung, M. Morandi, T. Stock and M. Afshar, “Evaluation of a Passive Sampler for Volatile Organic Compounds at ppb Concentrations, Varying Temperatures, and Humidities with 24-h Exposures; 2. Sampler Performance,” Environmental Science and Technology, Vol. 33, No. 20, 1999, pp. 3666-3671. doi:10.1021/es990613f
[26] J. Begerow, E. Jermann, T. Keles and L. Dunemann, “Performance of Two Different Types of Passive Sam- plers for the GC/ECD-FID Determination of Environ- mental VOC Levels in Air,” Fresenius’ Journal of Ana- lytical Chemistry, Vol. 363, No. 4, 1999, pp. 399-403.
[27] B. Oury, F. Lhuillier, J.-C. Protois and Y. Morele, “Be- havior of the GABIE, 3M 3500, PerkinElmer Tenax TA, and Radiello 145 Diffusive Samplers Exposed over a Long Time to a Low Concentration of VOCs,” Journal of Occupational and Environmental Hygiene, Vol. 3, No. 10, 2006, pp. 547-557. doi:10.1080/15459620600906613
[28] U. Schlink, M. Rehwagen, M. Damm, M. Richter, M. Borte, and O. Herbarth, “Seasonal Cycle of Indoor-VOCs: Comparison of Apartments and Cities,” Atmospheric Environment, Vol. 38, No. 8, 2004, pp. 1181-1190. doi:10.1016/j.atmosenv.2003.11.003
[29] P. Fellin and R. Otson, “Seasonal Trends of Volatile Or- ganic Compounds (VOCs) in Canadian Homes,” Proceedings of the 6th Conference on Indoor Air Quality and Climate, Vol. 2, 1993, pp. 117-122.
[30] K. B. Hoddinott and A. P. Lee, “Establishing Background Levels of Risk for Residential Indoor Air,” Proceedings of the 1st NSF International Conference on Indoor Air Health: Impacts, Issues and Solutions, Ann Arbor, 1999, pp. 260-269.
[31] E. Lebret, H. L. van de Wiel, H. P. Bos, D. Noij and J. S. M. Boleij, “Volatile Organic Compounds in Dutch Homes,” Environment International, Vol. 12, No. 1-4, 1986, pp. 323-332. doi:10.1016/0160-4120(86)90046-2
[32] W. R. Ott, “Environmental Statistics and Data Analysis,” CRC Press, Boca Raton, 1995.
[33] W. B. Kindzierski, “Importance of Human Environmental Exposure to Hazardous Air Pollutants from Gas Flares,” Environmental Reviews, Vol. 8, No. 1, 2000, pp. 41-62. doi:10.1139/a00-005
[34] United States Environment Protection Agency, “Integrated Risk Information System (IRIS),” United States Environment Protection Agency, Washington DC, 2012. www.epa.gov/iris/
[35] Health Canada, “Federal Contaminated Site Risk As- sessment in Canada. Part I: Guidance on Human Health Preliminary Quantitative Risk Assessment (PQRA),” Health Canada, Ottawa, 2004. www.federalcontaminatedsites.gc.ca/publications/index-eng.aspx
[36] W. Kindzierski, J. Jin and M. Gamal El-Din, “Plain Lan- guage Explanation of Human Health Risk Assessment, OSRIN Report No. TR-14,” Oil Sands Research and In- formation Network, University of Alberta, Edmonton, 2011. www.osrin.ualberta.ca/en/OSRINPublications.aspx
[37] M. D. Jackson, L. A. Sparks, B. A. Tichenor, and J. B. White, “Evaluating Sources of Indoor Air Pollution,” Journal of the Air and Waste Management Association, Vol. 40, No. 4, 1990, pp. 487-492. doi:10.1080/10473289.1990.10466703
[38] R. Otson, P. Fellin and Q. Tran, “VOCs in Representative Canadian Residences,” Atmospheric Environment, Vol. 28, No. 22, 1994, pp. 3563-3569. doi:10.1016/1352-2310(94)00201-U
[39] P. Wolkoff and G. D. Nielsen, “Organic Compounds in Indoor Air—Their Relevance for Perceived Indoor Air Quality,” Atmospheric Environment, Vol. 35, No. 26, 2001, pp. 4407-4417. doi:10.1016/S1352-2310(01)00244-8
[40] P. Wolkoff, P. A. Clausen, B. Jensen, G. D. Nielsen and C. K. Wilkins, “Are We Measuring the Relevant Indoor Pollutants?” Indoor Air, Vol. 7, No. 2, 1997, pp. 92-106. doi:10.1111/j.1600-0668.1997.t01-2-00003.x

Copyright © 2024 by authors and Scientific Research Publishing Inc.

Creative Commons License

This work and the related PDF file are licensed under a Creative Commons Attribution 4.0 International License.