Author(s)

Hasan A. Mohammed^*, Nihad Ismeal Taha

Department of Chemistry, College of Science, University of Kirkuk, Kirkuk, Iraqi.

The binuclear Schiff base complexes prepared by condensation 2,6-diamino-pyridine and salicylaldehyde (LH) by using microwave and adding metal salts to ligand by same ratio. The Schiff base ligand was checked by infrared, electronic spectra and ¹HNMR spectroscopy and prepared complexes characterized by molar conductivity, infrared, electronic spectra and susceptibility measurements. The values of molar conductivities reveal that the complexes are non-electrolytes, from obtained data of electronic spectra and magnetic moment, an octahedral geometry was suggested, coordinated to the metal ions in a manner with N donor sites of imine groups, and oxygen of phenolic OH group.

Schiff Base, Binuclear Metal, Complexes, 2, 6-Diaminopyridine, Salicylaldehyde

Mohammed, H. and Taha, N. (2017) Microwave Preparation and Spectroscopic Investigation of Binuclear Schiff Base Metal Complexes Derived from 2,6-Diaminopyridine with Salicylaldehyde. International Journal of Organic Chemistry, 7, 412-419. doi: 10.4236/ijoc.2017.74033.