Nanoporous CuO/CeO₂ ribbons are successfully prepared through dealloying melt-spun Al_80-xCu₂₀Ce_x (x = 0.5, 1, 2, 3, at%) alloy in a 5 wt% NaOH aqueous solution, followed by calcining in air. The samples are characterized by XRD, SEM, EDS, HRTEM, Raman and gas chromatograph. For the dealloyed melt-spun Al_80-xCu₂₀Ce_x (x = 0.5, 1, 2, 3, at%) alloy, the XRD results indicate that Cu and Cu₂O are formed, while CuO and CeO₂ are formed coupled with calcinations. The SEM shows that the CuO/CeO₂ ribbons with a homogeneous pore/grain structure are thermally stable up to 600℃because uniform CeO₂ particles are dispersedly loaded on the fine CuO grains of the porous structure, which is validated by TEM again. Meanwhile, the Raman spectra show that the concentration of oxygen vacancies reach a maximum value when the calcining temperature at 600℃. In addition, the gas chromatograph results show that the dealloyed Al₇₈Cu₂₀Ce₂ ribbons with calcined at 600℃have the best active catalysis for CO oxidation and the rates of CO conversation reaching at 50% and 100% are 150℃and 320℃, respectively, owing to the synergetic effects of the CuO and CeO₂ species.