The 3d³4p, 3d³5p and 3d²4s4p odd configurations of the V II spectrum have been reanalysed and three 3d²4s4p triplets are assigned higher energies than previously proposed. We have determined the fine structure parameters, the largest and next largest eigenvector percentages of levels, their calculated Landé g_J-factors and predicted positions for missing experimental levels up to 100,000 cm^-1 for the 3d²4s4p configuration. Furthermore for the first time a hyperfine structure (HFS) parametric treatment, involving levels of these two configurations has been carried out. The deduced single-electron HFS parameter values are successfully checked with those obtained by means of ab initio calculations.